Kinetic modeling of the SWNT growth by CO disproportionation on CoMo catalysts

Journal of Nanoscience and Nanotechnology

Volumn 8, Issue 11, 2008, Pages 6141-6152

  Monzon, A ^a,b   Lolli, G ^a   Cosma, S ^a   Mohamed, S B ^a   Resasco, D E ^a  

^a University of Oklahoma   (United States)

^b UNIVERSITY OF ZARAGOZA   (Spain)

Author keywords

Co Mo catalysts; CoMoCAT process; Kinetic modeling; SWNT growth

Indexed keywords

ACTIVE SITES; CARBON CONCENTRATIONS; CARBON DEPOSITIONS; CATALYST ACTIVATIONS; CO DISPROPORTIONATION; CO-MO CATALYSTS; COMOCAT PROCESS; DIRECT MEASUREMENTS; DISPROPORTIONATION; DRIVING FORCES; EXPERIMENTAL DATUMS; FLOW REACTORS; FUNCTION OF TIMES; GROWTH TERMINATIONS; IN-SITU; KINETIC MODELING; KINETIC MODELS; METAL PARTICLES; PHYSICAL PARAMETERS; SURFACE FUGACITIES; SWNT GROWTH; TYPICAL VALUES;

CARBON CLUSTERS; CARBON DIOXIDE; CARBON MONOXIDE; CARBON NANOTUBES; CATALYSIS; CATALYST DEACTIVATION; CATALYSTS; COBALT; COBALT COMPOUNDS; GROWTH (MATERIALS); IGNEOUS ROCKS; KINETIC THEORY; MATHEMATICAL MODELS; MOLYBDENUM; NANOTUBES; SULFUR COMPOUNDS; SURFACE DIFFUSION;

SINGLE-WALLED CARBON NANOTUBES (SWCN);

CARBON DIOXIDE; CARBON NANOTUBE; COBALT; MOLYBDENUM;

ARTICLE; CHEMICAL MODEL; CHEMISTRY; COMPUTER SIMULATION; CONFORMATION; CRYSTALLIZATION; KINETICS; MACROMOLECULE; MATERIALS TESTING; METHODOLOGY; NANOTECHNOLOGY; PARTICLE SIZE; SURFACE PROPERTY; ULTRASTRUCTURE;

CARBON DIOXIDE; COBALT; COMPUTER SIMULATION; CRYSTALLIZATION; KINETICS; MACROMOLECULAR SUBSTANCES; MATERIALS TESTING; MODELS, CHEMICAL; MOLECULAR CONFORMATION; MOLYBDENUM; NANOTECHNOLOGY; NANOTUBES, CARBON; PARTICLE SIZE; SURFACE PROPERTIES;

EID: 58149296348     PISSN: 15334880     EISSN: None     Source Type: Journal    
DOI: 10.1166/jnn.2008.SW21     Document Type: Article

References (46)

