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The spectra of a variety of oxo-and hydroxo-bridged metal dimers have been reported by several workers, but no interpretations beyond reference to the review of McCarthy and Güdel (ref 29) were generally given.
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Time-resolved emission spectroscopy has been used by several workers to help distinguish inequivalent sites in solid matrixes at low temperatures. See ref 29 for more details.
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85088621935
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2+ show electrochemical behavior associated with oxidation of the ligand.
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85088621122
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note
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B, a difference well within the detection limits of our experiment.
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66
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0542368849
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note
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The dielectric constant quoted in common references for a given solvent is usually the bulk, continuum dielectric. This may or may not be an accurate reflection of the effective dielectric of the first solvation shell about a given chromophore.
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67
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85088620593
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note
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III complexes.
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68
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0542392592
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note
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This band was fitted to two Gaussians using Peakfit (4.01 ed.; Jandel Scientific Software, Inc., 1995) in order to estimate the magnitude of the splitting between the two transitions.
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70
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0542392595
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note
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Variable solvent studies have been carried out on this complex as well, but no significant spectral shifting is observed.
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0542416265
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We are currently engaged in variable-temperature emission studies to further elucidate the details of the excited-state properties of this system and will be reporting the results of this work elsewhere.
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