Direct observation of reductive elimination of MeX (X = Cl, Br, I) from RhIII complexes: Mechanistic insight and the importance of sterics

Journal of the American Chemical Society

Volumn 135, Issue 30, 2013, Pages 11040-11047

  Feller, Moran ^a   Diskin Posner, Yael ^a   Leitus, Gregory ^a   Shimon, Linda J W ^a   Milstein, David ^a  

^a WEIZMANN INSTITUTE OF SCIENCE   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

CO-ORDINATIVELY UNSATURATED; DIRECT OBSERVATIONS; METHYL HALIDES; POLAR APROTIC SOLVENT; POLAR PROTIC; RATE INCREASE; REDUCTIVE ELIMINATION; STERIC FACTOR;

BROMINE COMPOUNDS; RHODIUM; RHODIUM COMPOUNDS; UNSATURATED COMPOUNDS;

CHLORINE COMPOUNDS;

ACETONITRILE; HALIDE; ISONITRILE DERIVATIVE; PYRIDINE DERIVATIVE; RHENIUM; SOLVENT;

ARTICLE; COMPLEX FORMATION; CRYSTAL STRUCTURE; ELIMINATION REACTION; MOLECULAR MECHANICS; TEMPERATURE DEPENDENCE;

EID: 84881037430     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja401852c     Document Type: Article

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