Indicators for optical oxygen sensors

Bioanalytical Reviews

Volumn 4, Issue 2-4, 2012, Pages 115-157

  Quaranta, Michela ^a   Borisov, Sergey M ^a   Klimant, Ingo ^a  

^a GRAZ UNIVERSITY OF TECHNOLOGY   (Austria)

Author keywords

Bioanalysis; Luminescence; Metal complexes; Oxygen indicators; Quenching

Indexed keywords

DISSOLVED OXYGEN; METALLOPORPHYRIN; OXYGEN; POLYCYCLIC AROMATIC HYDROCARBON; PYRIDINE DERIVATIVE; TRANSITION ELEMENT;

ABSORPTION SPECTROSCOPY; BIOREACTOR; BIOTECHNOLOGY; BRIGHTNESS; CHEMICAL PROCEDURES; COMPLEX FORMATION; CROSS ALLERGY; DIAGNOSTIC IMAGING; ENZYMIC BIOSENSOR; FLAME PHOTOMETRY; FOOD PACKAGING; IMAGE PROCESSING; LUMINESCENCE; MARINE BIOLOGY; MOLECULAR INTERACTION; MOLECULAR PROBE; MOLECULAR STABILITY; NONHUMAN; OPTICAL OXYGEN SENSOR; OXYGEN CONCENTRATION; OXYGEN QUENCHING; PHOTODYNAMICS; PHOTOLUMINESCENCE; PHOTOPHYSICS; PHYSICS; PRIORITY JOURNAL; PULSE OXIMETRY; REVIEW; SENSOR; SOLUBILITY; TOXICITY TESTING;

EID: 84870799551     PISSN: 18672086     EISSN: 18672094     Source Type: Book Series    
DOI: 10.1007/s12566-012-0032-y     Document Type: Review

References (260)

1. Alava-Moreno F, Valencia-Gonzalez MJ, Sanz-Medel A, Diaz-Garcia ME (1997) Oxygen sensing based on the room temperature phosphorescence intensity quenching of some lead-8-hydroxyquinoline complexes. Analyst 122: 807-810.
2. Alford PC, Cook MJ, Lewis APMGSG, Skarda V, Thomson AJ, Glasper JL, Robbins DJ (1985) Luminescent metal complexes. Part 5. Luminescence properites of ring-substituted 1, 10-phenanthroline tris-complexes of ruthenium (II). J Chem Soc Perkin Trans 2: 705-709.
3. Amao Y (2003) Probes and polymers for optical sensing of oxygen. Mikrochim Acta 143(1): 1-12.
4. Amao Y, Asai K, Okura I (1999) Photoluminescent oxygen sensing using palladium tetrakis(4-carboxyphenyl)porphyrin self-assembled membrane on alumina. Anal Commun 36(5): 179-180.
5. Amao Y, Asai K, Okura I (2000) Oxygen sensing based on lifetime of photoexcited triplet state of platinum porphyrin-polystyrene film using time-resolved spectroscopy. J Porphyrins Phthalocyanines 4: 292-299.
6. Amao Y, Asai KOI, Shinohara H, Nishide H (2000) Platinum porphyrin embedded in poly(1-trimethylsilyl-1-propyne) film as an optical sensor for trace analysis oxygen. Analyst 125: 1911-1914.
7. Amao Y, Ishikawa Y, Okura I (2001) Green luminescent iridium(III) complex immobilized in fluoropolymer film as optical oxygen-sensing matrial. Anal Chem Acta 445: 177-182.
8. Amao Y, Ishikawa Y, Okura I, Miyashita T (2001) Optical oxygen sensing material: terbium(III) complex adsorbed thin film. Bull Chem Soc Jpn 74: 2455-2449.
9. Amao Y, Miyashita T, Okura I (2000) Optical oxygen sensing based on the luminescence change of metalloporphyrins immobilized in styrene-pentafuorostyrene copolymer film. Analyst 125: 871-875.
10. Amao Y, Okura I (2000) An oxygen sensing system based on the phosphorescence quenching of metalloporohyrin thin film on allumina plates. Analyst 125: 1601-1604.
11. Amao Y, Okura I (2003) Optical oxygen sensing materials: chemisorption film of ruthenium(II) polypyridyl complexes attached to anionic polymer. Sens Actuators B 88: 162-167.
