Towards organocatalytic polyketide synthases with diverse electrophile scope: Trifluoroethyl thioesters as nucleophiles in organocatalytic Michael reactions and beyond

Angewandte Chemie - International Edition

Volumn 47, Issue 24, 2008, Pages 4588-4591

  Alonso, Diego A ^a   Kitagaki, Shinji ^a   Utsumi, Naoto ^a   Barbas III, Carlos F ^a  

^a SCRIPPS RESEARCH INSTITUTE   (United States)

Author keywords

Amination; Asymmetric synthesis; Michael reaction; Organocatalysis; Polyketide synthases

Indexed keywords

ALDEHYDES; AMINES; CHEMICAL REACTIONS; ESTERS; ORGANIC COMPOUNDS; POLYMERS;

AMINATION; ASYMMETRIC SYNTHESIS; MICHAEL REACTION; ORGANOCATALYSIS; POLYKETIDE SYNTHASES;

NUCLEOPHILES;

BIOMIMETIC MATERIAL; ESTER; POLYKETIDE SYNTHASE; THIOL DERIVATIVE;

ARTICLE; CATALYSIS; CHEMISTRY; SYNTHESIS;

BIOMIMETIC MATERIALS; CATALYSIS; ESTERS; POLYKETIDE SYNTHASES; SULFHYDRYL COMPOUNDS;

EID: 47149096183     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200801088     Document Type: Article

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