Determination of sulfite in beer based on fluorescent derivatives and liquid chromatographic separation

Journal of the American Society of Brewing Chemists

Volumn 70, Issue 4, 2012, Pages 296-302

  Abrahamsson, Victor ^a   Hoff, Signe ^b   Nielsen, Nikoline J ^b   Lund, Marianne N ^b   Andersen, Mogens L ^b  

^a LINNAEUS UNIVERSITY   (Sweden)

^b UNIVERSITY OF COPENHAGEN   (Denmark)

Author keywords

Analysis; Beer; Matrix match; Sulfite; ThioGlo 1

Indexed keywords

EID: 84871342213     PISSN: 03610470     EISSN: None     Source Type: Journal    
DOI: 10.1094/ASBCJ-2012-1012-01     Document Type: Article

References (29)

1. Akasaka, K., Matsuda, H., Ohrui, H., Meguro, H., and Suzuki, T. Fluorometric determination of sulfite in wine by N-(9-acridinyl) maleimide. Agric. Biol. Chem. 54:501-504, 1990.
2. Akasaka, K., Suzuki, T., Ohrui, H., and Meguro, H. Fluorometric determination of sulfite with N-(9-acridinyl)-maleimide for high performance liquid chromatography. Agric. Biol. Chem. 50:1139-1144, 1986.
3. Akasaka, K., Suzuki, T., Ohrui, H., and Meguro, H. Fluorometric determination of sulfites in rainwater. Anal. Sci. 2:443-446, 1986.
4. Andersen, M. L., Outtrup, H., and Skibsted, L. H. Potential antioxidants in beer assessed by ESR spin trapping. J. Agric. Food Chem. 48:3106-3111, 2000.
5. ASBC. Beer 21: Total sulfur dioxide. In: Methods of Analysis (CD). American Society of Brewing Chemists, St. Paul, MN, 2009.
6. Baker, C. D., and Upperton, A. M. The determination of sulphur dioxide in beer-collaborative trial of four methods. J. Inst. Brew. 98:462-462, 1992.
7. Bamforth, C. W., and Lentini, A. The flavor instability of beer. In: Beer, A Quality Perspective. C. W. Bamforth, Ed. Academic, Burlington, MA. Pp. 85-109, 2009.
8. Claudia, R. C., and Francisco, J. C. Application of flow injection analysis for determining sulphites in food and beverages: A review. Food Chem. 112:487-493, 2009.
9. Covalent Associates. ThioGlo information and guidelines. http:// www.covalentassociates.com/ThioGlo%20information%20and%20 guidelines.pdf
10. European Brewery Convention. Analytica-EBC. Verlag Hans Carl, Nürnberg, Germany, 1998.
11. Gales, P. W. Brewing Chemistry and Technology. American Society of Brewing Chemists, St. Paul, MN, 2010.
12. Hurse, T. J., and Abeydeera, W. P. P. Quantification of sulfur and sulfur-containing compounds in wastewaters by means of a combination of liquid chromatographic method. J. Chromatogr. A 942:201-210, 2002.
13. International Conference on Harmonisation of Technical Requirements for Registration of Pharmaceuticals for Human Use. Validation of Analytical Procedures: Text and Methodology. 2005.
14. International Organization for Standardization. ISO 5725-2. In: Accuracy (Trueness and Precision) of Measurements Methods and Results-Part 2. 1994.
15. Kalia, J., and Raines, R. T. Catalysis of imido group hydrolysis in maleimide conjugate. Bioorg. Med. Chem. Lett. 17:6286-6289, 2007.
16. Kamata, T., Ohrui, H., and Meguro, H. Highly sensitive enzymatic assay of sulfhydryl compounds and the enzyme activities by N-(9-acridinyl)maleimide fluorometry (review). J. Trace. Microprobe Tech. 20:449-461, 2002.
17. Kaneda, H., Takashio, M., Osawa, T., Kawakishi, S., and Tamaki, T. Behavior of sulfites during fermentation and storage of beer. J. Am. Soc. Brew. Chem. 54:115-120, 1996.
18. Koch, M., Köppen, R., Siegel, D., Witt, A., and Nehls, I. Determination of total sulfite in wine by ion chromatography after in-Sample oxidation. J. Agric. Food Chem. 58:9463-9467, 2010.
19. Lund, M. N., and Andersen, M. L. Detection of thiol groups in beer and their correlation with oxidative stability. J. Am. Soc. Brew. Chem. 69:163-169, 2011.
20. Meguro, H., Akasaka, K., Ohrui, H., and Matsui, S. I. Highly sensitive N-(9-acridinyl)maleimide (NAM) fluorometry to determine sulfite below ppm level in environmental and biological samples. J. Trace. Microprobe Tech. 20:463-472, 2002.
21. Michigami, Y., Morooka, M., and Ueda, K. Determination of sulphite and sulphate by ion chromatography using a weakly basic phthalate eluent. J. Chromatogr. A 732:403-407, 1996.
22. Nyborg, M., Outtrup, H., and Dreyer, T. Investigation of the protective mechanism of sulfite against beer staling and formation of adducts with trans-2-nonenal. J. Am. Soc. Brew. Chem. 57:24-28, 1999.
23. The European Parliament and the Council of the European Union. Directive 95/2/EC. Off. J. Eur. Union. 1995.
24. The European Parliament and the Council of the European Union. Directive 2003/89/EC. Off. J. Eur. Union. 2003.
25. Uchida, M., and Ono, M. Determination of hydrogen peroxide in beer and its role in beer oxidation. J. Am. Soc. Brew. Chem. 57:145-150, 1999.
26. Vally, H., Misso, N. L. A., and Madan, V. Clinical effects of sulphite additives. Clin. Exp. Allergy 39:1643-1651, 2009.
27. Wedzicha, B. L. Effects of sulfur dioxide on food quality. In: Food shelf life stability. N. A. M. Eskin, and D. S. Robinson, Eds. CRC Press, Boca Raton, FL. Pp. 265-294, 2001.
28. World Health Organization. Food Additives: Sulfur Dioxide and Sulfites. World Health Organization, Geneva, 1974.
29. Zhao, M., Hibbert, D. B., and Gooding, J. J. Determination of sulfite in beer samples using an amperometric fill and flow channel biosensor employing sulfite oxidase. Anal. Chim. Acta 556:195-200, 2006.