Rhodium-catalyzed regio-, diastereo-, and enantioselective [2+2+2] cycloaddition of 1,6-enynes with acrylamides

Angewandte Chemie - International Edition

Volumn 51, Issue 52, 2012, Pages 13031-13035

  Masutomi, Koji ^a   Sakiyama, Norifumi ^a   Noguchi, Keiichi ^a   Tanaka, Ken ^a,b  

^a TOKYO UNIVERSITY OF AGRICULTURE AND TECHNOLOGY   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

Author keywords

Asymmetric catalysis; Cycloaddition; Cyclohexenes; Enynes; Rhodium

Indexed keywords

1 ,6-ENYNES; [2+2+2] CYCLOADDITION; ACRYLAMIDES; ASYMMETRIC CATALYSIS; ASYMMETRIC VARIANTS; BISPHOSPHINE; CARBON-CARBON BOND-FORMING REACTIONS; CYCLOADDITIONS; CYCLOHEXADIENES; CYCLOHEXENES; ELECTRON-DEFICIENT; ENANTIOSELECTIVE; ENYNES; FACILE PREPARATION; INTRAMOLECULAR REACTIONS; MONTGOMERY; REACTIVE SUBSTRATES; RESEARCH GROUPS; RHODIUM-CATALYZED; SINGLE-STEP; STEREOGENIC CENTERS;

ACETYLENE; AMIDES; CATALYSIS; CATALYSTS; CYCLOADDITION; NICKEL; OLEFINS; RHODIUM; STEREOCHEMISTRY;

RHODIUM COMPOUNDS;

EID: 84871962315     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201206122     Document Type: Article

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