Highly active iridium(III)-NHC system for the catalytic B-N bond activation and subsequent solvolysis of ammonia-borane

Organometallics

Volumn 30, Issue 20, 2011, Pages 5487-5492

  Fortman, George C ^a   Slawin, Alexandra M Z ^a   Nolan, Steven P ^a  

^a UNIVERSITY OF ST ANDREWS   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION PARAMETER; ACTIVE CATALYST; BOND ACTIVATION; CATALYST LOADINGS; CO-ORDINATIVELY UNSATURATED; RESTING STATE; SPECTROSCOPIC DATA; X-RAY STRUCTURE;

AMMONIA; CATALYST ACTIVITY; IRIDIUM COMPOUNDS; SOLVENTS;

IRIDIUM;

EID: 80054725759     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om2007437     Document Type: Article

References (30)

1. Staubitz, A.; Robertson, A. P. M.; Manners, I. Chem. Rev. 2010, 110, 4079-4124
2. Smythe, N. C.; Gordon, J. C. Eur. J. Inorg. Chem. 2010, 509-521
3. Alcaraz, G.; Sabo-Etienne, S. Angew. Chem., Int. Ed. 2010, 49, 7170-7179
4. Hamilton, C. W.; Baker, R. T.; Staubitz, A.; Manners, I. Chem. Soc. Rev. 2009, 38, 279-293
5. Stephens, F. H.; Pons, V.; Baker, R. T. Dalton Trans. 2007, 2613-2626
6. Marder, T. B. Angew. Chem., Int. Ed. 2007, 46, 8116-8118
7. Kelly, H. C.; Marchelli, F. R.; Giutso, M. B. Inorg. Chem. 1964, 3, 431-437
8. Ryschkewitsch, G. E. J. Am. Chem. Soc. 1960, 82, 3290-3294
9. Kelly, H. C.; Marriott, V. B. Inorg. Chem. 1979, 18, 2875-2878
10. D'Ulivo, A.; Onor, M.; Pitzalis, E. Anal. Chem. 2004, 76, 6342-6352
11. Chandra, M.; Xu, Q. J. Power Sources 2006, 156, 190-194
12. Clark, T. J.; Whittell, G. R.; Manners, I. Inorg. Chem. 2007, 46, 7522-2527
13. Graham, T. W.; Tsang, C.-W.; Chen, X.; Guo, R.; Jia, W.; Lu, S.-M.; Sui-Seng, C.; Ewart, C. B.; Lough, A.; Amoroso, D.; Abdur-Rashid, K. Angew. Chem. Int., Ed. 2010, 49, 8708-8711
14. Scott, N. M.; Dorta, R.; Stevens, E. D.; Correa, A.; Cavallo, L.; Nolan, S. P. J. Am. Chem. Soc. 2005, 127, 3516-3526
15. Scott, N. M.; Pons, V.; Stevens, E. D.; Heinekey, D. M.; Nolan, S. P. Angew. Chem., Int. Ed. 2005, 44, 2512-2515
16. Cavallo, L.; Nolan, S. P.; Jacobsen, H. Can. J. Chem. 2009, 87, 1362-1368
17. Fortman, G. C.; Jacobsen, H.; Cavallo, L.; Nolan, S. P. Chem. Commun. 2011, 9723-9725
18. Loboda, N. V.; Antipin, M. Y.; Akomov, V. M.; Struchkov, Y. T.; Skvortsov, V. G.; Petrova, O. V.; Molodkin, A. K. Zh. Neorg. Khim. 1993, 38, 1960-1962
19. Salentine, C. G. Inorg. Chem. 1983, 22, 3920-3924
20. Jia, D.; Zhao, Y.; Pan, S. Chinese Patent CN 101824651, 2010.
21. CCDC-826131 (borate), CCDC-826132 (4), and CCDC-826133 (5) contain supplementary crystallographic data for this contribution. These data can be obtained free of charge from The Cambridge Cryatallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
22. Deeming, A. J.; Doherty, S.; Marshall, J. E.; Powell, J. L.; Senior, A. M. Dalton Trans. 1993, 1093-1100
23. Xu, W.; Lough, A. J.; Morris, R. H. Can. J. Chem. 1997, 75, 475-482
24. Rais, D.; Bergman, R. G. Chem. Eur. J. 2004, 10, 3970-3978
25. Hughes, R. P.; Smith, J. M.; Incarvito, C. D.; Lam, K.-C.; Rhatigan, B.; Rhein-gold, A. L. Organometallics 2004, 23, 3362-3362
26. Vicente, J.; Chicote, M. T.; Vicente-Hernández, I.; Bautista, D. Inorg. Chem. 2008, 47, 9592-9605
27. Heiden, Z. M.; Gorecki, B. J.; Rauchfuss, T. B. Organometallics 2008, 27, 1542-1549
28. Blacker, A. J.; Brown, S.; Clique, B.; Gourlay, B.; Headley, C. E.; Ingham, S.; Ritson, D.; Screen, T.; Stirling, M. J.; Taylor, D.; Thompson, G. Org. Process Res. Dev. 2009, 13, 1370-1378
29. Salomon, M. A.; Jungton, A.-K.; Braun, T. Dalton Trans. 2009, 7669-7677
30. Tang, C. Y.; Thompson, A. L.; Aldridge, S. J. Am. Chem. Soc. 2010, 132, 10578-10591