-
2
-
-
0003467672
-
-
4th ed, Wiley, New York, and pp
-
b) J. March, Advanced Organic Chemistry, 4th ed., Wiley, New York, 1992, pp.531-534 and pp. 689-694.
-
(1992)
Advanced Organic Chemistry
-
-
March, J.1
-
3
-
-
53849117963
-
-
87th ed, Taylor & Francis, CRC, Boca Raton
-
CRC Handhook of Chemistry & Physics, 87th ed., Taylor & Francis, CRC, Boca Raton 2006, pp. 9-51.
-
(2006)
CRC Handhook of Chemistry & Physics
, pp. 9-51
-
-
-
5
-
-
84949473250
-
-
Ed. F. R. Hartley, Wiley, Chichester UK
-
b)C. L. Raston, G. Salem, in Chemistry of the Metal-Carbon Bond, Vol. 4 (Ed. F. R. Hartley), Wiley, Chichester (UK), 1987, pp. 159-306.
-
(1987)
Chemistry of the Metal-Carbon Bond
, vol.4
, pp. 159-306
-
-
Raston, C.L.1
Salem, G.2
-
6
-
-
0003487210
-
-
For general references see: a, University Science Books, Sausalito, CA
-
For general references see: a) J. P. Collman, L. S. Hegedus, J. R. Norton, R. O. Finke, Principles and Applications of Organotransition Metal Chemistry, University Science Books, Sausalito, CA, 1987;
-
(1987)
Principles and Applications of Organotransition Metal Chemistry
-
-
Collman, J.P.1
Hegedus, L.S.2
Norton, J.R.3
Finke, R.O.4
-
8
-
-
53849100497
-
-
Palladium in Organic Synthesis: J. Tsuji, Top. Organomet. Chem. 2005, 14, 1-332.
-
"Palladium in Organic Synthesis": J. Tsuji, Top. Organomet. Chem. 2005, 14, 1-332.
-
-
-
-
11
-
-
33751281236
-
-
b) R. F. Heck, Synlett 2006, 18, 2855-2860;
-
(2006)
Synlett
, vol.18
, pp. 2855-2860
-
-
Heck, R.F.1
-
14
-
-
33745395707
-
-
b) J. F. Hartwig, Synlett 2006, 9, 1283-1294.
-
(2006)
Synlett
, vol.9
, pp. 1283-1294
-
-
Hartwig, J.F.1
-
15
-
-
33646198385
-
-
2nd ed, Eds, M. Beller, C. BoIm, Wiley-VCH, Weinheim
-
a) A. Zapf, M. Beller, T. H. Riermeier, Transition Metals for Organic Synthesis, Vol. 1, 2nd ed. (Eds.: M. Beller, C. BoIm,), Wiley-VCH, Weinheim, 2004, pp. 231-256;
-
(2004)
Transition Metals for Organic Synthesis
, vol.1
, pp. 231-256
-
-
Zapf, A.1
Beller, M.2
Riermeier, T.H.3
-
18
-
-
13444263825
-
-
Angew. Chem. Int. Ed. 2005, 44, 674-688.
-
(2005)
Angew. Chem. Int. Ed
, vol.44
, pp. 674-688
-
-
-
20
-
-
0037112673
-
-
Angew. Chem. Int. Ed. 2002, 41, 4176-4211;
-
(2002)
Angew. Chem. Int. Ed
, vol.41
, pp. 4176-4211
-
-
-
22
-
-
38849191003
-
-
c) E. A. B. Kantchev, C. J. O'Brien, M. G. Organ, Angew. Chem. 2007, 119, 2824-2870;
-
(2007)
Angew. Chem
, vol.119
, pp. 2824-2870
-
-
Kantchev, E.A.B.1
O'Brien, C.J.2
Organ, M.G.3
-
23
-
-
34250797354
-
-
Angew. Chem. Int. Ed. 2007, 46, 2768-2813;
-
(2007)
Angew. Chem. Int. Ed
, vol.46
, pp. 2768-2813
-
-
-
24
-
-
0024807182
-
-
for early work on catalytic Ar-Cl activation see: Y. Ben-David, M. Portnoy, D. Milstein, J. Am. Chem. Soc. 1989, 111, 8742-8744.
-
d) for early work on catalytic Ar-Cl activation see: Y. Ben-David, M. Portnoy, D. Milstein, J. Am. Chem. Soc. 1989, 111, 8742-8744.