12. Amao Y, Okura I, Miyashita T (2000) Optical oxygen sensing based on the luminescence quenching of Europium(III) complex immobilized in fluoropolymer film. Bull Chem Soc Jpn 73: 2663-2668.
13. Amao Y, Okura I, Miyashita T (2001) Pyrene chemisorption film on an alumina plate as an optical oxygen-sensing material. Bull Chem Soc Jpn 74: 1159-1160.
14. Amao Y, Tabuchi Y, Yamashita Y, Kimura K (2002) Novel optical oxygen sensing material: metalloporphyrin dispersed in fluorinated poly(aryl ether ketone) films. Eur Polym J 38: 675-681.
15. Anni M, Rella R (2010) Oxygen optical gas sensing by reversible fluorescence quenching in photo-oxidized poly(9, 9-dioctylfluorene) thin films. J Phys Chem B 114: 1559-1561.
16. Arain S, Gernot JT, Krause C, Gerlach J, Wolfbeis OS, Klimant I (2006) Characterization of microtiterplates with integrated optical sensors for oxygen and pH, and their applications to enzyme activity screening, respirometry, and toxicological assays. Sensors Actuators B Chem 113(2): 639-648.
17. Babilas P, Lamby P, Prantl L, Schreml S, Jung EM, Liebsch G, Wolfbeis OS, Landthaler M, Szeimies R-M, Abels C (2008) Transcutaneous pO2 imaging during tourniquet-induced forearm ischemia using planar optical oxygen sensors. Skin Res Technol 14(3): 304-311.
18. Badocco D, Mondin A, Pastore P, Voltolina S, Gross S (2008) dependence of calibration sensitivity of a polysulfone/Ru(II)-tris(4, 7-diphenyl-1. 10-phenanthroline)-based oxygen optical sensor on its structural parameters. Anal Chem Acta 627: 239-246.
19. Baldini F, Bacci M, Cosi F, Bianco ADB (1992) Absorption-based optical-fibre oxygen sensor. Sens Actuators B 7: 752-757.
20. Basu BJ, Anandan C, Rajam KS (2003) Study of the mechanism of degradation of pyrene-based pressure sensitive paints. Sens Actuators B 94(3): 257-266.
21. Basu BJ, Thirumurugan A, Dinesh AR, Anandan C, Rajam K (2005) Optical oxygen sensor coating based on the fluorescence quenching of a new pyrene derivative. Sens Actuators B 104(1): 15-22.
22. Bergman I (1968) Rapid-response atmospheric oxygen monitor based on fluorescence quenching. Nature 218: 396.
23. Bizzarri A, Koehler H, Cajlakovic M, Pasic A, Schaupp L, Klimant I, Ribitsch V (2006) Continuous oxygen monitoring in subcutaneous adipose tissue using microdialysis. Anal Chim Acta 573-574: 48-56.
24. Borisov SM, Klimant I (2007) Ultrabright oxygen optodes based on cyclometalated iridium(III) coumarin complexes. Anal Chem 79: 7501-7509.
25. Borisov SMLP, Klimant I (2011) Novel optical trace oxygen sensors based on platinum(II) and palladium(II) complexes with 5, 10, 15, 20-meso-tetrakis-(2, 3, 4, 5, 6-pentafluorphenyl)-porphyrin covalently immobilized on silica-gel particles. Anal Chim Acta 690(1): 108-115.
26. Borisov S, Klimant I (2012) New luminescent oxygen-sensing and temperature-sensing materials based on gadolinium(III) and europium(III) complexes embedded in an acridone/polystyrene conjugate. Anal Bioanal Chem. doi: 10. 1007/s00216-012-6244-8.
27. Borisov SM, Nuss G, Haas W, Saf R, Schmuck M, Klimant I (2009) New NIR-emitting complexes of platinum(II) and palladium(II) with fuorinated benzoporphyrins. J Photochem Photobio A 201: 128-135.
28. Borisov SM, Nuss G, Klimant I (2008) Red light-excitable oxygen sensing materials based on platinum(II) and palladium(II) benzoporphyrins. Anal Chem 80(24): 9435-9442.
