Aryl-halide versus aryl-aryl reductive elimination in Pt(IV)-phosphine complexes

Journal of the American Chemical Society

Volumn 128, Issue 27, 2006, Pages 8710-8711

  Yahav Levi, Anette ^a   Goldberg, Israel ^a   Vigalok, Arkadi ^a  

^a TEL AVIV UNIVERSITY   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

PHOSPHINE DERIVATIVE; PLATINUM DERIVATIVE;

ADDITION REACTION; ARTICLE; CHEMICAL BOND; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; OXIDATION; REDUCTION; THERMODYNAMICS;

CRYSTALLOGRAPHY, X-RAY; HYDROCARBONS, HALOGENATED; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOPLATINUM COMPOUNDS; OXIDATION-REDUCTION; PHOSPHINES; STEREOISOMERISM; TIME FACTORS;

EID: 33745952959     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja062166r     Document Type: Article

References (35)

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34. 2 cannot be excluded.
35. In the presence of TBA-Br, the biaryl formation from 6a,b might occur via the direct elimination or chelate ring-opening. Ion-pair rearrangement mechanisms also cannot be ruled out at this stage.