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Volumn 14, Issue 35, 2008, Pages 10915-10918

Complete direct and reverse optically induced valence tautomeric interconversion in a cobalt-dioxolene complex

Author keywords

Cobalt; Molecular switches; Photomagnetism; Semiquinone; Tautomerism

Indexed keywords

COBALT; FULLERENES; SPIN DYNAMICS; TOLUENE; TRANSITION METALS;

EID: 57149141526     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200801120     Document Type: Article
Times cited : (84)

References (41)
  • 2
    • 57149130899 scopus 로고    scopus 로고
    • M. Irie, (Guest Ed.): Chem. Rev. 2000, 100, 1683.
    • M. Irie, (Guest Ed.): Chem. Rev. 2000, 100, 1683.
  • 26
    • 57149134733 scopus 로고    scopus 로고
    • The reason for the poor refinement[33a] should be ascribed to the occurrence of a third phase, most probably a fraction of the all Co 11-SQ phase nucleating at low temperatures. This could explain the presence of intense h0l reflections which should be extinct due to the glide plane of the space group P21/c. A refinement in the lower symmetry group P21, did not lead to an improvement of the quality, as in agreement with the E statistics of SIR-97,[33b] which clearly indicate that the structure is centrosymmetric. The probable presence of another phase is also suggested by different reflections at the end of the refinement, featuring high F0 and low F c values. We are currently investigating this issue in more detail trying to assign a structure to this third phase
    • c values. We are currently investigating this issue in more detail trying to assign a structure to this third phase.
  • 28
    • 57149131748 scopus 로고    scopus 로고
    • [28a,d]
    • [28a,d]
  • 38
    • 57149135402 scopus 로고    scopus 로고
    • G. M. Sheldrick, SHELXL-97, University of Göttingen (Germany), 1997
    • a) G. M. Sheldrick, SHELXL-97, University of Göttingen (Germany), 1997


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.