29. Borisov SM, Wolfbeis OS (2006) Temperature-sensitive europium(III) probes and their use for simultaneous luminescent sensing of temperature and oxygen. Anal Chem 78(14): 5094-5101.
30. Borisov SM, Wolfbeis OS (2008) Optical biosensors. Chem Rev 108(2): 423-461.
31. Borisov SM, Zenkl G, Klimant I (2010) Phosphorescent platinum(II) and palladium(II) complexes with azatetrabenzoporphyrins-new red laser diode-compatible indicators for optical oxygen sensing. ACS App Mater Interfaces 2(2): 366-374.
32. Brinas RP, Troxler T, Hochstrasser RM, Vinogradov SA (2005) Phosphorescent oxygen sensor with dendritic protection and two-photon absorbing antenna. J Am Chem Soc 127(33): 11851-11862.
33. Burke CS, Moore JP, Wencel D, McEvoy AK, MacCraith BD (2008) Breath-by-breath measurement of oxygen using a compact optical sensor. J Biomed Opt 13(no. 1): 014027.
34. Cao Y, Koo Y-EL, Kopelman R (2004) Poly(decyl methacrylate)-based fluorescent PEBBLE swarm nanosensors for measuring dissolved oxygen in biosamples. Analyst 129(8): 745-750.
35. Carraway ER, Demas JN, DeGraff BA (1991) Luminescence quenching mechanism for microheterogeneous systems. Anal Chem 63(4): 332-336.
36. Cattaneo MV, Male KB, Luong JHT (1992) A chemiluminescence fiber-optic biosensor system for the determination of glutamine in mammalian cell cultures. Biosens Bioelec 7(8): 569-574.
37. Ceroni P, Lebedev AY, Marchi E, Yuan M, Esipova TV, Bergamini G, Wilson DF, Busch TM, Vinogradov SA (2011) Evaluation of phototoxicity of dendritic porphyrin-based phosphorescent oxygen probes: an in vitro study. Photochem Photobiol Sci 10(6): 1056-1065.
38. Chan C-M, Chan M-Y, Zhang M, Lo W, Wong K-Y (1999) The performance of oxygen sensing films with ruthenium-adsorbed fumed silica dispersed in silicone rubber. Analyst 124: 691-694.
39. Chang G, Morigaki K, Tatsu Y, Hikawa T, Goto T, Imaishi H (2011) Vertically integrated human P450 and oxygen sensing film for the annays of P450 metabolic activity. Anal Chem 83: 2956-2963.
40. Choi MF, Hawkins P (1995) A novel oxygen and/or carbon dioxide-sensitive optical transducer. Talanta 42(3): 483-492.
41. Choi MF, Hawkins P (1996) A fibre-optic oxygen sensor based on contact charge-transfer absorption. Sens Actuators B 30(3): 167-171.
42. Choi MMF, Pang WSH, Xiao D, Wu X (2001) An optical glucose biosensor with eggshell membrane as an enzyme immobilization platform. Analyst 126: 1558-1563.
43. Choi NW, Verbridge SS, Williams RM, Chen J, Kim J-Y, Schmehl R, Farnum CE, Zipfel WR, Fischbach C, Stroock AD (2012) Phosphorescent nanoparticles for quantitative measurements of oxygen profiles in vitro and in vivo. Biomaterials 33(9): 2710-2722.
44. Chu C-S, Lo Y-L (2010) 2D full-field measurement of oxygen concentration based on the phase fluorometry technique that uses the four-frame integrating-bucket method. Sens Actuators B 147(1): 310-315.
45. Chu C-S, Lo Y-L (2011) Highly sensitive and linear calibration optical fiber oxygen sensor based on Pt(II) complex embedded in sol-gel matrix. Sens Actuators B 155(1): 53-57.
46. Clark HA, Barker SL, Brasuel M, Miller MT, Monson E, Parus S, Shi Z-Y, Song A, Thorsrud B, Kopelman R, Ade A, Meixner W, Athey B, Hoyer M, Hill D, Lightle R, Philbert MA (1998) Subcellular optochemical nanobiosensors: probes encapsulated by biologically localised embedding (PEBBLEs). Sens Actuators B 51: 12-16.
47. Collman JP, Brauman JI, Doxsee KM, Halbert TR, Hayes SE, Suslick KS (1978) Oxygen binding to cobalt porphyrins. J Am Chem Soc 100(9): 2761-2766.
