Catalytic generation of borenium ions by cooperative B-H bond activation: The elusive direct electrophilic borylation of nitrogen heterocycles with pinacolborane

Journal of the American Chemical Society

Volumn 135, Issue 30, 2013, Pages 10978-10981

  Stahl, Timo ^a   Müther, Kristine ^a,b   Ohki, Yasuhiro ^b   Tatsumi, Kazuyuki ^b   Oestreich, Martin ^a  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

^b NAGOYA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

BOND ACTIVATION; BOND METATHESIS; BORYLATION; ELECTROPHILIC AROMATIC SUBSTITUTIONS; NITROGEN HETEROCYCLES; PINACOLBORANE; SULFUR ATOMS; THIOLATES;

HYDRIDES; RUTHENIUM; RUTHENIUM COMPOUNDS;

NITROGEN;

9 BORABICYCLO[3.3.1]NONANE; BORANE DERIVATIVE; CATECHOLBORANE; NITROGEN; PINACOLBORANE; UNCLASSIFIED DRUG;

ARTICLE; ATOM; BORYLATION; CATALYSIS; CATALYST; CHEMICAL BOND; CHEMICAL REACTION; COMPLEX FORMATION; CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; ELECTROPHILICITY; PROTON NUCLEAR MAGNETIC RESONANCE; SUBSTITUTION REACTION;

EID: 84881061410     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja405925w     Document Type: Article

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