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Volumn 46, Issue 19, 2007, Pages 7810-7817

Preparation of ammonia borane in high yield and purity, methanolysis, and regeneration

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[No Author keywords available]

Indexed keywords


EID: 34948836206     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic700772a     Document Type: Article
Times cited : (450)

References (54)
  • 1
    • 34948875778 scopus 로고    scopus 로고
    • Raissi, A. T. Proceedings of the 2002 U.S. DOE Hydrogen Program Review; NREL/CP-610-32405; U.S. Department of Energy: Washington, DC, 2002; http://www.eere.energy.gov/hydrogenandfuelcells/ pdfs/32405b15.pdf.
    • (a) Raissi, A. T. Proceedings of the 2002 U.S. DOE Hydrogen Program Review; NREL/CP-610-32405; U.S. Department of Energy: Washington, DC, 2002; http://www.eere.energy.gov/hydrogenandfuelcells/ pdfs/32405b15.pdf.
  • 9
    • 34948865195 scopus 로고    scopus 로고
    • Borane ammonia complex, 90% Tech. grade, Aldrich catalog price of $116.50/10 g.
    • Borane ammonia complex, 90% Tech. grade, Aldrich catalog price of $116.50/10 g.
  • 13
    • 33846497860 scopus 로고    scopus 로고
    • Stephens, F. H.; Baker, R. T.; Matus, M. H.; G., Daniel J.; Dixon, D. A. Angew. Chem., Int. Ed. 2007, 46, 746.
    • (d) Stephens, F. H.; Baker, R. T.; Matus, M. H.; G., Daniel J.; Dixon, D. A. Angew. Chem., Int. Ed. 2007, 46, 746.
  • 18
    • 31344478075 scopus 로고    scopus 로고
    • De B., S.; Carewska, M.; Cento, C.; Gislon, P.; Pasquali, M.; S. S; Prosini, P P. Thermochim. Acta 2006, 441, 184.
    • (i) De B., S.; Carewska, M.; Cento, C.; Gislon, P.; Pasquali, M.; S. S; Prosini, P P. Thermochim. Acta 2006, 441, 184.
  • 29
    • 34948848103 scopus 로고    scopus 로고
    • Parts of this work were presented during (a) the inaugural Purdue University Energy Center Hydrogen Initiative Symposium, April 5
    • Parts of this work were presented during (a) the inaugural Purdue University Energy Center Hydrogen Initiative Symposium, April 5, 2006,
    • (2006)
  • 30
    • 34948852738 scopus 로고    scopus 로고
    • and (b) during the symposium entitled, Role of Catalysts in Hydrogen Production sponsored by the FUEL Division of the ACS during the 232nd ACS National Meeting, San Francisco, CA, September 11, 2006.
    • and (b) during the symposium entitled, "Role of Catalysts in Hydrogen Production" sponsored by the FUEL Division of the ACS during the 232nd ACS National Meeting, San Francisco, CA, September 11, 2006.
  • 32
    • 34948875258 scopus 로고    scopus 로고
    • Procedures for handling air- and moisture-sensitive compounds has been described in Brown, H. C.; Kramer, G. W.; Levy, A. B.; Midland, M. M. Organic Synthesis via Boranes; Aldrich: Milwaukee, WI, 2000; 1, Chapter 9.
    • (a) Procedures for handling air- and moisture-sensitive compounds has been described in Brown, H. C.; Kramer, G. W.; Levy, A. B.; Midland, M. M. Organic Synthesis via Boranes; Aldrich: Milwaukee, WI, 2000; Vol. 1, Chapter 9.
  • 33
    • 34948828539 scopus 로고    scopus 로고
    • For the hydride analysis procedure estimation of hydrogen after hydrolysis or alcoholysis, see ref 10a, pp 241-245
    • (b) For the hydride analysis procedure (estimation of hydrogen after hydrolysis or alcoholysis), see ref 10a, pp 241-245.
  • 34
    • 0000150155 scopus 로고
    • For the hydrolysis of borohydrides see a
    • For the hydrolysis of borohydrides see (a) Brown, H. C.; Brown, C. A. J. Am. Chem. Soc. 1962, 84, 1493.
    • (1962) J. Am. Chem. Soc , vol.84 , pp. 1493
    • Brown, H.C.1    Brown, C.A.2
  • 42
    • 34948880711 scopus 로고    scopus 로고
    • For alcoholysis of borohydride, see: (a) Ramachandran, P. V.; Hazra, D; Raju, B. C.; Reddy M., V.; Bhattacharyya, A. U.S. Pat. Appl. 2005255024, 2005.
    • For alcoholysis of borohydride, see: (a) Ramachandran, P. V.; Hazra, D; Raju, B. C.; Reddy M., V.; Bhattacharyya, A. U.S. Pat. Appl. 2005255024, 2005.
  • 44
    • 34948815595 scopus 로고    scopus 로고
    • For methanolysis of other metal hydrides, see:, Patent JP 2003206101
    • For methanolysis of other metal hydrides, see: Morita, Y.; Suzuki, M. Jpn. Patent JP 2003206101, 2003.
    • (2003)
    • Morita, Y.1    Suzuki2    Jpn, M.3
  • 45
    • 34948885105 scopus 로고    scopus 로고
    • AB has 26% solubility in water. A 10% water solution of ammonia borane loses 1.8% hydrogen over 4 days, 4.8% over a month, and 45% over 18 months, see ref 1a
    • AB has 26% solubility in water. A 10% water solution of ammonia borane loses 1.8% hydrogen over 4 days, 4.8% over a month, and 45% over 18 months, see ref 1a.
  • 50
  • 54
    • 34948853255 scopus 로고    scopus 로고
    • Ramachandran, P. V.; Gagare, Pravin D.; Raju, B. C. Patent application number 60/817,911, filed on June 30, 2006.
    • Ramachandran, P. V.; Gagare, Pravin D.; Raju, B. C. Patent application number 60/817,911, filed on June 30, 2006.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.