48. Cook MJ, Lewis AP, McAuliffe GSG, Skarda V, Thomson AJ, Glasper JL, Robbins DJ (1984) Luminescent metal complexes. Part 1. Tris-chelate of substituted 2, 2′-bipyriydyls with ruthenium(II) as dyes for luminescent solar collectors. J Chem Soc Perkin Trans II 1293-1301.
49. Cook PLM, Wenzhöfer F, Glud RN, Janssen F, Huettel M (2007) Benthic solute exchange and carbon mineralization on two shallow subtidal sandy sediments: effect of advective pore-water exchange. Limnol Oceanogr 5(52): 1943-1963.
50. Costa-Fernandez JM, Diaz-Garcia ME, Sanz-Medel A (1998) Sol-gel immobilized room-temperature phosphorescent metal-chelate as luminescent oxygen sensing material. Anal Chem Acta 360: 17-26.
51. Coyle LM, Gouterman M (1999) Correcting lifetime measurements for temperature. Sens Actuators B 61: 92-99.
52. Currie MJ, Mapel JK, Heidel TD, Goffri S, Baldo MA (2008) High-efficiency organic solar concentrators for photovoltaics. Science 321(5886): 226-228.
53. Dawson WR, Kropp JL (1969) Radiationless deactivation and anomalous fluorescence of singlet 1, 12-benzperylene. J Phys Chem 73(no. 6): 1752-1758.
54. Del Bianco A, Baldini F, Bacci M, Klimant I, Wolfbeis OS (1993) A new kind of oxygen-sensitive transducer based on an immobilized metallo-organic compound. Sens Actuators B 11: 347-350.
55. DeRosa MC, Hodgson DJ, Enright GD, Dawson B, Evans CEB, Crutchley RJ (2004) Iridium luminophore complexes for unimolecular oxygen sensors. J Am Chem Soc 126(24): 7619-7626.
56. Djurovich PI, Murphy D, Thompson ME, Hernandez B, Gao R, Hunt PL, Selke M (2007) Cyclometalated iridium and platinum complexes as singlet oxygen photosenitizers: quantum yields, queching rates and correlation with electronic strucures. Dalton Trans 34: 3763-3770.
57. Dmitriev RI, Ropiak HM, Ponomarev GV, Yashunsky DV, Papkovsky DB (2011) Cell-penetrating conjugates of coproporphyrins with oligoarginine peptides: rational design and application for sensing intracellular O2. Bioconjugate Chem 22(12): 2507-2518.
58. Dmitriev RI, Zhdanov AV, Ponomarev GV, Yashunski DV, Papkovsky DB (2010) Intracellular oxygen-sensitive phosphorescent probes based on cell-penetrating peptides. Anal Biochem 398(1): 24-33.
59. Donckt EV, Camerman B, Vandeloise (1996) Fibre-optic oxygen sensor based on luminescence quenching of a Pt(II) complex embedded in polymer matrices. Sens Actuators B 32: 121-127.
60. Douglas P, Eaton K (2002) Response characteristics of thin film oxygen sensors, Pt and Pd octaethylporphyrins in polymer films. Sens Actuators B 82(2-3): 200-208.
61. Draxler S, Lippitsch ME, Klimant I, Kraus H, Wolfbeis OS (1995) Effects of polumer matrices on the time-resolved luminescence of a ruthenium complex quenched by oxygen. J Phys Chem 99: 3162-3167.
62. Dremel B, Li S-Y, Schmid R (1992) On-line determination of glucose and lactate concentrations in animal cell culture based on fibre optic detection of oxygen in flow-injection analysis. Biosens Bioelecron 7(2): 133-139.
63. Dunphy I, Vinogradov SA, Wilson D (2002) Oxyphor R2 and G2: phosphors for measuring oxygen by oxygen-dependent quenching of phosphorescence. Anal Biochem 310(2): 191-198.
64. Eastwood D, Gouterman M (1970) Porphyrins: XVIII. Luminescence of (Co), (Ni), Pd, Pt complexes. J Mol Spectrosc 35(3): 359-375.
65. Erskine RW, Field BO (1976) Reversible oxygenation. Struc Bond 28: 1-50.
66. Esipova TV, Karagodov A, Miller J, Wilson DF, Busch TM, Vinogradov SA (2011) Two New "protected" oxyphors for biological oximetry: properties and application in tumor imaging. Anal Chem 83(22): 8756-8765.
