Mechanistic investigations and substrate scope evaluation of ruthenium-catalyzed direct sp3 arylation of benzylic positions directed by 3-substituted pyridines

Journal of Organic Chemistry

Volumn 78, Issue 2, 2013, Pages 658-672

  Dastbaravardeh, Navid ^a   Kirchner, Karl ^a   Schnürch, Michael ^a   Mihovilovic, Marko D ^a  

^a VIENNA UNIVERSITY OF TECHNOLOGY   (Austria)

Author keywords

[No Author keywords available]

Indexed keywords

ARGON ATMOSPHERES; ARYL RINGS; ARYLATIONS; ARYLBORONATES; BENZYLIC; BENZYLIC AMINES; C-H ACTIVATION; C-H INSERTION; ENERGY PROFILE; HIGH YIELD; MECHANISTIC STUDIES; REACTION CONDITIONS; ROTAMERS; RU CATALYSIS; SIMPLE REACTION;

CATALYSIS; CHEMICAL ACTIVATION; FUNCTIONAL GROUPS; PYRIDINE; RUTHENIUM;

AROMATIC COMPOUNDS;

3 CHLORO N (4 METHYLBENZYL)PYRIDIN 2 AMINE; 3 METHYL N (4 METHYLBENZYL)PYRIDIN 2 AMINE; 3 METHYL N [4 (TRIFLUOROMETHYL)BENZYL]PYRIDIN 2 AMINE; 3 METHYL N [PHENYL(4 TOLYL)METHYL]PYRIDIN 2 AMINE; 3 METHYL N [PHENYL(M TOLYL)METHYL]PYRIDIN 2 AMINE; 3 METHYL N [PHENYL[4 (TRIFLUOROMETHYL)PHENYL]METHYL]PYRIDIN 2 AMINE; ARGON; BENZILIC ACID; CARBON; FUNCTIONAL GROUP; METHYL 4 [[(3 METHYLPYRIDIN 2 YL)AMINO]METHYL]BENZOATE; N (4 FLUOROBENZYL) 3 METHYLPYRIDIN 2 AMINE; N (4 ISOPROPOXYBENZYL) 3 METHYLPYRIDIN 2 AMINE; N (4 METHOXYBENZYL) 3 METHYLPYRIDIN 2 AMINE; N (4 METHYLBENZYL) 3 (TRIFLUOROMETHYL)PYRIDIN 2 AMINE; N (4 METHYLBENZYL) 3 PHENYLPYRIDIN 2 AMINE; N [(3 CHLOROPHENYL)(PHENYL)METHYL] 3 METHYLPYRIDIN 2 AMINE; N [(4 CHLOROPHENYL)(PHENYL)METHYL] 3 METHYLPYRIDIN 2 AMINE; N [(4 FLUOROPHENYL)(PHENYL)METHYL] 3 METHYLPYRIDIN 2 AMINE; N [(4 METHOXYPHENYL)(PHENYL)METHYL] 3 METHYLPYRIDIN 2 AMINE; N [[4 (TERT BUTYL)PHENYL](PHENYL)METHYL] 3 METHYLPYRIDIN 2 AMINE; N [PHENYL (4TOLYL)METHYL] 3 (TRIFLUOROMETHYL)PYRIDIN 2 AMINE; N BENZHYDRYL 3 (TRIFLUOROMETHYL)PYRIDIN 2 AMINE; N BENZHYDRYL 3 METHYLPYRIDIN 2 AMINE; N BENZHYDRYL 3 PHENYLPYRIDIN 2 AMINE; N BENZYL 3 (TRIFLUOROMETHYL)PYRIDIN 2 AMINE; N BENZYL 3 CHLOROPYRIDIN 2 AMINE; N BENZYL 3 PHENYLPYRIDIN 2 AMINE; PYRIDINE DERIVATIVE; RUTHENIUM; UNCLASSIFIED DRUG;

ARTICLE; ARYLATION; ATMOSPHERE; CATALYSIS; CHEMICAL ANALYSIS; CHEMICAL REACTION; CONFORMATION;

EID: 84872546191     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo302547q     Document Type: Article

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