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Volumn 42, Issue 12, 2013, Pages 4197-4207

Platinum(ii) and platinum(iv) complexes stabilized by abnormal/mesoionic C4-bound dicarbenes

Author keywords

[No Author keywords available]

Indexed keywords

LIGANDS; PLATINUM; SOLVENTS; STEREOCHEMISTRY; SYNTHESIS (CHEMICAL);

EID: 84874424288     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/c2dt32423g     Document Type: Article
Times cited : (36)

References (127)
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    • C2-H bond activation in imidazolium salts with a basic platinum precursor salt has precedents
    • T. Kosterke T. Pape F. E. Hahn J. Am. Chem. Soc. 2011 133 2112
    • (2011) J. Am. Chem. Soc. , vol.133 , pp. 2112
    • Kosterke, T.1    Pape, T.2    Hahn, F.E.3
  • 73
    • 55349085466 scopus 로고    scopus 로고
    • Formally, the platinated heterocyclic carbon should be labeled C5. For the sake of consistency, the nomenclature established in previous work will be used (see references cited in ref. 9) and N1 is bearing the modular wingtip group (Me, Hex) and C4 is bound to the platinum center
    • M. Heckenroth E. Kluser A. Neels M. Albrecht Dalton Trans. 2008 6242
    • (2008) Dalton Trans. , pp. 6242
    • Heckenroth, M.1    Kluser, E.2    Neels, A.3    Albrecht, M.4
  • 79
    • 80052511143 scopus 로고    scopus 로고
    • Addition of HCl (5 equiv.) to 2a yielded a 3:2 mixture of 2a′ and the platinum(iv) complex 4a, implying oxidative addition of HCl or transient formation of Cl2 (see below for details)
    • A. Poulain M. Iglesias M. Albrecht Curr. Org. Chem. 2011 15 3325
    • (2011) Curr. Org. Chem. , vol.15 , pp. 3325
    • Poulain, A.1    Iglesias, M.2    Albrecht, M.3
  • 91
    • 33750972045 scopus 로고    scopus 로고
    • A search in the Cambridge Crystallographic Database revealed 13 structures, containing a cationic four-coordinate Pt(ii) center with mutually cis-coordinated κS-DMSO and Cl-
    • S. Ahrens T. Strassner Inorg. Chim. Acta 2006 359 4789
    • (2006) Inorg. Chim. Acta , vol.359 , pp. 4789
    • Ahrens, S.1    Strassner, T.2
  • 107
    • 8344230652 scopus 로고    scopus 로고
    • tegration of C5-resonances at δH 7.23, 7.10, 7.02 and 6.89 ppm, respectively, indicates a 0.08:0.44:1:0.33 ratio. Attempts to separate these species have been unsuccessful
    • L. M. Rendina R. J. Puddephatt Chem. Rev. 1997 97 1735
    • (1997) Chem. Rev. , vol.97 , pp. 1735
    • Rendina, L.M.1    Puddephatt, R.J.2
  • 125
    • 0001792356 scopus 로고    scopus 로고
    • Program CrysalisPro Version 1.171.33.55, Oxford Diffraction Limited, 2010. Analytical numeric absorption corrections using a multifaceted crystal model were based on expressions derived by Clark and Reid
    • A. L. Spek J. Appl. Crystallogr. 2003 36 7
    • (2003) J. Appl. Crystallogr. , vol.36 , pp. 7
    • Spek, A.L.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.