67. Fabricius-Dyg J, Mistlberger G, Staal M, Borisov SM, Klimant I, Kühl M (2012) Imaging of surface O2 dynamics in corals with magnetic micro optode particles. Mar Biol 159(7): 1621-1631.
68. Feng N, Xie J, Zhang D (2010) Synthesis, characterization, photophysical and oxygen-sensing properties of a novel europium(III) complex. Spectrochim Acta A 77(1): 292-296.
69. Fercher A, Borisov SM, Zhdanov AV, Klimant I, Papkovsky DB (2011) Intracellular O2 sensing probe based on cell-penetrating phosphorescent nanoparticles. ACS Nano 5(7): 5499-5508.
70. Filatov MA, Cheprakov AV (2011) The synthesis of new tetrabenzo- and tetranaphthoporphyrins via the addition reactions of 4, 7-dihydroisoindole. Tetrahedron 67(19): 3559-3566.
71. Finikova OS, Aleshchenkov SE, Brñas RP, Cheprakov AV, Carroll PJ, Vinogradov SA (2005) Synthesis of symmetrical tetraaryltetranaphtho[2, 3]porphyrins. J Org Chem 70(12): 4617-4628.
72. Finikova OS, Cheprakov AV, Carroll PJ, Vinogradov SA (2003) Novel route to functionalized tetraaryltetra[2, 3]naphthaloporphyrins via oxidative aromatization. J Org Chem 68: 7517-7520.
73. Finikova OS, Cheprakov AV, Vinogradov SA (2005) Synthesis and luminescence of soluble meso-unsunbstituted tetrabenzo- and tetranaphtho[2, 3]porphyrins. J Org Chem 70: 9562-9572.
74. Finikova OS, Lebedev AY, Aprelev A, Troxler T, Gao F, Garnacho C, Muro S, Hochstrasser RM, Vinogradov SA (2008) Oxygen microscopy by two-photon-excited phosphorescence. ChemPhysChem 9(12): 1673-1679.
75. Fischer JPWF (2010) A novel planar optode setup for concurrent oxygen and light field imaging: application to a benthic phototrophic community. Limnol Oceanogr Meth 8: 254-268.
76. Fischer LH, Borisov SM, Schaeferling M, Klimant I, Wolfbeis OS (2010) Dual sensing of pO2 and temperature using a water-based and sprayable fluorescent paint. Analyst 135: 1224-1229.
77. Fischer LH, Stich MIJ, Wolfbeis OS, Tian N, Holder E, Schäferling M (2009) Red- and green-emitting iridium(III) complexes for a Dua barometric and temperature-sensitive paint. Chem Eur J 15: 10857-10863.
78. Fujiwara Y, Amao Y (2004) Novel optical oxygen sensing material: 1-pyrenedecanoic acid and perfuorodecanoic acid chemisorbed onto anodic oxidized aluminium plate. Sens Actuators B 99: 130-133.
79. Ge X, Hanson M, Shen H, Kostov Y, Brorson KA, Frey DD, Moreira AR, Rao G (2006) Validation of an optical sensor-based high-throughput bioreactor system for mammalian cell culture. J Biotechnol 122(3): 293-306.
80. Gernot TJ, Klimant I, Wittmann C, Heinzle E (2003) Integrated optical sensing of dissolved oxygen in microtiter plates: a novel tool for microbial cultivation. Biotechnol Bioeng 81(7): 829-836.
81. Ghosh RN, Askeland PA, Kramer S, Loloee R (2011) Optical dissolved oxygen sensor utilizing molybdenum chloride cluster phosphorescence. Appl Phys Lett 98: 221103-3.
82. Ghosh RN, Baker GL, Ruud C, Nocera D (1999) Fiber-optic oxygen sensor using molybdenum chloride cluster luminescence. Appl Phys Lett 75(19): 2885-2887.
83. Gillanders RN, Tedford MC, Crilly PJ, Bailey RT (2005) A composite thin film optical sensor for dissolved oxygen in contaminated aqueous environments. Anal Chem Acta 545: 189-194.
