Studies on elimination pathways of β-halovinyl ketones leading to allenyl and propargyl ketones and furans under the action of mild bases

Journal of Organic Chemistry

Volumn 77, Issue 24, 2012, Pages 11132-11145

  Kim, Hun Young ^a   Li, Jian Yuan ^a   Oh, Kyungsoo ^a  

^a INDIANA UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALLENYL; ELIMINATION REACTION; ENOLIZATION; ONE-POT SYNTHESIS; PROPARGYL; SYNTHETIC UTILITY;

AROMATIC COMPOUNDS; COPPER COMPOUNDS; DEUTERIUM; ORGANIC POLLUTANTS;

KETONES;

1 (4 BROMOPHENYL) 3 CHLOROOCT 2 EN 1 ONE; 1 CHLORO 1 CYCLOHEXYLPENT 1 EN 3 ONE; 1 PHENYLOCT 2 YN 1 ONE; 2 (4 CHLORO 6 OXO 6 PHENYLHEX 4 EN 1 YL)ISOINDOLINE 1,3 DIONE; 3 CHLORO 1 (4 METHOXYPHENYL)OCT 2 EN 1 ONE; 3 CHLORO 1 (4 NITROPHENYL)OCT 2 EN 1 ONE; 3 CHLORO 1 (4 TOLYL)OCT 2 EN 1 ONE; 3 CHLORO 1 PHENYLOCT 2 EN 1 ONE; 3 CHLORO 3 CYCLOHEXYL 1 PHENYLPROP 2 EN 1 ONE; 3,7 DICHLORO 1 PHENYLHEPT 2 EN 1 ONE; 4 CHLORO 1 PHENYLNON 3 EN 2 ONE; 5 CHLORODEC 4 EN 3 ONE; ALLENYL KETONE; BASE; BETA CHLOROVINYL KETONE; BETA HALOVINYL KETONE; DEUTERIUM; FURAN DERIVATIVE; KETONE; METHYL 5 CHLORO 7 OXO 7 PHENYLHEPT 5 ENOATE; PROPARGYL KETONE; UNCLASSIFIED DRUG;

ARTICLE; DEHALOGENATION; ELIMINATION REACTION; ONE POT SYNTHESIS; PROTON TRANSPORT; STEREOCHEMISTRY;

ALKENES; ALKYNES; FURANS; HALOGENATION; HYDROGEN-ION CONCENTRATION; KETONES; MODELS, MOLECULAR; MOLECULAR CONFORMATION;

EID: 84871534996     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo302253c     Document Type: Article

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