Unusual rearrangement and dearomatization reactions in Cu(I)-catalyzed atom transfer radical cyclizations from N-(1-phenylethyl)trichloroacetamides

Tetrahedron

Volumn 69, Issue 24, 2013, Pages 4883-4889

  Diaba, Faïza ^a   Montiel, Juan A ^a   Bonjoch, Josep ^a  

^a UNIVERSITY OF BARCELONA   (Spain)

Author keywords

Amides; ATRC; Memory of chirality; Nitrogen heterocycles; Radical reactions

Indexed keywords

2 CHLORO 6 (1,1 DICHLOROACETYL) 7 PHENYL 7 METHYL 6 AZABICYCLO[3.2.1]OCTANE 2 CARBONITRILE; 2,2 DICHLORO N (4 CYCANOCYCLOHEX 3 EN 1 YL) 2 PHENYLACETAMIDE; 4 (4,4 DICHLORO 1 METHYL 3,8 DIOXO 2 AZASPIRO[4.5]DECA 6,9 DIEN 2 YL)CYCLOHEX 1 ENECARBONITRILE; 4 (4,4,8 TRICHLORO 1 METHYL 3 OXO 2 AZASPIRO[4.5]DECA 6,9 DIEN 2 YL)CYCLOHEX 1 ENECARBONITRILE; 4,4' [4,4,4',4' TETRACHLORO 1,1' DIMETHYL 3,3' DIOXO (8,8'-BI2,2' DIAZASPIRO[4.5]DECANE) 6,6',9,9' TETRAENE 2,2' DIYL]BIS(CYCLOHEX 1 ENECARBONITRILE); 4,4,6 TRICHLORO 2 [1 PHENYLETHYL] 3 OXO 2 AZABICYCLO[3.3.1]NONANE 6 CARBONITRILE; 6 ACETYL 7 METHYL 7 PHENYL 6 AZABICYCLO[3.2.1]OCTANE 2 CARBONITRILE; ACETAMIDE DERIVATIVE; AMINE; COPPER CHLORIDE; HETEROCYCLIC COMPOUND; N (1 PHENYLETHYL)TRICHLOROACETAMIDE DERIVATIVE; NITRILE; TRISPYRIDYLMETHYLAMINE; UNCLASSIFIED DRUG;

AROMATIZATION; ARTICLE; ATOM TRANSFER RADICAL CYCLIZATION; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYSIS; CHEMICAL MODIFICATION; CHEMICAL STRUCTURE; CHIRALITY; CRYSTAL STRUCTURE; CYCLIZATION; DIASTEREOISOMER; DIMERIZATION; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; RADICAL REACTION; STEREOCHEMISTRY; SUBSTITUTION REACTION;

EID: 84877574743     PISSN: 00404020     EISSN: 14645416     Source Type: Journal    
DOI: 10.1016/j.tet.2013.04.042     Document Type: Article

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