84. Glud RN, Kühl MRN (1999) Heterogeneity of oxygen production and consumption in a photosynthetic microbial mat as studied by planar optodes. J Phycol 35: 270-279.
85. Glud RN, Ramsing NB, Gundersen JK, Klimant I (1996) Planar optrodes: a new tool for fine scale measurements of two dimensional O2 distribution in bethic communities. Mar Ecol Prog Ser 140: 217-226.
86. Glud RN, Tengberg A, Kühl M, Hall POJ, Klimant I (2001) An in situ instrument for planar O2 optode measurements at benthic interfaces. Limnol Ocenogr 46(8): 2073-2080.
87. Guo L, Ni Q, Li J, Zhang L, Lin X, Xie Z, Chen G (2008) A novel sensor based on the porous plastic probe for determitation of dissolved oxygen in seawater. Talanta 74: 1032-1037.
88. Haitao J, Huilin Y, Fan L, Yang L (2012) Fabrication and performances of an optical sensor system constructed by a novel Cu(I) complex embedded on silica matrix. J Lumin 132: 198-204.
89. Hanson MA, Ge X, Kostov Y, Brorson KA, Moreira AR, Rao G (2007) Comparisons of optical pH and dissolved oxygen sensors with traditional electrochemical probes during mammalian cell culture. Biotechnol Bioeng 97(4): 833-841.
90. Hanson K, Tamayo A, Diev VV, Whited MT, Djurovich PI, Thompson ME (2010) Efficient dipyrrin-centered phosphorescence at room temperature from bis-cyclometalated iridium(III) dipyrrinato complexes. Inorg Chem 49(13): 6077-6084.
91. Hartmann P, Leiner MJP, Lippitsch ME (1995) Luminescence quenching behavior of an oxygen sensor based on a Ru(II) complex dissolved in polystyrene. Anal Chem 67(1): 88-93.
92. Hartmann P, Ziegler W, Holst G, Lübbers DW (1997) Oxygen flux fluorescence lifetime imaging. Sens Actuators B 38: 110-115.
93. He H, Fraatz RJ, Leiner MJP, Rehn MM, Tusa JK (1995) Selection of silicone polymer matrix for optical gas sensing. Sens Actuators B 29: 246-250.
94. Higgins C, Wencel D, Burke CS, MacCraith BD, McDonagh C (2007) Novel hybrid optical sensor materials for in-breath O2 analysis. Analyst 133: 241-247.
95. Holst G, Grundwald B (2001) Luminescence lifetime imaging with transparent oxygen optodes. Sens Actuators B 74: 78-90.
96. Holst G, Kohls O, Klimant I, König B, Kühl M, Richter T (1998) A modular luminescence lifetime imaging system for mapping oxygen distribution in biological samples. Sens Actuators B 51: 163-170.
97. Imasaka T, Ishibashi K, Ishibashi N (1982) Time-resolved fluorimetry with a sub-nanosecond dye laser source for the determination of polynuclear aromatic hydrocarbons after separation by high-performance liquid chromatography. Anal Chim Acta 142: 1-12.
98. Jensen ST, Kühl M, Glud RN, Jørgensen BB, Prieme A (2005) Oxic microzones and radial oxygen loss from roots of Zostera marina. Mar Ecol Prog Ser 293: 49-58.
99. Jones PF (1968) On the use of phosphorescence quenching for determining permeabilities of polymeric films to gases. J Polym Sci B Polym Lett 6(7): 487-491.
100. Kautsky H (1939) Quenching of luminescence by oxygen. Trans Faraday Soc 35: 216-219.
101. Kellner K, Liebsch G, Klimant I, Wolfbeis OS, Blunk T, Schulz MB, Göpferich A (2002) Determination of oxygen gradients in engineered tissue using a fluorescent sensor. Biotechnol Bioeng 80(1): 73-83.
102. Khalil G, Gouterman M, Ching S, Costin C, Coyle L, Gouin S, Green E, Sadilek M, Wan R, Yearyean J, Zelelow B (2002) Synthesis and spectroscopic characterization of Ni, Zn, Pd and Pt tetra(pentafuorophenyl)porpholactone with comparison to Mg, Zn, Y, Pd and Pt metal complexes of tetra(pentafuorophenyl)porphine. J Porphyrins Phthalocynines 6: 135-145.
