Studies on K2CO3-Catalyzed 1,4-Addition of 1,2-Allenic Ketones with Diethyl Malonate: Controlled Selective Synthesis of β,γ-Unsaturated Enones and α-Pyrones

Journal of Organic Chemistry

Volumn 68, Issue 23, 2003, Pages 8996-9002

  Ma, Shengming ^a   Yu, Shichao ^a   Yin, Shaohu ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ENONES; LACTONIZATION;

CARBON; CATALYSIS; CHEMICAL BONDS; SUBSTITUTION REACTIONS; SYNTHESIS (CHEMICAL);

KETONES;

1,2 ALLENIC KETONE DERIVATIVE; 2 PYRONE DERIVATIVE; ALKADIENE; ALLYL COMPOUND; BETA,GAMMA UNSATURATED ENONE DERIVATIVE; CARBON; KETONE DERIVATIVE; MALONIC ACID DERIVATIVE; MALONIC ACID DIETHYL ESTER; NATURAL PRODUCT; POTASSIUM CARBONATE; PROPADIENYL KETONE DERIVATIVE; UNCLASSIFIED DRUG;

ADDITION REACTION; ARTICLE; CATALYST; CHEMICAL ANALYSIS; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; MICHAEL ADDITION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STEREOCHEMISTRY; STRUCTURE ANALYSIS; SUBSTITUTION REACTION; SYNTHESIS; TECHNIQUE;

EID: 0242576780     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo034633i     Document Type: Article

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