Photo-induced valence tautomerism in Co complexes

Accounts of Chemical Research

Volumn 40, Issue 5, 2007, Pages 361-369

  Sato, Osamu ^a   Cui, Aili ^b   Matsuda, Ryotaro ^a   Tao, Jun ^c   Hayami, Shinya ^d  

^a KYUSHU UNIVERSITY   (Japan)

^b TSINGHUA UNIVERSITY   (China)

^c XIAMEN UNIVERSITY   (China)

^d HIROSHIMA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 38149102067     PISSN: 00014842     EISSN: None     Source Type: Journal    
DOI: 10.1021/ar600014m     Document Type: Article

References (48)

1. Feringa, B. L. Molecular Switches; VCH, New York, 2001.
2. Irie, M. Diarylethenes for Memories and Switches. Chem. Rev. 2000, 100, 1685-1716.
3. Yu, Y. L.; Ikeda, T. Alignment Modulation of Azobenzene-Containing Liquid Crystal Systems by Photochemical Reactions. J. Photochem. Photobiol., C 2004, 5, 247-265.
4. Hashimoto, K.; Ohkoshi, S. Design of Novel Magnets Using Prussian Blue Analogues. Philos. Trans. R. Soc. London, Ser. A 1999, 357, 2977-3003.
5. Sato, O.; Tao, J.; Zhang, Y. Z. Control of Magnetic Properties through Extermal Stimuli. Angew. Chem., Int. Ed. 2007, 46, 2152-2187.
6. Evangelio, E.; Ruiz-Molina, D. Valence Tautomerism: New Challenges for Electroactive Ligands. Eur. J. Inorg. Chem. 2005, 2957-2971.
7. Pierpont, C. G. Studies on Charge Distribution and Valence Tautomerism in Transition Metal Complexes of Catecholate and Semiquinonate Ligands. Coord. Chem. Rev. 2001, 216-217, 99-125.
8. Pierpont, C. G. Unique Properties of Transition Metal Quinone Complexes of the MQ3 Series. Coord. Chem. Rev. 2001, 219-221, 415-433.
9. Gütlich, P.; Dei, A. Valence Tautomeric Interconversion in Transition Metal 1,2-Benzoquinone Complexes. Angew. Chem. Int., Ed. Engl. 1997, 36, 2734-2736.
10. Shultz, D. A. Valence Tautomerism in Dioxolene Complexes of Cobalt. Magnetism: Molecules to Materials II; Miller, J. S., Drillon, M., Eds.; Wiley: New York, 2001; pp 281-306.
11. Dei, A.; Gatteschi, D.; Sangregorio, C.; Sorace, L. Quinonoid Metal Complexes: Toward Molecular Switches. Acc. Chem. Res. 2004, 37, 827-835.
12. Beni, A.; Carbonera, C.; Dei, A.; Letard, J. F.; Righini, R.; Sangregorio, C.; Sorace, L. Optically Induced Valence Tautomeric Interconversion in Cobalt Dioxolene Complexes. J. Braz. Chem. Soc. 2006, 17, 1522-1533.
13. Tao, J.; Maruyama, H.; Sato, O. Valence Tautomeric Transitions with Thermal Hysteresis Around Room Temperature and Photo-induced Effects Observed in a Cobalt-Tetraoxolene Complex. J. Am. Chem. Soc. 2006, 128, 1790-1791.
14. Liu, H. W.; Matsuda, K.; Gu, Z.-Z.; Takahashi, K.; Cui, A. L.; Nakajima, R.; Fujishima, A.; Sato, O. Reversible Valence Tautomerism Induced by a Single-Shot Laser Pulse in a Cobalt-Iron Prussian Blue Analog. Phys. Rev. Lett. 2003, 90, 167403.
