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Volumn 42, Issue 16, 2013, Pages 5623-5626

Thioether-based anchimeric assistance for asymmetric coordination chemistry with ruthenium(ii) and osmium(ii)

Author keywords

[No Author keywords available]

Indexed keywords

ASYMMETRIC SYNTHESIS; BIPYRIDINES; CHIRAL AUXILIARIES; CO-ORDINATION CHEMISTRIES; HALF-SANDWICH COMPLEXES; OXAZOLINE RING; RUTHENIUM POLYPYRIDYL COMPLEXES; THIOETHER SUBSTITUENTS;

EID: 84877030832     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/c3dt00015j     Document Type: Article
Times cited : (7)

References (37)
  • 33
    • 77956207711 scopus 로고    scopus 로고
    • Note that according to the Cahn-Ingold-Prelog priority rules, the formal assignment of the absolute stereochemistry at the oxazoline moiety depends on the presence and location of the sulfur in the substituent at the 4-position, leading to the following formal assignments of the major stereoisomers of the formed ruthenium complexes: Λ-S (3a), Δ-R (3b-g), and Δ-S (3h)
    • L. Gong S. P. Mulcahy D. Devarajan K. Harms G. Frenking E. Meggers Inorg. Chem. 2010 49 7692
    • (2010) Inorg. Chem. , vol.49 , pp. 7692
    • Gong, L.1    Mulcahy, S.P.2    Devarajan, D.3    Harms, K.4    Frenking, G.5    Meggers, E.6
  • 37
    • 0042587565 scopus 로고
    • It is noteworthy that the auxiliary can be recovered afterwards. For example, when reacting Δ- 3b in MeCN (50 mM) with bpy (15 eq.) and TFA (5 eq.) in a sealed vial at 110 °C for 2 hours, the auxiliary 2b was isolated in a yield of 92% and an e.r. >99%
    • C. F. Liu N. C. Liu J. C. Bailar Inorg. Chem. 1964 3 1085
    • (1964) Inorg. Chem. , vol.3 , pp. 1085
    • Liu, C.F.1    Liu, N.C.2    Bailar, J.C.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.