trans-Chloromethylbis(dimethyl sulfoxide)platinum(II): X-ray Structure, Mechanism of Isomerization, and Its Use as a Precursor to Organoamine Complexes of Variable Geometrical Configurations

Inorganic Chemistry

Volumn 35, Issue 26, 1996, Pages 7691-7698

  Romeo, Raffaello ^a   Scolaro, Luigi Monsù ^a   Nastasi, Nicola ^a   Mann, Brian Ernest ^b   Bruno, Giuseppe ^a   Nicolò, Francesco ^a  

^a UNIVERSITY OF MESSINA   (Italy)

^b UNIVERSITY OF SHEFFIELD   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 2542523989     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic960428s     Document Type: Article

References (72)

1. Davies, J. A. Adv. Inorg. Chem. Radiochem. 1981, 24, 115. Davies, J. A.; Hartley, F. R. Chem. Rev. 1981, 81, 79.
2. Davies, J. A. Adv. Inorg. Chem. Radiochem. 1981, 24, 115. Davies, J. A.; Hartley, F. R. Chem. Rev. 1981, 81, 79.
3. (a) Farrell, N.; Kiley, D. M.;Schmidt, W.; Hacker, M . Inorg. Chem. 1990, 29, 397.
4. (b) Lempers, E. L. M.; Bloemink, M. J.; Reedijk, J. Inorg. Chem. 1991, 30, 201.
5. (c) Lippard, S. J. Pure Appl. Chem. 1987, 59, 731.
6. (d) Reedijk, J. Pure Appl. Chem. 1987, 59, 181.
7. (e) Sherman, S. E.; Lippard, S. J. Chem. Rev. 1987, 87, 1153.
8. (f) Nicolini, M., Ed.Platinum and Other Metal Coordination Compounds in Cancer Chemiotherapy; Martinus Nijhoff Pubishing: Boston, 1988.
9. (g) Pasini, A.; Zunino, F.; Angew. Chem. 1987, 99, 632.
10. (h) Farrel, N. Transition Metal Complexes as Drugs and Chemotherapeutic Agents; Kluwer Academic Publishers : Dordrecht, The Netherlands, 1989.
11. Mestroni, G.; Alessio, E.; Sava, G.; Pacor, S.; Coluccia, M. In Metal Complexes in Cancer Chemotherapy; Keppler, B. K., Ed.; VCH Verlag: Weinheim, Germany, 1994.
12. (a) Romeo, R., Tobe, M. L. Inorg. Chem. 1974, 13, 1991.
13. (b) Elding, L. I.; Groning, O. Inorg. Chem. 1978, 17, 1872.
14. (c) Tobe, M. L.; Treadgold, A. T.; Cattalini, L. J. Chem. Soc., Dalton Trans. 1988, 2347.
15. Rochon, F. D.; Kong P. C.; Melanson, R. Inorg. Chem., 1990, 29, 2708. Melanson, R.; Hubert, J.; Rochon, F. D. Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 1976, 32, 1914.
16. Rochon, F. D.; Kong P. C.; Melanson, R. Inorg. Chem., 1990, 29, 2708. Melanson, R.; Hubert, J.; Rochon, F. D. Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 1976, 32, 1914.
17. (a) Elding, L. I.; Groning, A. B. Inorg. Chim. Acta 1978, 31, 243.
18. (b) Annibale, G.; Cattalini, L.; Canovese, L.; Michelon, G.; Marangoni, P.; Tobe, M. L. Inorg. Chem. 1983, 22, 975.
19. (c) Fanizzi, F. P.; Intini, F. P.; Maresca, L.; Natile, G.; Uccello-Barretta, G. Inorg. Chem. 1990, 29, 929.
20. (a) Romeo, R.; Cusumano, M. Inorg. Chim. Acta 1981, 49, 167.
21. (b) Braddock, P. D.; Romeo, R.; Tobe, M. L. Inorg. Chem. 1974, 13, 1170.
