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Volumn 131, Issue 15, 2009, Pages 5370-5371

New tantalum ligand-free catalyst system for highly selective trimerization of ethylene affording 1-hexene: New evidence of a metallacycle mechanism

Author keywords

[No Author keywords available]

Indexed keywords

1-HEXENE; CATALYST SYSTEM; CATALYTIC ACTIVITY; HEXADIENE; LIGAND-FREE; LOW-VALENT; METALLACYCLE; REDUCING REAGENTS; TRIMERIZATION; TRIMETHYLSILYL;

EID: 67849121575     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja8100837     Document Type: Article
Times cited : (101)

References (39)
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    • Some references for selective ethylene trimerization. For Cr-based catalysts, see: (a, U.S. Patent 4,668,838 Union Carbide, 1987
    • Some references for selective ethylene trimerization. For Cr-based catalysts, see: (a) Briggs, J. R. U.S. Patent 4,668,838 (Union Carbide), 1987.
    • Briggs, J.R.1
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    • EP 416 403 Phillips Petroleum
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    • EP 699 648 Sumitomo Chemical
    • (c) Tamura, M.; Iwanaga, K.; Ito, Y. EP 699 648 (Sumitomo Chemical), 1995.
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    • Blann, K.; Bollmann, A.; Dixon, J. T.; Hess, F. M.; Killian, E.; Maumela, H.; Morgan, D. H.; Neveling, A.; Otto, S.; Overett, M. J. Chem. Commun. 2005, 620. For Ti-based catalysts, see: (k) Deckers, P. J. W.; Hessen, B.; Teuben, J. H. Angew. Chem., Int. Ed. 2001, 40, 2516.
    • (j) Blann, K.; Bollmann, A.; Dixon, J. T.; Hess, F. M.; Killian, E.; Maumela, H.; Morgan, D. H.; Neveling, A.; Otto, S.; Overett, M. J. Chem. Commun. 2005, 620. For Ti-based catalysts, see: (k) Deckers, P. J. W.; Hessen, B.; Teuben, J. H. Angew. Chem., Int. Ed. 2001, 40, 2516.
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    • Wu, T.; Qian, Y.; Huang, J. J. Mol. Catal. A: Chem. 2004, 214, 227. For Ta-based catalyst, see: (m) Andes, C.; Harkins, S. B.; Murtuza, S.; Oyler, K.; Sen, A. J. Am. Chem. Soc. 2001, 123, 7423.
    • (l) Wu, T.; Qian, Y.; Huang, J. J. Mol. Catal. A: Chem. 2004, 214, 227. For Ta-based catalyst, see: (m) Andes, C.; Harkins, S. B.; Murtuza, S.; Oyler, K.; Sen, A. J. Am. Chem. Soc. 2001, 123, 7423.
  • 16
    • 8844261118 scopus 로고    scopus 로고
    • Some references for selective ethylene tetramerization: (a) Bollmann, A.; Blann, K.; Dixon, J. T.; Hess, F. M.; Killian, E.; Maumela, H.; McGuinness, D. S.; Morgan, D. H.; Neveling, A.; Otto, S.; Overett, M.; Slawin, A. M. Z.; Wasserscheid, P.; Kuhlmann, S. J. Am. Chem. Soc. 2004, 126, 14712.
    • Some references for selective ethylene tetramerization: (a) Bollmann, A.; Blann, K.; Dixon, J. T.; Hess, F. M.; Killian, E.; Maumela, H.; McGuinness, D. S.; Morgan, D. H.; Neveling, A.; Otto, S.; Overett, M.; Slawin, A. M. Z.; Wasserscheid, P.; Kuhlmann, S. J. Am. Chem. Soc. 2004, 126, 14712.
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    • World Patent WO 2004056478
    • (b) World Patent WO 2004056478, 2004.
    • (2004)
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    • World Patent WO 2004056479
    • (c) World Patent WO 2004056479, 2004.
    • (2004)
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    • See e.g. (a) Agapie, T.; Schofer, S. J.; Labinger, J. A.; Bercaw, J. E. J. Am. Chem. Soc. 2004, 126, 1304.
    • See e.g. (a) Agapie, T.; Schofer, S. J.; Labinger, J. A.; Bercaw, J. E. J. Am. Chem. Soc. 2004, 126, 1304.
  • 28
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    • Experimental details are given in the Supporting Information
    • Experimental details are given in the Supporting Information.
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    • See e.g.: (a) Arney, D. J.; Wexler, P. A.; Wigley, D. E. Organometallics 1990, 9, 1282.
    • See e.g.: (a) Arney, D. J.; Wexler, P. A.; Wigley, D. E. Organometallics 1990, 9, 1282.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.