Hydrogen generation from the dehydrogenation of ammonia-borane in the presence of ruthenium(III) acetylacetonate forming a homogeneous catalyst

International Journal of Hydrogen Energy

Volumn 38, Issue 1, 2013, Pages 180-187

  Duman, Sibel ^a   Özkar, Saim ^b  

^a BINGOL UNIVERSITY   (Turkey)

^b MIDDLE EAST TECHNICAL UNIVERSITY   (Turkey)

Author keywords

Acetylacetonate; Ammonia borane; Dehydrogenation; Homogeneous catalysis; Ruthenium

Indexed keywords

ACETYLACETONATES; ACTIVATION PARAMETER; AMMONIA-BORANE; CATALYST CONCENTRATION; CATALYTIC DEHYDROGENATION; ENTHALPY OF ACTIVATION; ENTROPY OF ACTIVATION; FIRST ORDER; HOMOGENEOUS CATALYSIS; HOMOGENEOUS CATALYST; HYDROGEN GAS; HYDROGEN GENERATIONS; KINETIC DATA; LOW TEMPERATURES; SUBSTRATE CONCENTRATIONS; TOLUENE SOLUTION; TURNOVER FREQUENCY;

ACTIVATION ENERGY; AMMONIA; CATALYST DEACTIVATION; HYDROGEN; HYDROGEN PRODUCTION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION KINETICS; RUTHENIUM; RUTHENIUM COMPOUNDS; TOLUENE;

DEHYDROGENATION;

EID: 84871997822     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2012.10.041     Document Type: Article

References (46)

