Solvent effects on valence tautomerism: A comparison between the interconversion in solution and solid state

Solid State Sciences

Volumn 11, Issue 4, 2009, Pages 793-800

  Evangelio, Emi ^a   Rodriguez Blanco, Clara ^b   Coppel, Yannick ^d   Hendrickson, David N ^c   Sutter, Jean Pascal ^d   Campo, Javier ^b   Ruiz Molina, Daniel ^a,e  

^a UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

^b CSIC   (Spain)

^c UNIVERSITY OF CALIFORNIA   (United States)

^d LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

^e CATALAN INSTITUTE OF NANOSCIENCE AND NANOTECHNOLOGY ICN2   (Spain)

Author keywords

Bistability; Interconversion; Polymeric matrix; Solid state; Solvent effects; Valence tautomerism

Indexed keywords

POLYMERS; SOLID SOLUTIONS; SOLVENTS;

BISTABILITY; INTERCONVERSION; POLYMERIC MATRIX; SOLVENT EFFECTS; VALENCE TAUTOMERISM;

AMORPHOUS MATERIALS;

EID: 63249087098     PISSN: 12932558     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.solidstatesciences.2007.11.039     Document Type: Article

References (34)

1. Gütlich P., Garcia Y., and Woike T. Coord. Chem. Rev. 219-221 (2001) 839-879
2. Kahn O., and Launay J.P. Chemtronics 3 (1988) 140
3. Hauser A. Coord. Chem. Rev. 111 (1991) 275
4. For a review of VT, please see:. Evangelio E., and Ruiz-Molina D. Eur. J. Inorg. Chem. (2005) 2957
5. Gütlich P., and Dei A. Angew. Chem., Int. Ed. Engl. 36 (1997) 2734
6. Adams D.M., Dei A., Rheingold A.L., and Hendrickson D.N. Angew. Chem., Int. Ed. Engl. 32 (1993) 880
7. Adams D.M., Dei A., Rheingold A.L., and Hendrickson D.N. J. Am. Chem. Soc. 115 (1993) 8221
8. Jung O.-S., Lee D.H., Sohn Y.S., and Pierpont C.G. Inorg. Chem. 37 (1998) 5875
9. Jung O.-S., Jo D.H., Lee Y.A., Conklin B.J., and Pierpont C.G. Inorg. Chem. 36 (1997) 19
10. Jung O.-S., and Pierpont C.G. J. Am. Chem. Soc. 116 (1994) 2229
11. Roux C., Adams D.M., Itie J.P., Polian A., Hendrickson D.N., and Verdaguer M. Inorg. Chem. 35 (1996) 2846
12. Caneschi A., Dei A., De Biani F.F., Gütlich P., Ksenofontov V., Levchenko G., Hoefer A., and Renz F. Chem.-Eur. J. 7 (2001) 3926
13. Adams D.M., Li B., Simon J.D., and Hendrickson D.N. Angew. Chem., Int. Ed. Engl. 34 (1995) 1481
14. Larsen S.K., and Pierpont C.G. J. Am. Chem. Soc. 110 (1988) 1827
15. Caneschi A., Cornia A., and Dei A. Inorg. Chem. 37 (1998) 3419
16. Gentili P.L., Bussotti L., Righini R., Beni A., Bogani L., and Dei A. Chem. Phys. 314 (2005) 9
17. Cador O., Chabre F., Dei A., Sangregorio C., Van Slageren J., and Vaz M.G.F. Inorg. Chem. 42 (2003) 6432
18. Similar behavior was observed in its related oxidized form:. Ruiz-Molina D., Veciana J., Wurst K., Hendrickson D.N., and Rovira C. Inorg. Chem. 39 (2000) 617
19. For examples of other complexes exhibiting VT only in solution, please see:. Hendrickson D.N., and Pierpont C.G. Top. Curr. Chem. 234 (2004) 63-95
20. Bencini A., Caneschi A., Carbonera Ch., Dei A., Gatteschi D., Righini R., Sangregorio C., and Van Slageren J. J. Mol. Struct. 656 (2003) 141
21. Adams D.M., Noodleman L., and Hendrickson D.N. Inorg. Chem. 36 (1997) 3966
22. Adams D.M., and Hendrickson D.N. J. Am. Chem. Soc. 118 (1996) 11515
23. Ruiz D., Yoo J., Guzei I., Rheingold A.L., and Hendrickson D.N. Chem. Commun. (1998) 2089
24. Ruiz-Molina D., Zakharov L.N., Rheingold A.L., and Hendrickson D.N. J. Phys. Chem. Solids 65 (2004) 831
25. Evans D.F. J. Chem. Soc. (1959) 2003
26. Sur S.K. J. Magn. Reson. 82 (1989) 169
27. Values obtained from the reviews of
28. MeOH:. J. Chem. Eng. Data 39 (1994) 876
29. Acetone:. J. Chem. Eng. Data 42 (1997) 2
30. Toluene:. J. Chem. Eng. Data 44 (1999) 411
31. Chloroform:. J. Chem. Eng. Data 46 (2001) 2
32. Acetonitrile:. J. Chem. Eng. Data 47 (2002) 1037
33. c for the different solvents.
34. Ventosa N., Ruiz-Molina D., Sedo J., Tomas X., Andre B., Rovira C., and Veciana J. Chem.-Eur. J. 5 (1999) 12