-
-
-
-
25
-
-
53849099117
-
-
In this Concept article, we will try to discuss only the unequivocally confirmed C-X reductive-elimination reactions. Some examples of C-X bond-forming reactions, not necessarily involving the reductive-elimination step, will be described in the end
-
In this Concept article, we will try to discuss only the unequivocally confirmed C-X reductive-elimination reactions. Some examples of C-X bond-forming reactions, not necessarily involving the reductive-elimination step, will be described in the end.
-
-
-
-
27
-
-
0000553967
-
-
a) N. F. Goldshleger, V. V. Eskova, A. E. Shilov, A. A. Shteinman, Zh. Fiz. Khim. 1972, 46, 1353-1354;
-
(1972)
Zh. Fiz. Khim
, vol.46
, pp. 1353-1354
-
-
Goldshleger, N.F.1
Eskova, V.V.2
Shilov, A.E.3
Shteinman, A.A.4
-
28
-
-
53849092537
-
-
b) V. V. Lavrushko, A. E. Shilov, A. A. Shteinman, Kinet. Katal. 1975, 16, 1479-1483.
-
(1975)
Kinet. Katal
, vol.16
, pp. 1479-1483
-
-
Lavrushko, V.V.1
Shilov, A.E.2
Shteinman, A.A.3
-
32
-
-
0002892941
-
-
a) G. A. Luinstra, L. Wang, S. S. Stahl, J. A. Labinger, J. E. Bercaw, J. Organomet. Chem. 1995, 504, 75-91;
-
(1995)
J. Organomet. Chem
, vol.504
, pp. 75-91
-
-
Luinstra, G.A.1
Wang, L.2
Stahl, S.S.3
Labinger, J.A.4
Bercaw, J.E.5
-
33
-
-
1542616949
-
-
b) G. A. Luinstra, J. A. Labinger, J. E. Bercaw, J. Am. Chem. Soc. 1993, 115, 3004-3005.
-
(1993)
J. Am. Chem. Soc
, vol.115
, pp. 3004-3005
-
-
Luinstra, G.A.1
Labinger, J.A.2
Bercaw, J.E.3
-
34
-
-
53849143776
-
-
3-Cl reductive elimination was also proposed in: a V. V. Zamashchikov, E. S. Rudakov, S.A. Mitchenko, TM. Pekhtereva, Koord. Khim. 1985, 11, 69-71;
-
3-Cl reductive elimination was also proposed in: a) V. V. Zamashchikov, E. S. Rudakov, S.A. Mitchenko, TM. Pekhtereva, Koord. Khim. 1985, 11, 69-71;
-
-
-
-
35
-
-
0000542088
-
-
b) E. Lindner, O. Wang, H. A. Mayer, R. Fawzi, M. Sleimann, Organometallics 1993, 12, 1865-1870.
-
(1993)
Organometallics
, vol.12
, pp. 1865-1870
-
-
Lindner, E.1
Wang, O.2
Mayer, H.A.3
Fawzi, R.4
Sleimann, M.5
-
36
-
-
0001468889
-
-
a) K. I. Goldberg, J. Yan, E. L. Winter, J. Am. Chem. Soc. 1994, 116, 1573-1574;
-
(1994)
J. Am. Chem. Soc
, vol.116
, pp. 1573-1574
-
-
Goldberg, K.I.1
Yan, J.2
Winter, E.L.3
-
37
-
-
0000827044
-
-
b) K. I. Goldberg, J. Yan, E. M. Breitung, J. Am. Chem. Soc. 1995, 117, 6889-6896.
-
(1995)
J. Am. Chem. Soc
, vol.117
, pp. 6889-6896
-
-
Goldberg, K.I.1
Yan, J.2
Breitung, E.M.3
-
38
-
-
0037108776
-
-
R. P. Hughes, J. S. Overby, K.-C. Lam, C. D. Incarvito, A. L. Rheingold. Polyhedron 2002, 21, 2357-2360.
-
(2002)
Polyhedron
, vol.21
, pp. 2357-2360
-
-
Hughes, R.P.1
Overby, J.S.2
Lam, K.-C.3
Incarvito, C.D.4
Rheingold, A.L.5
-
41
-
-
53849083962
-
-
Following the same reaction by P NMR spectrometry revealed the formation of large amounts of an additional product in the reaction mixture. This product is most likely a quaternary phosphonium salt, which was not detected by UV/Vis spectroscopy.
-
Following the same reaction by "P NMR spectrometry revealed the formation of large amounts of an additional product in the reaction mixture. This product is most likely a quaternary phosphonium salt, which was not detected by UV/Vis spectroscopy.
