A strategy enabling enantioselective direct conjugate addition of inert aryl methane nucleophiles to enals with a chiral amine catalyst under mild conditions

Chemistry - A European Journal

Volumn 19, Issue 28, 2013, Pages 9147-9150

  Li, Tengfei ^a   Zhu, Jin ^a   Wu, Deyan ^a   Li, Xiangmin ^a   Wang, Sinan ^a   Li, Hao ^a   Li, Jian ^a   Wang, Wei ^a,b  

^a EAST CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

^b UNIVERSITY OF NEW MEXICO   (United States)

Author keywords

aryl methane; enals; iminium catalysis; Michael addition; organocatalysis

Indexed keywords

CONJUGATE ADDITION; ELECTRONWITHDRAWING; ENALS; ENANTIOSELECTIVE; ENANTIOSELECTIVE CONJUGATE ADDITION; IMINIUM CATALYSIS; MICHAEL ADDITIONS; ORGANOCATALYSIS;

ADDITION REACTIONS; CATALYSIS; CHEMICAL ACTIVATION; CHEMICAL COMPOUNDS; METHANE; NUCLEOPHILES; REACTION KINETICS;

ENANTIOSELECTIVITY;

AMINE; DRUG DERIVATIVE; METHANE;

ARTICLE; ARYL METHANE; CATALYSIS; ENALS; IMINIUM CATALYSIS; MICHAEL ADDITION; ORGANOCATALYSIS; STEREOISOMERISM; SYNTHESIS;

ARYL METHANE; ENALS; IMINIUM CATALYSIS; MICHAEL ADDITION; ORGANOCATALYSIS;

AMINES; CATALYSIS; METHANE; STEREOISOMERISM;

EID: 84879879491     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201300304     Document Type: Article

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