1. B. Kitiyanan, W. E. Alvarez, J. H. Harwell, and D. E. Resasco, Chem. Phys. Lett. 317, 497 (2000).
2. D. E. Resasco, W. E. Alvarez, F. Pompeo, L. Balzano, J. E. Herrera, B. Kitiyanan, and A. Borgna, J. Nanopart. Res. 4, 131 (2002).
3. D. E. Resasco, J. E. Herrera, and L. Balzano, J. Nanosci. Nanotechnol. 4, 398 (2004).
4. D. E. Resasco, J. E. Herrera, and L. Balzano, J. Nanosci. Nanotechnol. 3, 1 (2003).
5. J. E. Herrera, L. Balzano, A. Borgna, W. E. Alvarez, and D. E. Resasco, J. Catal. 204, 129 (2001).
6. L. Zhang, L. Balzano, and D. E. Resasco, J. Phys. Chem. B 109, 14375 (2005).
7. W. E. Alvarez, B. Kitiyanan, A. Borgna, and D. E. Resasco, Carbon 39, 547 (2001).
8. J. E. Herrera and D. E. Resasco, J. Catal. 221, 354 (2004).
9. G. Lolli, L. A. Zhang, L. Balzano, N. Sakulchaicharoen, Y. Q. Tan, and D. E. Resasco J. Phys. Chem. B 110, 2108 (2006).
10. S. M. Bachilo, L. Balzano, J. E. Herrera, F. Pompeo, D. E. Resasco, and R. B. Weisman, J. Am. Chem. Soc. 125, 11186 (2003).
11. Z. Zhu, J. Crochet, M. S. Arnold, M. C. Hersam, H. Ulbricht, D. Resasco, and T. Hertel, J. Phys. Chem. C 111, 3831 (2007).
12. A. Jorio, A. P. Santos, H. B. Ribeiro, C. Fantini, M. Souza, J. P. M. Vieira, C. A. Furtado, J. Jiang, R. Saito, L. Balzano, D. E. Resasco, and M. A. Pimenta, Phys. Rev. B 72, Art. No. 075207 (2005).
13. S. G. Chou, H. B. Ribeiro, E. B. Barros, A. P. Santos, D. Nezich, G. G. Samsonidze, C. Fantini, M. A. Pimenta, A. Jorio, F. Plentz Filho, M. S. Dresselhaus, G. Dresselhaus, R. Saito, M. Zheng, G. B. Onoa, E. D. Semke, A. K. Swan, M. S. Unluj, and B. B. Goldberg, Chem. Phys. Lett. 397, 296 (2004).
14. Y. Maeda, M. Kanda, M. Hashimoto, T. Hasegawa, S. Kimura, Y. F. Lian, T. Wakahara, T. Akasaka, S. Kazaoui, N. Minami, T. Okazaki, Y. Hayamizu, K. Hata, J. Lu, and S. Nagase, J. Am. Chem. Soc. 128, 12239 (2006).
15. M. Zheng and E. D. Semke, J. Am. Chem. Soc. 129, 6084 (2007).
16. Y. Maeda, M. Kanda, M. Hashimoto, T. Hasegawa, S. Kimura, Y. Lian, T. Wakahara, T. Akasaka, S. Kazaoui, N. Minami, T. Okazaki, Y. Hayamizu, K. Hata, J. Lu, and S. Nagase, J. Am. Chem. Soc. 128, 12239 (2006).
17. N. Nair, M. L. Usrey, W. J. Kim, R. D. Braatz, and M. S. Strano, Anal. Chem. 78, 7689 (2006).
18. N. Nair, M. L. Usrey, W. J. Kim, R. D. Braatz, and M. S. Strano, Anal. Chem. 78, 7689 (2006).
19. P. B. Balbuena, J. Zhao, S. P. Huang, Y. X. Wang, N. Sakulchaicharoen, and D. E. Resasco, J. Nanosci. Nanotechnol. 6, 1247 (2006).
20. E. Lamouroux, P. Serp, and P. Kalck, Catal. Rev. 49, 341 (2007).
21. J. Zhao and P. B. Balbuena, J. Phys. Chem. A 110, 2771 (2006).
22. F. Ding, A. Rosén, and K. Bolton, AIP Conf. Proc. 723, 364 (2004).
23. F. Ding, A. Rosén, and K. Bolton, Comp. Mater. Sci. 35, 243 (2006).
24. J.Zhao, A. Martinez-Limia, and P. B. Balbuena, Nanotechnology 16, S575 (2005).
25. K. Bolton, F. Ding, and A. J. Rosen, J. Nanosci. Nanotechnol. 6, 1211 (2006).
26. T. Liliedahl, K. Sjöström, and L. P. Wiktorsson, AIChE J. 37, 1415 (1991).
27. E. G. Prout and F. C. Tompkins, Trans. Faraday Sot. 40, 488 (1944).
28. B. Delmon, Bull. Soc. Chim. France 590 (1961).
29. T. V. Hiep and S. Kaliaguine, Chem. Eng. Sci. 28, 195 (1973).
30. J. I. Villacampa, C. Royo, E. Romeo, J. A. Montoya, P. Del Angel, and A. Monzón, Appl. Catal. A: Gen. 252, 363 (2003).
31. M. Pérez-Cabero, E. Romeo, C. Royo, A. Monzón, A. Guerrero-Ruíz, and I. Rodríguez-Ramos, J. Catal. 224, 197 (2004).
32. D. Farcasiu, J. O. Li, and A. Kogelbauer, J. Molec. Catal. A 124, 67 (1997).
33. E. L. Agorreta, J. A. Peña, J. Santamaria, and A. Monzón, Ind. Eng. Chem. Res. 30, 111 (1991).
34. P. Mcallister and E. E. Wolf, J. Catal. 138, 129 (1992).
35. M. Morbidelli, A. Servida, and A. Varma, Ind. Eng. Chem. Fund. 21, 278 (1982).
36. A. L. Pozzi and H. F. Rase, Ind. Eng. Chem. 50, 1075 (1958).
37. J. Corella, J. Adanez, and A. Monzón, Ind. Eng. Chem. Res. 27, 375 (1988).
38. A. Borgna, T. F. Garetto, A. Monzón, and C. R. Apesteguía, J. Catal. 146, 69 (1994).
39. J. W. Snoeck, G. F. Froment, and M. Fowles, Ind. & Eng. Chem. Res. 41, 4252 (2002).
40. S. Huang, M. Woodson, R. Smalley, and J. Liu, Nano Lett. 4, 1025 (2004).
41. L. X. Zheng, M. J. O'Connell, S. K. Doom, X. Z. Liao, Y. H. Zhao, E. A. Akhadov, M. A. Hoffbauer, B. J. Roop, Q. X. Jial, R. C. Dye, D. E. Peterson, S. M. Huang, J. Liu, and Y. T. Zhu, Nat. Mater. 3, 673 (2004).
42. K. Hata, D. N. Futaba, K. Mizuno, T. Namai, M. Yumura, and S. Iijima, Science 306, 1362 (2004).
43. L. Zhang, Y. Tan, and D. E. Resasco, Chem. Phys. Lett. 422, 198 (2006).
44. D. N. Futaba, K. Hata, T. Yamada, K. Mizuno, M. Yumura, and S. Iijima, Phys. Rev. Lett. 95, 056104 (2005).
45. D. N. Futaba, K. Hata, T. Namai, T. Yamada, K. Mizuno, Y. Hayamizu, M. Yumura, and S. Iijima, J. Phys. Chem. B 110, 8035 (2006).
46. L. Zhang, Z. Li, Y. Tan, G. Lolli, N. Sakulchaicharoen, F. G. Requejo, B. S. Mun, and D. E. Resasco, Chem. Mat. 18, 5624 (2006).