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Organic Letters

Volumn 9, Issue 13, 2007, Pages 2581-2584

N-heterocyclic carbene-initiated α-acylvinyl anion reactivity: Additions of α-hydroxypropargylsilanes to aldehydes

(3) Reynolds, Troy E a Stern, Charlotte A a Scheidt, Karl A a

a NORTHWESTERN UNIVERSITY (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE; HETEROCYCLIC COMPOUND; SILANE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY;

ALDEHYDES; HETEROCYCLIC COMPOUNDS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; SILANES;

EID: 34547219364 PISSN: 15237060 EISSN: None Source Type: Journal
DOI: 10.1021/ol0710515 Document Type: Article

Times cited : (46)

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- Solvent, hydrogen atoms (including OH) were removed from ORTEP for clarity. X-ray data for 14: C36H45Cl 5N2O, MW, 698.99, T, 153(2) K, λ, 0.71073 Å, monoclinic space group, P2(1)/c, a, 10.0917(8) Å, b, 15.981(12) Å, c, 23.623(18) Å, β= 95.076(1)°, V, 3794.8(5) Å3, Z, 4, Dc, 1.223 g/cm3, μ, 0.411 mm-1, F(000, 415, crystal size 0.30 × 0.29 × 0.28 mm3, independent reflections 9255 [R(int, 0.0930, reflections collected 35196, refinement method was full-matrix least-squares on F 2, goodness-of-fit on F2 was 0.976, final R indices [I > 2σ(I, R1, 0.0906, wR2, 0.2519, R indices (all data) R1, 0.1274, wR2, 0.2519, largest diff. peak and hole 2.047 and -1.193 e Å-3. See the Supporting Information for additional details
- -3. See the Supporting Information for additional details.

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