22. (a) Lanza, S.; Minniti, D.; Romeo, R.; Tobe, M. L. Inorg. Chem. 1983, 22, 2006.
23. (b) Cattalini, L.; Marangoni, G.; Michelon, G.; Paolucci, G.; Tobe, M. L. Inorg. Chem. 1981, 20, 71.
24. (c) Bonivento, M.; Canovese, L.; Cattalini, L.; Marangoni, G.; Michelon, G.; Tobe, M. L. Inorg. Chem. 1981, 20, 1493.
25. Romeo, R.; Minniti, D.; Lanza, S.; Tobe, M. L. Inorg. Chim. Acta 1977, 22, 87.
26. Eaborn, C.; Kundu, K.; Pidcock, A. J. J. Chem. Soc., Dalton Trans. 1981, 933.
27. (a) Lanza, S.; Minniti, D.; Moore, P.; Sachinidis, J.; Romeo, R.; Tobe, M. L. Inorg. Chem. 1984, 23, 4428.
28. (b) Lanza, S.; Minniti, D.; Romeo, R.; Moore, P.; Sachinidis, J.; Tobe, M. L. J. Chem. Soc., Chem. Commun. 1984, 542.
29. (c) Alibrandi, G.; Bruno, G.; Lanza, S.; Minniti, D.; Romeo, R.; Tobe, M.L. Inorg. Chem. 1987, 26, 185.
30. (d) Minniti, D.; Alibrandi, G.; Tobe, M. L.; Romeo, R. Inorg. Chem. 1987, 26, 3956.
31. (e) Frey, U.; Helm, L.; Merbach, A. E.; Romeo, R. J. Am. Chem. Soc. 1989, 111, 8161.
32. (f) Alibrandi, G.; Minniti, D.; Monsù Scolaro, L.; Romeo, R. Inorg. Chem. 1989, 28, 1939.
33. (g) Romeo, R.; Grassi, A.; Monsù Scolaro, L. Inorg. Chem. 1992, 31, 4383.
34. Price, J. H.; Williamson, A. N.; Schramm, R. F.; Wayland, B. B. Inorg. Chem. 1972, 11, 1280.
35. Davies, J. A.; Sood, A. Inorg. Chem. 1985, 24, 4213.
36. Price, J. H.; Birk, J. P.; Wayland, B. B. Inorg. Chem. 1978, 17, 2245.
37. Annibale, G.; Bonivento, M.; Canovese, L.; Cattalini, L.; Michelon, G.; Tobe, M. L. Inorg. Chem. 1985, 24, 797.
38. Annibale, G.; Bonivento, M.; Cattalini, L.; Tobe, M. L. J. Chem. Soc., Dalton Trans. 1992, 3433.
39. Van Geet, A. L. Anal. Chem. 1968, 40, 2227. Van Geet, A. L. Anal. Chem. 1970, 42, 679.
40. Van Geet, A. L. Anal. Chem. 1968, 40, 2227. Van Geet, A. L. Anal. Chem. 1970, 42, 679.
41. Kopfmann, G.; Huber, R. Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 1968, 24, 348.
42. SHELXTL-PLUS, Version 4.2; Siemens Analytical X-ray Instruments Inc.: Madison, WI, 1991.
43. Sheldrick, G. M. SHELXL-93, Program for the Refinement of Crystal Structures; University of Göttingen: Göttingen, Germany, 1994.
44. International Tables for X-ray Crystallography, Wilson, A. J. C., Ed.; Kluwer Academic Publishers: Dordrecht, The Netherlands, 1992; Vol. C.
45. Nardelli, M. Comput. Chem. 1983, 7, 95 (version locally modified).
46. Bennett, M. J.; Cotton, F. A.; Weaver, D. L.; Williams, R. J.; Watson, W. H. Acta Crystallogr. 1967, 23, 788.
47. Melanson, R.; Rochon, F. D. Acta Crystallogr., Sect. C: Struct. Crystallogr. Cryst. Chem. 1988, 44, 1893.
48. Sotman, S. S.; Fundamenskii, V. S.; Kukushkin, V. Yu.; Pankova, E. Yu. Zh. Obshch. Khim. 1988, 58, 2297.
49. Caligaris, M.; Carugo, O. Coord. Chem. Rev. 1996, 153, 1-23.
50. Elding, L. I.; Oskarsson, A. Inorg. Chim. Acta 1987, 130, 209.