-
-
-
-
44
-
-
33846639194
-
-
P. M. Maitlis, A. Haynes, B. R. James, M. Catellani, G. P. Chiusoli, Dalton Trans. 2004, 3409-3419.
-
(2004)
Dalton Trans
, pp. 3409-3419
-
-
Maitlis, P.M.1
Haynes, A.2
James, B.R.3
Catellani, M.4
Chiusoli, G.P.5
-
45
-
-
0022939609
-
-
For a comprehensive report on the Monsanto process see
-
For a comprehensive report on the Monsanto process see: T. W. Dekleva, D. Forster, Adv. Catal. 1986, 34, 81-130.
-
(1986)
Adv. Catal
, vol.34
, pp. 81-130
-
-
Dekleva, T.W.1
Forster, D.2
-
46
-
-
0033920307
-
-
P. Braunstein, Y. Chauvin, J. Fischer, H. Olivier, C. Strohmann, D. V. Toronto. New J. Chem. 2000, 24, 437-445.
-
(2000)
New J. Chem
, vol.24
, pp. 437-445
-
-
Braunstein, P.1
Chauvin, Y.2
Fischer, J.3
Olivier, H.4
Strohmann, C.5
Toronto, D.V.6
-
51
-
-
34948853914
-
-
The validity of the Ar-F reductive-elimination mechanism in this reaction was recently contested: V. V. Grushin, D. J. Marshall, Organometallics 2007, 26, 4997-5002.
-
The validity of the Ar-F reductive-elimination mechanism in this reaction was recently contested: V. V. Grushin, D. J. Marshall, Organometallics 2007, 26, 4997-5002.
-
-
-
-
53
-
-
38749098194
-
-
A. Kaspi, A. Yahav-Levi, I. Goldberg, A. Vigalok, Inorg. Chem. 2008, 47, 5-7.
-
(2008)
Inorg. Chem
, vol.47
, pp. 5-7
-
-
Kaspi, A.1
Yahav-Levi, A.2
Goldberg, I.3
Vigalok, A.4
-
54
-
-
0242659049
-
-
a) A. Yahav, I. Goldberg, A. Vigalok, J. Am. Chem. Soc. 2003, 125, 13634-13635;
-
(2003)
J. Am. Chem. Soc
, vol.125
, pp. 13634-13635
-
-
Yahav, A.1
Goldberg, I.2
Vigalok, A.3
-
55
-
-
14744290546
-
-
b) A. Yahav, I. Goldberg, A. Vigalok, Inorg. Chem. 2005, 44, 1547-1153.
-
(2005)
Inorg. Chem
, vol.44
, pp. 1547-1153
-
-
Yahav, A.1
Goldberg, I.2
Vigalok, A.3
-
57
-
-
53849123143
-
-
R. W. Cockman, E. A. V. Ebsworth, J. H. Holloway, H. Murdoch, N. Robertson, P. G. Watson, in Fluorine Chemistry (Toward the 21 st Century) (Eds.: J. S. Thrasher and S. H. Strauss), ACS, Washington, DC, 1994, Chapter 20, p. 327.
-
R. W. Cockman, E. A. V. Ebsworth, J. H. Holloway, H. Murdoch, N. Robertson, P. G. Watson, in Fluorine Chemistry (Toward the 21 st Century) (Eds.: J. S. Thrasher and S. H. Strauss), ACS, Washington, DC, 1994, Chapter 20, p. 327.
-
-
-
-
58
-
-
33745952959
-
-
A. Yahav-Levi, I. Goldberg, A. Vigalok, J. Am. Chem. Soc. 2006, 125, 8710-8711.
-
(2006)
J. Am. Chem. Soc
, vol.125
, pp. 8710-8711
-
-
Yahav-Levi, A.1
Goldberg, I.2
Vigalok, A.3
-
59
-
-
41449100280
-
-
A. Yahav-Levi, I. Goldberg, A. Vigalok, A. N. Vedernikov, J. Am. Chem. Soc. 2008, 130, 724-731.
-
(2008)
J. Am. Chem. Soc
, vol.130
, pp. 724-731
-
-
Yahav-Levi, A.1
Goldberg, I.2
Vigalok, A.3
Vedernikov, A.N.4
-
62
-
-
33745577893
-
-
a) D. Kalyani, A. R. Dick, W. Q. Anani, M. S. Sanford, Org. Lett. 2006, 8, 2523-2526;
-
(2006)
Org. Lett
, vol.8
, pp. 2523-2526
-
-
Kalyani, D.1
Dick, A.R.2
Anani, W.Q.3
Sanford, M.S.4
-
63
-
-
33750468676
-
-
b) D. Kalyani, A. R. Dick, W. Q. Anani, M. S. Sanford, Tetrahedron 2006, 62, 11483-11498;
-
(2006)
Tetrahedron
, vol.62
, pp. 11483-11498
-
-
Kalyani, D.1
Dick, A.R.2
Anani, W.Q.3
Sanford, M.S.4
-
64
-
-
33744928374
-
-
c) K. L. Hull, W. Q. Anani, M. S. Sanford, J. Am. Chem. Soc. 2006, 128, 7134-7135.