15. Sato, O.; Iyoda, T.; Fujishima, A.; Hashimoto, K. Photoinduced Magnetization of a Cobalt Iron Cyanide. Science 1996, 272, 704-705.
16. 2] to [CO(III)(Catecholate) (Semiquinonate)] Valence-Tautomeric Conversion. J. Am. Chem. Soc. 1993, 115, 8221-8229.
17. 2, X = O, S, Se, and Te. Inorg. Chem. 1997, 36, 19-24.
18. Molina, D. R.; Veciana, J.; Wurst, K.; Hendrickson, D. N.; Rovira, C. Redox-Tunable Valence Tautomerism in a Cobalt Schiff Base Complex. Inorg. Chem. 2000, 39, 617-619.
19. Hendrickson, D. N.; Pierpont, C. G. Valence Tautomeric Transition Metal Complexes. Top. Curr. Chem. 2004, 234, 63-95.
20. Cador, O.; Dei, A.; Sangregorio, C. Isotopic Effects May Induce Cooperativity in Valence Tautomeric Transition. Chem. Commun. 2004, 652-653.
21. Cador, O.; Chabre, F.; Dei, A.; Sangregorio, C.; Slageren, J. V.; Vaz, M. G. F. Temperature-Induced Solid-State Valence Tautomeric Interconversion in Two Cobalt-Schiff Base Diquinone Complexes. Inorg. Chem. 2003, 42, 6432-6440.
22. Dolphin, D.; Niem, T.; Felton, R. H.; Fujita, I. Reversible Intramolecular Electron Transfer in an Oxidized Nickel Porphyrin. J. Am. Chem. Soc. 1975, 97, 5288-5290.
23. Kaim, W.; Schwederski, B. Cooperation of Metals with Electroactive Ligands of Biochemical Relevance: Beyond Metallophyrins. Pure Appl. Chem. 2004, 76, 351-364.
24. Saunders, M. Measurement of the Rate of Rearrangement of Bullvalene. Tetrahedron Lett. 1963, 1699-1702.
25. Manisse, N.; Chuche, J. New Valence Tautomerism-Thermal Rearrangement of cis-2-Vinyl-3-ethynyl 3-Membered Heterocycles. J. Am. Chem. Soc. 1977, 99, 1272-1273.
26. Buchanan, R. M.; Pierpont, C. G. Tautomeric Catecholate-Semi-quinone Interconversion via Metal-Ligand Electron Transfer. Stractual, Spectral, and Magnetic Properties of (3,5-Di-tert-butylcatecholato)-(3,5-di-tert- butylsemiquinone)(bipyridyl)cobalt(III), a Complex Containing Mixed-Valence Organic Ligands. J. Am. Chem. Soc. 1980, 102, 4951-4957.
27. Decurtins, S.; Gütlich, P.; Kohler, C. P.; Spiering, H.; Hauser, A. Light-Induced Excited Spin State Trapping in a Transition-Metal Complex - The Hexa-1-propyltetrazole-Iron(II) Tetrafluoroborate Spin-Crossover System. Chem. Phys. Lett. 1984, 105, 1-4.
28. Hayami, S.; Gu, Z.-Z.; Shiro, M.; Einaga, Y.; Fujishima, A.; Sato, O. First Observation of Light Induced Excited Spin State Trapping for an Iron(III) Complex. J. Am. Chem. Soc. 2000, 122, 7126-7127.
29. Gütlich, P.; Hauser, A.; Spiering, H. Thermal and Optical Switching of Iron(II) Complexes. Angew. Chem., Int. Ed. Engl. 1994, 33, 2024-2054.
30. Gütlich, P.; Garcia, Y.; Wolke, T. Photoswitchable Coordination Compounds. Coord. Chem. Rev. 2001, 219-221, 839-879.
31. III(3,5-DTBSQ)(3,5-DTBCAT)] Interconversion. Angew. Chem., Int. Ed. 1995, 34, 1481-1483.
