Mass spectrometry study and infrared spectroscopy of the complex between camphor and the two enantiomers of protonated alanine: The role of higher-energy conformers in the enantioselectivity of the dissociation rate constants

Chirality

Volumn 25, Issue 8, 2013, Pages 436-443

  Sen, Ananya ^a   Le Barbu Debus, Katia ^a   Scuderi, Debora ^b   Zehnacker Rentien, Anne ^a  

^a CNRS   (France)

^b UNIVERSITÉ PARIS SACLAY   (France)

Author keywords

collision induced dissociation; entropic effects; homochiral preference; IRMPD; mass spectrometry; vibrational spectroscopy

Indexed keywords

ALANINE; CAMPHOR;

ARTICLE; COLLISIONALLY ACTIVATED DISSOCIATION; CONTROLLED STUDY; DIASTEREOISOMER; DISSOCIATION; ENANTIOMER; ENANTIOSELECTIVITY; HYDROGEN BOND; INFRARED SPECTROSCOPY; MASS SPECTROMETRY; PRIORITY JOURNAL;

COLLISION-INDUCED DISSOCIATION; ENTROPIC EFFECTS; HOMOCHIRAL PREFERENCE; IRMPD; MASS SPECTROMETRY; VIBRATIONAL SPECTROSCOPY;

ALANINE; CAMPHOR; COORDINATION COMPLEXES; MASS SPECTROMETRY; MODELS, MOLECULAR; PROTONS; QUANTUM THEORY; SPECTROPHOTOMETRY, INFRARED; STEREOISOMERISM;

EID: 84880511506     PISSN: 08990042     EISSN: 1520636X     Source Type: Journal    
DOI: 10.1002/chir.22164     Document Type: Article

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