-
(2006)
J. Am. Chem. Soc
, vol.128
, pp. 7134-7135
-
-
Hull, K.L.1
Anani, W.Q.2
Sanford, M.S.3
-
65
-
-
0037450893
-
-
a) R. van Belzen, C. J. Elsevier, A. Dedieu, N. Veldman, A. L. Spek, Organometallics 2003, 22, 722-736;
-
(2003)
Organometallics
, vol.22
, pp. 722-736
-
-
van Belzen, R.1
Elsevier, C.J.2
Dedieu, A.3
Veldman, N.4
Spek, A.L.5
-
66
-
-
0001203082
-
-
b) P. L. Alsters, P. F. Engel, M. P. Hogerheide, M. Copijn, A. L. Spek, G. van Koten, Organometallics 1993, 12, 1831-1844;
-
(1993)
Organometallics
, vol.12
, pp. 1831-1844
-
-
Alsters, P.L.1
Engel, P.F.2
Hogerheide, M.P.3
Copijn, M.4
Spek, A.L.5
van Koten, G.6
-
67
-
-
37049033864
-
-
IV complex was recently reported: S. R. Whiefield, M.S. Sanford, J. Am. Chem. Soc. 2007, 129, 15142-15143.
-
IV complex was recently reported: S. R. Whiefield, M.S. Sanford, J. Am. Chem. Soc. 2007, 129, 15142-15143.
-
-
-
-
68
-
-
53849122483
-
-
The mechanism of metal-carbon bond cleavage in the presence of electrophiles has been the subject of much controversy. In particular, problems in distinguishing between the oxidative addition/reductive elimination and direct SE2 mechanisms still remain unresolved: a U. Belluco. M. Giustiniani, M. Graziani, J. Am. Chem. Soc. 1967, 89, 6494-6500;
-
E2 mechanisms still remain unresolved: a) U. Belluco. M. Giustiniani, M. Graziani, J. Am. Chem. Soc. 1967, 89, 6494-6500;
-
-
-
-
70
-
-
0000202308
-
-
c) J. K. Jawad, R.J. Puddephatt, M. A. Stalter, Inorg. Chem. 1982, 21, 332-337;
-
(1982)
Inorg. Chem
, vol.21
, pp. 332-337
-
-
Jawad, J.K.1
Puddephatt, R.J.2
Stalter, M.A.3
-
72
-
-
0001041929
-
-
There still can be important differences in the reactivity of similar Pd and Pt complexes: A. F. M. J. van der Ploeg, G. van Koten, K. Vrieze, J. Organomet. Chem. 1981, 222, 155-174.
-
There still can be important differences in the reactivity of similar Pd and Pt complexes: A. F. M. J. van der Ploeg, G. van Koten, K. Vrieze, J. Organomet. Chem. 1981, 222, 155-174.
-
-
-
-
75
-
-
18044378817
-
-
Angew. Chem. Int. Ed. 2005, 44, 2324-2327;
-
(2005)
Angew. Chem. Int. Ed
, vol.44
, pp. 2324-2327
-
-
-
81
-
-
0037433554
-
-
a) J. Zanon, A. Klapars, S. L. Buchwald, J. Am. Chem. Soc. 2003, 125, 2890-2891;
-
(2003)
J. Am. Chem. Soc
, vol.125
, pp. 2890-2891
-
-
Zanon, J.1
Klapars, A.2
Buchwald, S.L.3
-
82
-
-
33744945513
-
-
b) P. Toto, J.-C. Gesquiere, N. Cousaert, B. Deprez, N. Willand, Tetrahedron Lett. 2006, 47, 4973-4978.
-
(2006)
Tetrahedron Lett
, vol.47
, pp. 4973-4978
-
-
Toto, P.1
Gesquiere, J.-C.2
Cousaert, N.3
Deprez, B.4
Willand, N.5
-
83
-
-
0035038661
-
-
B. K. Park, N. R. Kittenringham, P. M. O'Neill, Annual Rev. Pharmacol. Toxicol. 2001, 41, 443-470.
-
(2001)
Annual Rev. Pharmacol. Toxicol
, vol.41
, pp. 443-470
-
-
Park, B.K.1
Kittenringham, N.R.2
O'Neill, P.M.3
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