32. Adams, D. M.; Hendrickson, D. N. Pulsed Laser Photolysis and Thermodynamics Studies of Intramolecular Electron Transfer in Valence Tautomeric Cobalt o-Quinone Complexes. J. Am. Chem. Soc. 1996, 118, 11515-11528.
33. 5Cl. J. Photochem. Photobiol., A 2004, 167, 69-73.
34. Cui, A.; Takahashi, K.; Fujishima, A.; Sato, O. Novel Co Complex with High Transformation Temperature of Valence Tautomerism. J. Photochem. Photobiol., A 2004, 161, 243-246.
35. Sato, O.; Hayami, S.; Gu, Z.-Z.; Takahashi, K.; Nakajima, R.; Fujishima, A. Photo-reversible Valence Tautomerism in a Co Compound. Phase Transitions 2002, 75, 779-785.
36. Sato, O.; Hayami, S.; Gu, Z.-Z.; Takahashi, K.; Nakajima, R.; Fujishima, A. Photo-induced Reverse Valence Tautomerism in a Metastable Co Compound. Chem. Phys. Lett. 2002, 355, 169-174.
37. Sato, O.; Hayami, S.; Gu, Z.-Z.; Takahashi, K.; Nakajima, R.; Seki, K.; Fujishima, A. Photo-induced Valence Tautomerism in a Co Compound. J. Photochem. Photobiol., A 2002, 149, 111-114.
38. Sato, O.; Hayami, S.; Gu, Z.-Z.; Seki, K.; Nakajima, R.; Fujishima, A. Photo-induced Long-Lived Intramolecular Electron Transfer in a Co Valence Tautomeric Complex. Chem. Lett. 2001, 874-875.
39. 3 Studied by X-ray Absorption Spectroscopy. Chem. Phys. Lett. 2001, 345, 272-276.
40. Varret, F.; Nogues, M.; Goujon, A. Photomagnetic Properties of Some Inorganic Solids. Magnetism: Molecules to Material; Miller, J. S., Drillon, M., Eds.; Wiley: New York, 2001; pp 257-295.
41. Carbonera, C.; Dei, A.; Letard, J. F.; Sangregorio, C.; Sorace, L. Thermally and Light-Induced Valence Tautomeric Transition in a Dinuclear Cobalt-Tetraoxolene Complex. Angew. Chem., Int. Ed. 2004, 43, 3136-3138.
42. Beni, A.; Dei, A.; Shultz, D.A.; Sorace, L. Ligand Design Modulates Photoinduced Properties of Cobalt-Dioxolene Valence Tautomers. Chem. Phys. Lett. 2006, 428, 400-404.
43. 2(phen)]. Inorg. Chem. 1997, 36, 3966.
44. 2(phen)] Interconversion. Inorg. Chem. 1996, 35, 2846-2852.
45. Hearns, N. G. R.; Korcok, J. L.; Paquette, M. M.; Preuss, K. E. Dinuclear Cobalt Bis(dioxolene) Complex Exhibiting Two Sequential Thermally Induced Valence Tautomeric Transitions. Inorg. Chem. 2006, 45, 8817-8819.
46. Bin-Salamon, S.; Brewer, S. H.; Depperman, E. C.; Franzen, S.; Kampf, J. W.; Kirk, M. L.; Kumar, R. K.; Lappi, S.; Peariso, K.; Preuss, K. E.; Shultz, D. A. Testing Bridge-Mediated Differences in Dinuclear Valence Tautomeric Behavior. Inorg. Chem, 2006, 45, 4461-4467.
47. Kahn, O.; Martinez, C. J. Spin-Transition Polymers: From Molecular Materials toward Memory Devices. Science 1998, 279, 44-48.
48. Spiering, H.; Kohlhaas, T.; Romstedt, H.; Hauser, A.; Bruns-Yilmaz, C.; Kusz, J.; Gutlich, P. Correlations of the Distribution of Spin States in Spin Crossover Compounds. Coord. Chem. Rev. 1999, 190-192, 629-647.