Separating the initial growth rate from the rate of deactivation in the growth kinetics of multi-walled carbon nanotubes from ethene over a cobalt-based bulk catalyst in a fixed-bed reactor

Carbon

Volumn 58, Issue , 2013, Pages 107-115

  Becker, Michael J ^a   Xia, Wei ^a   Xie, Kunpeng ^a   Dittmer, Arne ^a   Voelskow, Kristian ^b   Turek, Thomas ^b   Muhler, Martin ^a  

^a RUHR UNIVERSITY BOCHUM   (Germany)

^b CLAUSTHAL UNIVERSITY OF TECHNOLOGY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

BULK CATALYSTS; CARBON SOURCE; COBALT-BASED; ETHENE CONCENTRATIONS; FIXED-BED REACTORS; KINETIC MODELS; MEAN LIFETIME; TIME ON STREAMS;

CARBON; CATALYST DEACTIVATION; CHEMICAL REACTORS; GROWTH RATE; GROWTH TEMPERATURE; KINETICS;

ETHYLENE;

EID: 84876412038     PISSN: 00086223     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.carbon.2013.02.038     Document Type: Article

References (40)

1. J. Robertson Realistic applications of CNTs Mater Today 7 10 2004 46 52
2. R. Andrews, D. Jacques, D. Qian, and T. Rantell Multiwall carbon nanotubes: synthesis and application Acc Chem Res 35 12 2002 1008 1017
3. C. Jin, T.C. Nagaiah, W. Xia, B. Spliethoff, S. Wang, and M. Bron Metal-free and electrocatalytically active nitrogen-doped carbon nanotubes synthesized by coating with polyaniline Nanoscale 2 6 2010 981 987
4. Q. Zhang, J.-Q. Huang, M.-Q. Zhao, W.-Z. Qian, and F. Wei Carbon nanotube mass production: principles and processes ChemSusChem 4 7 2011 864 889
5. C.H. See, and A.T. Harris A review of carbon nanotube synthesis via fluidized-bed chemical vapor deposition Ind Eng Chem Res 46 4 2007 997 1012
6. M. Bierdel, S. Buchholz, V. Michele, L. Mleczko, R. Rudolf, and M. Voetz Industrial production of multi-walled carbon nanotubes Phys Status Solidi 244 11 2007 3939 3943
7. J.-P. Tessonnier, M. Becker, W. Xia, F. Girgsdies, R. Blume, and L. Yao Spinel-type cobalt-manganese-based mixed oxide as sacrificial catalyst for the high-yield production of homogeneous carbon nanotubes ChemCat Chem 2 12 2010 1559 1561
8. R. Brukh, and S. Mitra Mechanism of carbon nanotube growth by CVD Chem Phys Lett 424 1-3 2006 126 132
9. Y. Yun, V. Shanov, Y. Tu, S. Subramaniam, and M.J. Schulz Growth mechanism of long aligned multiwall carbon nanotube arrays by water-assisted chemical vapor deposition J Phys Chem B 110 47 2006 23920 23925
10. 5-catalyzed carbon nanotubes grown by chemical vapor deposition J Electrochem Soc 153 4 2006 J21 J25
11. Q. Zhang, J. Huang, M. Zhao, W. Qian, Y. Wang, and F. Wei Radial growth of vertically aligned carbon nanotube arrays from ethylene on ceramic spheres Carbon 46 8 2008 1152 1158
12. L. Zhu, D.W. Hess, and C.-P. Wong Monitoring carbon nanotube growth by formation of nanotube stacks and investigation of the diffusion-controlled kinetics J Phys Chem B 110 11 2006 5445 5449
13. D. Futaba, K. Hata, T. Yamada, K. Mizuno, M. Yumura, and S. Iijima Kinetics of water-assisted single-walled carbon nanotube synthesis revealed by a time-evolution analysis Phys Rev Lett 95 5 2005 0561041 0561044
14. K. Hata, D.N. Futaba, K. Mizuno, T. Namai, M. Yumura, and S. Iijima Water-assisted highly efficient synthesis of impurity-free single-walled carbon nanotubes Science 306 5700 2004 1362 1364
15. N. Latorre, E. Romeo, F. Cazana, T. Ubieto, C. Royo, and J.I. Villacampa Carbon nanotube growth by catalytic chemical vapor deposition: a phenomenological kinetic model J Phys Chem C 114 11 2010 4773 4782
16. D.H. Lee, S.O. Kim, and W.J. Lee Growth kinetics of wall-number controlled carbon nanotube arrays J Phys Chem C 114 8 2010 3454 3458
17. M. Jönsson, O.A. Nerushev, and E.E.B. Campbell In situ growth rate measurements during plasma-enhanced chemical vapor deposition of vertically aligned multiwall carbon nanotube films Nanotechnology 18 30 2007 3057021 3057025
