Salt-free reducing reagent of bis(trimethylsilyl)cyclohexadiene mediates multielectron reduction of chloride complexes of W(VI) and W(IV)

Journal of the American Chemical Society

Volumn 135, Issue 16, 2013, Pages 5986-5989

  Tsurugi, Hayato ^a   Tanahashi, Hiromasa ^a   Nishiyama, Haruka ^a   Fegler, Waldemar ^b   Saito, Teruhiko ^a   Sauer, Andreas ^b   Okuda, Jun ^b   Mashima, Kazushi ^a  

^a OSAKA UNIVERSITY   (Japan)

^b RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

AZOPYRIDINE; CHLORIDE COMPLEXES; CYCLOHEXADIENES; MULTI-ELECTRON; REDOX-ACTIVE LIGAND; REDUCING REAGENTS; TRIMETHYLSILYL; TUNGSTEN COMPLEX;

CHLORINE COMPOUNDS; KETONES; LIGANDS; REDOX REACTIONS;

TUNGSTEN COMPOUNDS;

1 METHYL 3,6 BIS(TRIMETHYLSILYL)CYCLOHEXADIENE; 1,2 DIKETONE; 1,4 CYCLOHEXADIENE; ALPHA DIIMINE; AZOPYRIDINE DERIVATIVE; DIKETONE; IMINE; PYRIDINE DERIVATIVE; REDUCING AGENT; TOLUENE; TUNGSTEN DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; PROTON NUCLEAR MAGNETIC RESONANCE; REDUCTION; ROOM TEMPERATURE; SYNTHESIS; X RAY DIFFRACTION;

EID: 84876709004     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja401589a     Document Type: Article

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