1. R.J. Keaton, J.M. Blacquiere, and R.T. Baker Base metal catalyzed dehydrogenation of ammonia-borane for chemical hydrogen storage J Am Chem Soc 129 2007 1844 1845
2. P.V. Ramachandran, and P.D. Gagare Preparation of ammonia borane in high yield and purity, methanolysis, and regeneration Inorg Chem 46 2007 7810 7817
3. J.S. Wang, and R.A. Geanangel B-11 NMR-studies of the thermal-decomposition of ammonia borane in solution Inorg Chim Acta 148 1988 185 190
4. O.V. Komova, V.I. Simagina, G.V. Odegova, Y.A. Chesalov, O.V. Netskina, and A.M. Ozerova Low-temperature decomposition of ammonia borane in the presence of titania Inorg Mater 47 2011 1101 1106
5. F.H. Stephens, R.T. Baker, M.H. Matus, D.J. Grant, and D.A. Dixon Acid initiation of ammonia-borane dehydrogenation for hydrogen storage Angew Chem Int Ed 46 2007 746 749
6. C.A. Jaska, K. Temple, A.J. Lough, and I. Manners Transition metal-catalyzed formation of boron-nitrogen bonds: catalytic dehydrocoupling of amine-borane adducts to form aminoboranes and borazines J Am Chem Soc 125 2003 9424 9434
7. S. Swinnen, V.S. Nguyen, and M.T. Nguyen Hydrogen release from ammonia borane and derivatives in the presence of a ruthenium complex incorporating cooperative PNP ligands Chem Phys Lett 513 2011 195 200
8. M.C. Denney, V. Pons, T.J. Hebden, D.M. Heinekey, and K.I. Goldberg Efficient catalysis of ammonia borane dehydrogenation J Am Chem Soc 128 2006 12048 12049
9. T. Umegaki, J.M. Yan, X.B. Zhang, H. Shioyama, N. Kuriyama, and Q. Xu Boron- and nitrogen-based chemical hydrogen storage materials Int J Hydrogen Energy 34 2009 2303 2311
10. H. Erdogan, O. Metin, and S. Ozkar In situ-generated PVP-stabilized palladium(0) nanoclusters catalyst in hydrogen generation from the methanolysis of ammonia-borane Phys Chem Chem Phys 11 2009 10519 10525
11. G.C. Fortman, A.M.Z. Slawin, and S.P. Nolan Highly active iridium(III)-NHC system for the catalytic B-N bond activation and subsequent solvolysis of ammonia-borane Organometallics 30 2011 5487 5492
12. D.J. Heldebrant, A.N. Karkamkar, J. Hess, M. Bowden, S. Rassat, and F. Zheng The effects of chemical additives on the induction phase in solid-state thermal decomposition of ammonia borane Chem Mater 20 2008 5332 5336
13. 2+-induced room temperature hydrogen release from ammonia borane Energy Environ Sci 2 2009 1274 1276
14. A. Staubitz, A.P.M. Robertson, and I. Manners Ammonia-borane and related compounds as dihydrogen sources Chem Rev 110 2010 4079 4124
15. S.S. Wise, J.L. Margrave, H.M. Feder, and W.N. Hubbard Fluorine bomb calorimetry. XVI. The enthalpy of formation of boron nitride J Phys Chem 70 1966 7 10
16. M. Zahmakiran, T. Ayvali, and K. Philippot In situ formed catalytically active ruthenium nanocatalyst in room temperature dehydrogenation/ dehydrocoupling of ammonia-borane from Ru(cod)(cot) precatalyst Langmuir 28 2012 4908 4914
17. N. Blacquiere, S. Diallo-Garcia, S.I. Gorelsky, D.A. Black, and K. Fagnou Ruthenium-catalyzed dehydrogenation of ammonia boranes J Am Chem Soc 130 2008 14034 14035
18. O. Metin, S. Duman, M. Dinc, and S. Ozkar Oleylamine-stabilized palladium(0) nanoclusters as highly active heterogeneous catalyst for the dehydrogenation of ammonia borane J Phys Chem C 115 2011 10736 10743
19. S.K. Kim, T.J. Kim, T.Y. Kim, G. Lee, J.T. Park, and S.W. Nam Tetraglyme-mediated synthesis of Pd nanoparticles for dehydrogenation of ammonia borane Chem Commun 48 2012 2021 2023
20. S. Karahan, M. Zahmakiran, and S. Ozkar A facile one-step synthesis of polymer supported rhodium nanoparticles in organic medium and their catalytic performance in the dehydrogenation of ammonia-borane Chem Commun 48 2012 1180 1182
21. T. Ayvali, M. Zahmakiran, and S. Ozkar One-pot synthesis of colloidally robust rhodium(0) nanoparticles and their catalytic activity in the dehydrogenation of ammonia-borane for chemical hydrogen storage Dalton Trans 40 2011 3584 3591
22. S.F. Li, Y.H. Guo, W.W. Sun, D.L. Sun, and X.B. Yu Platinum nanoparticle functionalized CNTs as nanoscaffolds and catalysts to enhance the dehydrogenation of ammonia-borane J Phys Chem C 114 2010 21885 21890