18. A.A. Puretzky, D.B. Geohegan, S. Jesse, I.N. Ivanov, and G. Eres In situ measurements and modeling of carbon nanotube array growth kinetics during chemical vapor deposition Appl Phys A 81 2 2005 223 240
19. M. Perez-Cabero, E. Romeo, C. Royo, A. Monzon, A. Guerrero-Ruiz, and I. Rodriguez-Ramos Growing mechanism of CNTs: a kinetic approach J Catal 224 1 2004 197 205
20. J.-W. Snoeck, G.F. Froment, and M. Fowles Filamentous carbon formation and gasification: thermodynamics, driving force, nucleation, and steady-state growth J Catal 169 1 1997 240 249
21. V. Svrcek, I. Kleps, F. Cracioniou, J.L. Paillaud, T. Dintzer, and B. Louis Monitoring the chemical vapor deposition growth of multi-walled carbon nanotubes by tapered element oscillating microbalance J Chem Phys 124 18 2006 184705 184717
22. 3 catalyst Carbon 45 6 2007 1167 1175
23. A. Monzon, G. Lolli, S. Cosma, S.B. Mohamed, and D.E. Resasco Kinetic modeling of the SWNT growth by CO disproportionation on CoMo catalysts J Nanosci Nanotechnol 8 11 2008 6141 6152
24. C. Gommes, S. Blacher, Ch. Bossuot, P. Marchot, J.B. Nagy, and J.P. Pirard Influence of the operating conditions on the production rate of multi-walled carbon nanotubes in a CVD reactor Carbon 42 8-9 2004 1473 1482
25. A.M. Cassell, J.A. Raymakers, J. Kong, and H. Dai Large scale CVD synthesis of single-walled carbon nanotubes J Phys Chem B 103 31 1999 6484 6492
26. R. Philippe, P. Serp, P. Kalck, Y. Kihn, S. Bordere, and D. Plee Kinetic study of carbon nanotubes synthesis by fluidized-bed chemical vapor deposition AIChE J 55 2 2009 450 464
27. P.-L. Chen, J.-K. Chang, C.-T. Kuo, and F.-M. Pan Field emission of carbon nanotubes on anodic aluminum oxide template with controlled tube density Appl Phys Lett 86 12 2005 1231111 1231114
28. O.F.-K. Schlüter, B.I. Wehner, D. Hu, W. Xia, T. Quandt, and G. Marginean The iron-catalyzed synthesis of carbon microfibers from methane: the influence of growth conditions on conversion, selectivity, morphology and structure of the fibers Appl Catal A 274 1-2 2004 71 77
29. S. Helveg, C. Lopez-Cartes, J. Sehested, P.L. Hansen, B.S. Clausen, and J.R. Rostrup-Nielsen Atomic-scale imaging of carbon nanofiber growth Nature 427 6973 2004 426 429
30. R.T.K. Baker, M.A. Barber, P.S. Harris, F.S. Feates, and R.J. White Nucleation and growth of carbon deposits from the nickel catalyzed decomposition of acetylene J Catal 26 1 1972 51 62
31. J.A. Moulijn, A.E. van Diepen, and F. Kapteijn Catalyst deactivation: is it predictable? Appl Catal A 212 1-2 2001 3 16
32. M.J. Becker, W. Xia, J.-P. Tessonnier, R. Blume, L. Yao, and R. Schlögl Optimizing the synthesis of cobalt-based catalysts for the selective growth of multiwalled carbon nanotubes under industrially relevant conditions Carbon 49 15 2011 5253 5264
33. K.P. de Jong, and J.W. Geus Carbon nanofibers: catalytic synthesis and applications Catal Rev Sci Eng 42 4 2000 481 510
34. Y. Hao, Z. Qunfeng, W. Fei, Q. Weizhon, and L. Guohua Agglomerated CNTs synthesized in a fluidized-bed reactor: agglomerate structure and formation mechanism Carbon 41 14 2003 2855 2863
35. C.H. Bartholomew Mechanisms of catalyst deactivation Appl Catal A 212 1-2 2001 17 60
36. C.H. Bartholomew Carbon deposition in steam reforming and methanation Catal Rev Sci Eng 24 1 1982 67 112
37. J.G. McCarty, and H. Wise Hydrogenation of surface carbon on alumina-supported nickel J Catal 57 3 1979 406 416
38. W. Lee, and C.H. Bartholomew Multiple reaction states in CO hydrogenation on alumina-supported cobalt catalysts J Catal 120 1 1989 256 271
39. M. Chhowalla, K.B.K. Teo, C. Ducati, N.L. Rupesinghe, G.A.J. Amaratunga, and A.C. Ferrari Growth process conditions of vertically aligned carbon nanotubes using plasma enhanced chemical vapor deposition J Appl Phys 90 10 2001 5308 5317
40. V. Ivanov, A. Fonseca, J.B. Nagy, A. Lucas, P. Lambin, and D. Bernaerts Catalytic production and purification of nanotubules having fullerene-scale diameters Carbon 33 12 1995 1727 1738