Redox activity and two-step valence tautomerism in a family of dinuclear cobalt complexes with a spiroconjugated bis(dioxolene) ligand

Journal of the American Chemical Society

Volumn 135, Issue 22, 2013, Pages 8304-8323

  Alley, Kerwyn G ^a   Poneti, Giordano ^b,c   Robinson, Peter S D ^a   Nafady, Ayman ^d,g   Moubaraki, Boujemaa ^d   Aitken, Jade B ^e   Drew, Simon C ^a   Ritchie, Chris ^a   Abrahams, Brendan F ^a   Hocking, Rosalie K ^d   Murray, Keith S ^d   Bond, Alan M ^d   Harris, Hugh H ^f   Sorace, Lorenzo ^b   Boskovic, Colette ^a  

^a UNIVERSITY OF MELBOURNE   (Australia)

^b UNIVERSITY OF FLORENCE   (Italy)

^c GUGLIELMO MARCONI UNIVERSITY   (Italy)

^d MONASH UNIVERSITY   (Australia)

^e UNIVERSITY OF SYDNEY   (Australia)

^f UNIVERSITY OF ADELAIDE   (Australia)

^g KING SAUD UNIVERSITY   (Saudi Arabia)

Author keywords

[No Author keywords available]

Indexed keywords

DINUCLEAR COBALT COMPLEXES; ELECTRONIC INTERACTIONS; SINGLE CRYSTAL X-RAY DIFFRACTION; SPECTROSCOPIC STUDIES; TEMPERATURE DEPENDENCE; THERMALLY ACTIVATED; THERMALLY INDUCED; VIBRONIC COUPLING;

ALKYLATION; CARBON DIOXIDE; CHARGE DISTRIBUTION; COBALT; COMPLEXATION; LIGANDS; REDOX REACTIONS; SOLID SOLUTIONS; SPECTROSCOPIC ANALYSIS; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION;

COBALT COMPOUNDS;

AMINE; COBALT COMPLEX; PYRIDINE;

ARTICLE; CHEMICAL STRUCTURE; CONJUGATION; CRYSTAL STRUCTURE; ELECTRON SPIN RESONANCE; ISOLATION PROCEDURE; METHYLATION; OXIDATION REDUCTION REACTION; SOLID; SPIROCONJUGATION; SYNTHESIS; TAUTOMER; TEMPERATURE DEPENDENCE; THERMAL ANALYSIS; X RAY ABSORPTION SPECTROSCOPY; X RAY DIFFRACTION;

COBALT; DIOXOLANES; LIGANDS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; SPIRO COMPOUNDS;

EID: 84878657887     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja4021155     Document Type: Article

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