23. R.P. Shrestha, H.V.K. Diyabalanage, T.A. Semelsberger, K.C. Ott, and A.K. Burrell Catalytic dehydrogenation of ammonia borane in non-aqueous medium Int J Hydrogen Energy 34 2009 2616 2621
24. T. He, J.H. Wang, T. Liu, G.T. Wu, Z.T. Xiong, and J. Yin Quasi in situ Mossbauer and XAS studies on FeB nanoalloy for heterogeneous catalytic dehydrogenation of ammonia borane Catal Today 170 2011 69 75
25. T. He, Z.T. Xiong, G.T. Wu, H.L. Chu, C.Z. Wu, and T. Zhang Nanosized Co- and Ni-catalyzed ammonia borane for hydrogen storage Chem Mater 21 2009 2315 2318
26. R.T. Baker, J.C. Gordon, C.W. Hamilton, N.J. Henson, P.H. Lin, and S. Maguire Iron complex-catalyzed ammonia-borane dehydrogenation. A potential route toward B-N-containing polymer motifs using earth-abundant metal catalysts J Am Chem Soc 134 2012 5598 5609
27. A. Paul, and C.B. Musgrave Catalyzed dehydrogenation of ammonia-borane by iridium dihydrogen pincer complex differs from ethane dehydrogenation Angew Chem Int Ed 46 2007 8153 8156
28. A. Rossin, M. Caporali, L. Gonsalvi, A. Guerri, A. Lledos, and M. Peruzzini Selective B-H versus N-H bond activation in ammonia borane by [Ir(dPPM)(2)]OTf Eur J Inorg Chem 21 2009 3055 3059
29. 2 Angew Chem Int Ed 49 2010 918 920
30. S.K. Kim, W.S. Han, T.J. Kim, T.Y. Kim, S.W. Nam, and M. Mitoraj Palladium catalysts for dehydrogenation of ammonia borane with preferential B-H activation J Am Chem Soc 132 2010 9954 9955
31. B.L. Conley, and T.J. Williams Dehydrogenation of ammonia-borane by Shvo's catalyst Chem Commun 46 2010 4815 4817
32. B.L. Conley, D. Guess, and T.J. Williams A robust, air-stable, reusable ruthenium catalyst for dehydrogenation of ammonia borane J Am Chem Soc 133 2011 14212 14215
33. B.L. Conley, and T.J. Williams Thermochemistry and molecular structure of a remarkable agostic interaction in a heterobifunctional ruthenium-boron complex J Am Chem Soc 132 2010 1764 1765
34. A.D. Sutton, A.K. Burrell, D.A. Dixon, E.B. Garner, J.C. Gordon, and T. Nakagawa Regeneration of ammonia borane spent fuel by direct reaction with hydrazine and liquid ammonia Science 331 2011 1426 1429
35. E. Keceli, and S. Ozkar Ruthenium(III) acetylacetonate: a homogeneous catalyst in the hydrolysis of sodium borohydride J Mol Catal A Chem 286 2008 87 91
36. M. Masjedi, T. Demiralp, and S. Ozkar Testing catalytic activity of ruthenium(III) acetylacetonate in the presence of trialkylphosphite or trialkylphosphine in hydrogen generation from the hydrolysis of sodium borohydride J Mol Catal A Chem 310 2009 59 63
37. M. Zahmakiran, and S. Özkar Water dispersible acetate stabilized ruthenium(0) nanoclusters as catalyst for hydrogen generation from the hydrolysis of sodium borohyride J Mol Catal A Chem 258 2006 95 103
38. J.A. Widegren, and R.G. Finke A review of the problem of distinguishing true homogeneous catalysis from soluble or other metal-particle heterogeneous catalysis under reducing conditions J Mol Catal A Chem 198 2003 317 341
39. M. Metin, S. Duman, M. Dinç, and S. Özkar Oleylamine stabilized palladium(0) nanoclusters as highly active heterogeneous catalyst for the dehydrogenation of ammonia borane J Phys Chem C 115 2011 10736 10743
40. K.A. Connors Theory of chemical kinetics 1990 VCH Publishers New York
41. M.V. Twigg Mechanism of inorganic and organometallic reactions 1994 Plenum Press New York
42. ± Inorg Chem 45 2006 2413 2423
43. x Inorg Chem 22 1983 1684 1686
44. V. Pons, R.T. Baker, N.K. Szymczak, D.J. Heldebrant, J.C. Linehan, and M.H. Matus Coordination of aminoborane, NH(2)BH(2), dictates selectivity and extent of H(2) release in metal-catalysed ammonia borane dehydrogenation Chem Commun 28 2008 6597 6599
45. D.W. Himmelberger, L.R. Alden, M.E. Bluhm, and L.G. Sneddon Ammonia borane hydrogen release in ionic liquids Inorg Chem 48 2009 9883 9889
46. A. Staubitz, M.E. Sloan, A.P.M. Robertson, A. Friedrich, S. Schneider, and P.J. Gates Catalytic dehydrocoupling/dehydrogenation of N-methylamine-borane and ammonia-borane: synthesis and characterization of high molecular weight polyaminoboranes J Am Chem Soc 132 2010 13332 13345