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The Wilkinson's catalyst was freshly prepared by the standard procedure; see the Supporting Information
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The Wilkinson's catalyst was freshly prepared by the standard procedure; see the Supporting Information.
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32
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For details, see the Supporting Information
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For details, see the Supporting Information.
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Since intermediate 6b is more stable because the Rh center is at the more stabilized benzylic position, we envisioned both 7a and 7b could be detected in the mechanism without radical chain reaction
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Since intermediate 6b is more stable because the Rh center is at the more stabilized benzylic position, we envisioned both 7a and 7b could be detected in the mechanism without radical chain reaction.
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44
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78650377395
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We presumed the chloro atom on 9b may come from the catalyst
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We presumed the chloro atom on 9b may come from the catalyst.
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