Synthesis of 2,4-disubstituted piperidines via radical cyclization: Unexpected enhancement in diastereoselectivity with tris(trimethylsilyl)silane

Journal of Organic Chemistry

Volumn 71, Issue 14, 2006, Pages 5198-5207

  Gandon, Lucile A ^a   Russell, Alexander G ^a   Güveli, Tatyana ^a   Brodwolf, Angela E ^a   Kariuki, Benson M ^a   Spencer, Neil ^a   Snaith, John S ^a  

^a UNIVERSITY OF BIRMINGHAM   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

2, 4, DISUBSTITUTED PIPERIDINES; STEREOISOMER; TRIBUTYLTIN HYDRIDE; TRIS(TRIMETHYLSILYL)SILANE;

EXTRUSION; HYDRIDES; ISOMERS; MOLECULAR ORIENTATION; STEREOCHEMISTRY; SYNTHESIS (CHEMICAL);

SILANES;

PIPERIDINE DERIVATIVE; SILANE DERIVATIVE; TRIBUTYLTIN; TRIS(TRIMETHYLSILYL)SILANE; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLIZATION; DIASTEREOISOMER; GEOMETRY; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS;

CYCLIZATION; FREE RADICALS; MOLECULAR STRUCTURE; PIPERIDINES; SILANES; STEREOISOMERISM;

EID: 33745700322     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo060495w     Document Type: Article

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