51. Bardi, R.; Del Pra, A.; Piazzesi, A. M.; Trozzi, M. Cryst. Struct. Commun. 1981, 10, 301.
52. Bruno, G.; Nicolò, F.; Scopelliti, R.; Arena, G. Acta Crystallogr., Sect. C: Struct. Crystallogr. Cryst. Chem. 1996, C52, 827.
53. (a) Goel, A. B.; Goel, S.; van Derveer, D. Polyhedron 1984, 3, 373.
54. (b) Bardi, R.; Piazzesi, A. M. Inorg. Chim. Acta 1981, 17, 249.
55. Harrison, P. H.; Begley, M. J.; Molloy, K. C. J. Organomet. Chem. 1980, 186, 213, and references cited therein.
56. Pregosin, P. S. Annu. Rep. NMR Spectrosc. 1986, 17, 285.
57. 195Pt) is expected to be larger than 100 Hz; see: (a) Boag, N. M.; Browning, J.; Crocker, C.; Goggin, P. L.; Goodfellow, R. J.; Murray, M.; Spencer, J. L. J. Chem. Res., Synop. 1978, 228. (b) Kiffen, A. A.; Masters, C.; Visser, J. P. J. Chem. Soc., Dalton Trans. 1975, 1311. (c) Huis, R.; Masters, C. J. Chem. Soc., Dalton Trans. 1976, 1796.
58. 195Pt) is expected to be larger than 100 Hz; see: (a) Boag, N. M.; Browning, J.; Crocker, C.; Goggin, P. L.; Goodfellow, R. J.; Murray, M.; Spencer, J. L. J. Chem. Res., Synop. 1978, 228. (b) Kiffen, A. A.; Masters, C.; Visser, J. P. J. Chem. Soc., Dalton Trans. 1975, 1311. (c) Huis, R.; Masters, C. J. Chem. Soc., Dalton Trans. 1976, 1796.
59. 195Pt) is expected to be larger than 100 Hz; see: (a) Boag, N. M.; Browning, J.; Crocker, C.; Goggin, P. L.; Goodfellow, R. J.; Murray, M.; Spencer, J. L. J. Chem. Res., Synop. 1978, 228. (b) Kiffen, A. A.; Masters, C.; Visser, J. P. J. Chem. Soc., Dalton Trans. 1975, 1311. (c) Huis, R.; Masters, C. J. Chem. Soc., Dalton Trans. 1976, 1796.
60. 1H NMR spectrum has a signal attributable to water at δ = 1.60.
61. 2- are δ 824 (-3682), 611 (-3894), 602 (-3903), 540 (3964), and 112 (-4391).
62. Minniti, D.; Parisi, M. F. Inorg. Chim. Acta 1991, 188, 127.
63. Grassi, M.; Mann, B. E.; Pickup, B. T.; Spencer, C. M. J. Magn. Reson. 1986, 69, 92
64. Romeo, R.; Arena, G.; Monsù Scolaro, L.; Plutino, M. R. Inorg. Chim. Acta 1995, 240, 81.
65. Romeo, R. Arena, G.; Monsù Scolaro, L.; Plutino, M. R.; Bruno, G.; Nicolò, F. Inorg. Chem. 1994, 33, 4029, and references cited therein.
66. (a) Kong, P. C.; Iyamuremye, D.; Rochon, F. D. Can. J. Chem. 1976, 54, 3224.
67. (b) Reily, M. D.; Wilkowsky, K.; Shinozuka, K.; Marzilli, L. G. Inorg. Chem. 1985, 24, 27.
68. (c) Marzilli, L. G.; Hayden, Y.; Reily, M. D. Inorg. Chem. 1986, 25, 974.
69. Annibale, G.; Bonivento, M.; Cattalini, L.; Tobe, M. L. J. Chem. Soc., Dalton Trans. 1992, 3433.
70. See for example: (a) Andersen, G. K.; Cross, R. J. Chem. Soc. Rev. 1980, 9, 185.
71. (b) Wilkins, R. G. Kinetics and Mechanism of Reactions of Transition Metal Complexes; VCH Verlag: Weinhein, Germany, 1991.
72. (c) Romeo, R. Comments Inorg. Chem. 1990, 11, 21.