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3K has been reported, see: M. Pucheault, S. Darses and J.-P. Genet, J. Am. Chem. Soc., 2004, 126, 15356.
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15444376454
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note
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3, albeit in low yield (57% GC yield) as compared with 5.
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21
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0036301224
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(a) The direct conversion of aldehydes to ketones using the chelation-assisted catalytic system of 5 and 2-amino-3-picoline (in situ generation of the aldimine) was unsuccessful, because 2-amino-3-picoline is supposed to react with 5 to give an inactive complex during the reaction, see: J. A. Cabeza, Eur. J. Inorg. Chem., 2002, 1559;
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Cabeza, J.A.1
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22
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15444367857
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note
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(b) In the absence of acetone, the yield of 3a was decreased (47% GC yield) and severe reduction of 1a also took place;
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-
-
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23
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15444363922
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note
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Boronic acids were also applicable, but yields were approximately 20% lower compared with those of 2.
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-
-
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24
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15444375125
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note
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2. However, we observed comparable results even under anhydrous conditions. For a similar observation, see: ref. 4(b).
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27
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0000831355
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For the ruthenium-carbonyl complex-catalyzed C-H bond activation, see: C. H. Jun, H. Lee, J.-B. Park and D.-Y. Lee, Org. Lett, 1999, 1, 2161.
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0037442914
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For a similar transmetallation of alkoxo ruthenium species with an organoboron reagent, see: (a) F. Kakiuchi, S. Kan, K. Igi, N. Chatani and S. Murai, J. Am. Chem. Soc., 2003, 125, 1698;
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