Molybdenum-catalyzed transformation of molecular dinitrogen into silylamine: Experimental and DFT study on the remarkable role of ferrocenyldiphosphine ligands

Journal of the American Chemical Society

Volumn 133, Issue 10, 2011, Pages 3498-3506

  Tanaka, Hiromasa ^a   Sasada, Akira ^a   Kouno, Tomohisa ^a   Yuki, Masahiro ^b   Miyake, Yoshihiro ^b   Nakanishi, Haruyuki ^c   Nishibayashi, Yoshiaki ^b   Yoshizawa, Kazunari ^a  

^a KYUSHU UNIVERSITY   (Japan)

^b UNIVERSITY OF TOKYO   (Japan)

^c TOYOTA MOTOR CORPORATION   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ACID TREATMENTS; ACTIVE SPECIES; CATALYTIC CYCLES; CO-LIGANDS; DENSITY FUNCTIONAL THEORY CALCULATIONS; DFT STUDY; DINITROGEN; DINITROGEN COMPLEXES; FE COMPLEXES; FERROCENES; MOLYBDENUM COMPLEX; ROOM TEMPERATURE; SILYLAMINE; TURNOVER NUMBER;

CATALYSIS; DENSITY FUNCTIONAL THEORY; IRON COMPOUNDS; LIGANDS; MOLYBDENUM; SODIUM;

MOLYBDENUM COMPOUNDS;

AMINE; FERROCENE DERIVATIVE; HYDRAZIDE DERIVATIVE; IRON COMPLEX; MOLYBDENUM; NITROGEN DERIVATIVE; PHOSPHINE DERIVATIVE; PHOSPHORUS; SILICON DERIVATIVE;

ADDITION REACTION; ARTICLE; BIOTRANSFORMATION; CATALYSIS; CATALYST; DENSITY FUNCTIONAL THEORY; DISSOCIATION; EXPERIMENTAL STUDY; QUANTUM CHEMISTRY;

EID: 79952612539     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja109181n     Document Type: Article

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