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Volumn , Issue 19, 2011, Pages 2911-2926

Asymmetric synthesis of octahedral coordination complexes

Author keywords

Asymmetric synthesis; Chirality; Coordination modes; Ligand design; Octahedral complexes

Indexed keywords

CHELATION; LIGANDS; METAL COMPLEXES; STEREOSELECTIVITY; SYNTHESIS (CHEMICAL);

EID: 79959498654     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.201100327     Document Type: Review
Times cited : (101)

References (83)
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    • Werner already had the insight that octahedral coordination complexes are capable of possessing metal-centered optical activity earlier. See.
    • Werner already had the insight that octahedral coordination complexes are capable of possessing metal-centered optical activity earlier. See:, A. Werner, A. Vilmos, Z. Anorg. Allg. Chem. 1899, 21, 145-158.
    • (1899) Z. Anorg. Allg. Chem. , vol.21 , pp. 145-158
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  • 5
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    • For examples of asymmetric transformations catalyzed or induced by chiral octahedral metal complexes which solely possess metal centrochirality, see I. Sato, K. Kadowaki, Y. Ohgo, K. Soai, H. Ogino, Chem. Commun. 2001, 1022-1023.
    • (2001) Chem. Commun. , pp. 1022-1023
    • Sato, I.1    Kadowaki, K.2    Ohgo, Y.3    Soai, K.4    Ogino, H.5
  • 11
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    • For a comprehensive overview of chiral transition metal complexes and their applications, see:, Wiley, Chichester.
    • For a comprehensive overview of chiral transition metal complexes and their applications, see:, H. Amouri, M. Gruselle, Chirality in Transition Metal Chemistry, Wiley, Chichester, 2008.
    • (2008) Chirality in Transition Metal Chemistry
    • Amouri, H.1    Gruselle, M.2
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    • 178-180.
    • For previous reviews on stereoselective synthesis in coordination chemistry, see J.-L. Pierre, Coord. Chem. Rev. 1998, 178-180, 1183-1192.
    • (1998) Coord. Chem. Rev. , pp. 1183-1192
    • Pierre, J.-L.1
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    • III
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    • Liu, C.F.1    Liu, N.C.2
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    • For previous reports regarding ligand substitutions under retention of the metal-centered configuration in nonracemic chiral octahedral metal complexes, see also B. Bosnich, F. P. Dwyer, Aust. J. Chem. 1966, 19, 2229-2233.
    • (1966) Aust. J. Chem. , vol.19 , pp. 2229-2233
    • Bosnich, B.1    Dwyer, F.P.2
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    • For a related example in which the ligand substitution under retention of configuration occurs less efficiently, see.
    • For a related example in which the ligand substitution under retention of configuration occurs less efficiently, see:, S. D. Bergman, M. Kol, Inorg. Chem. 2005, 44, 1647-1654.
    • (2005) Inorg. Chem. , vol.44 , pp. 1647-1654
    • Bergman, S.D.1    Kol, M.2
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    • For dynamic transformation under thermodynamic control, see, for example.
    • For dynamic transformation under thermodynamic control, see, for example:, W. K. Lee, Y. S. Park, P. Beak, Acc. Chem. Res. 2009, 42, 224-234.
    • (2009) Acc. Chem. Res. , vol.42 , pp. 224-234
    • Lee, W.K.1    Park, Y.S.2    Beak, P.3
  • 83
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    • For a related system in which the carbon stereocenters within the spacer are not removed, see.
    • For a related system in which the carbon stereocenters within the spacer are not removed, see:, H. Weizman, J. Libman, A. Shanzer, J. Am. Chem. Soc. 1998, 120, 2188-2189.
    • (1998) J. Am. Chem. Soc. , vol.120 , pp. 2188-2189
    • Weizman, H.1    Libman, J.2    Shanzer, A.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.