Synthesis and structure of the dimethyl sulfide adducts of mono- and bis(pentafluorophenyl)borane

Organometallics

Volumn 29, Issue 9, 2010, Pages 2194-2197

  Fuller, Anna Marie ^a   Hughes, David L ^a   Lancaster, Simon J ^a   White, Callum M ^a  

^a UNIVERSITY OF EAST ANGLIA   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

COLORLESS CRYSTALS; DIETHYL ETHERS; DIMETHYL SULFIDE; FACILE EXCHANGE; PENTAFLUOROPHENYL; TRIS(PENTAFLUOROPHENYL) BORANE;

ETHERS; SYNTHESIS (CHEMICAL);

SULFUR COMPOUNDS;

EID: 77951801469     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om100152v     Document Type: Article

References (24)

1. Parks, D. J.; Spence, R. E. von H.; Piers, W. E. Angew. Chem., Int. Ed. Engl. 1995, 34, 809
2. Parks, D. J.; Piers, W. E.; Yap, G. P. A. Organometallics 1998, 17, 5492
3. Piers, W. E.; Chivers, T. Chem. Soc. Rev. 1997, 26, 345
4. Parks, D. J.; Piers, W. E. Tetrahedron 1998, 54, 15469
5. Spies, P.; Kehr, G.; Bergander, K.; Wibbeling, B.; Fröhlich, R.; Erker, G. Dalton Trans. 2009, 1534
6. For reviews of the chemistry of tris(pentafluorophenyl)borane see: ref 3 and Chen, E. Y.-X.; Marks, T. J. Chem. Rev. 2000, 100, 1391
7. Erker, G. Dalton Trans. 2005, 1883
8. Piers, W. E. Adv. Organomet. Chem. 2005, 52, 1
9. For recent reviews on 'frustrated Lewis pairs', see: Stephan, D. W. Dalton Trans. 2009, 3129
10. Stephan, D. W.; Erker, G. Angew. Chem., Int. Ed. 2010, 49, 46
11. Jiang, C.; Blacque, O.; Berke, H. Organometallics 2009, 28, 5233
12. Hoshi, M.; Shirakawa, K.; Okimoto, M. Tetrahedron Lett. 2007, 48, 8475
13. Duchateau, R.; Lancaster, S. J.; Thornton-Pett, M.; Bochmann, M. Organometallics 1997, 16, 4995
14. 2HB], resulting from dissociation of the weakly bound dimethyl sulfide ligand.
15. 2.
16. 3 and toluene, respectively: Lancaster, S. J.; Hughes, D. L. Dalton Trans. 2003, 1779
17. 6 were collected from a standard sample.
18. 5 rings of the minor component was not possible since not all atoms could be located in difference maps: the located atoms were refined isotropically.
19. Lancaster, S. J. http://www.syntheticpages.org/pages/215.
20. Pohlmann, J. L. W.; Brinckman, F. E. Z. Naturforsch. 1965, 20b, 5
21. CrysAlis-CCD and -RED; Oxford Diffraction Ltd: Abingdon, UK, 2008.
22. Sheldrick, G. M. Acta Crystallogr., Sect. A: Found. Crystallogr. 2008, 64, 112
23. Farrugia, L. J. J. Appl. Crystallogr. 1999, 32, 837
24. International Tables for X-Ray Crystallography; Wilson, A. J. C., Ed.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1992; Vol. C, pp 193, 219, and 500.