103. Klimant I, Belser P, Wolfbeis OS (1994) Novel metal-organic ruthenium(II) diimin complexes for use as longwave excitable luminescent oxygen probes. Talanta 41(6): 985-991.
104. Klimant I, Kühl M, Glud R, Holst G (1997) Optical measurement of oxygen and temperature in microscale: strategies and biological applications. Sens Actuators B 38(1-3): 29-37.
105. Klimant I, Meyer V, Kühl M (1995) Fiberoptic oxygen microsensors, a new tool in aquatic biology. Limnol Oceanogr 40: 1159-1165.
106. Klimant I, Ruckruh F, Liebsch G, Stangelmayer A, Wolfbeis OS (1999) Fast response oxygen micro-optodes based on novel soluble ormosil glasses. Mikrochim Acta 131(1): 35-46.
107. Klimant I, Wolfbeis OS (1995) Oxygen-sensitive luminescent materials based on silicone-soluble ruthenium diimine complexes. Anal Chem 67: 3160-3166.
108. Knopp JA, Longmuir IS (1972) Intracellular measurement of oxygen by quenching of fluorescence of pyrenebutyric acid. Biochim Biophys Acta 279: 393-397.
109. Kober EM, Caspar JV, Lumpkin RS, Meyer TJ (1986) Application of the energy gap law to excited-state decay of osmium(II)-polypyridine complexes: calculation of relative nonradiative decay rates from emission spectral profiles. J Phys Chem 90(16): 3722-3734.
110. Kocincova AS, Nagl S, Arain S, Krause C, Borisov SM, Arnold M, Wolfbeis OS (2008) Multiplex bacterial growth monitoring in 24-well microplates using a dual optical sensor for dissolved oxygen and pH. Biotechnol Bioeng 100(no. 3): 430-438.
111. Kolle C, Gruber W, Trettnak WBK, Dolezal C, Reininger F (1997) Fast optochemical sensor for continuous monitoring of oxygen in breath-gas analysis. Sens Actuators B 38-39: 141-149.
112. König B, Kohls O, Holst G, Glud RN, Kühl M (2005) Fabrication and test of sol-gel based planar oxygen optodes for use in aquatic sediments. Mar Chem 97: 262-276.
113. Koo Y-EL, Cao Y, Kopelman R, Koo SM, Brasuel M, Philbert MA (2004) Real-time measurements of dissolved oxygen inside live cells by organically modified silicate fluorescent nanosensors. Anal Chem 76(9): 2498-2505.
114. Koren K, Borisov SMKI (2012) Stable optical oxygen sensing materials based on click-coupling of fluorinated platinum(II) and palladium (II) porphyrins-a convenient way to eliminate dye migration and leaching. Sens Actuators B 169: 173-181.
115. Koren K, Borisov SM, Saf R, Klimant I (2011) Strongly phosphorescent iridium(III)-porphyrins-new oxygen indicators with tuneable photophysical properties and functionalities. Eur J Inorg Chem 2011(no. 10): 1531-1534.
116. Koren K, Dmitriev RI, Borisov SM, Papkovsky DB, Klimant I (2012) Complexes of IrIII-octaethylporphyrin with peptides as probes for sensing cellular O2. ChemBioChem 13(8): 1184-1190.
117. Köse ME, Crutcheley RJ, DeRosa MC, Ananthakrishnan N, Reynolds JR, Schanze KS (2005) Morphology and oxygen sensor response of luminescent Ir-labeled poly(dimethylsiloxane)/polystyrene polymer blend films. Langmuir 21: 8255-8262.
118. Kostov Y, Harms P, Pilato RS, Rao G (2000) Ratiometric oxygen sensing: detection of dual-emission ratio through a single emission filter. Analyst 125(6): 1175-1178.
119. Kuhl Y, Cohen T, Dalsgaard B, Jorgensen B, Reversbech NP (1995) Microenvironment and photosynthesis of zooxanthellea in scleractinian corals studied with microsensors for O2, pH and light. Mar Ecol Prog Ser 117: 159-172.
120. Kühl G, Larkum AWD, Ralph P (2008) Imaging of oxygen dynamics within the endolithic algal community of the massive coral porites lobata. J Phycol 44: 541-550.
121. Kühl M, Polerecky L (2008) Functional and structural imaging of phototrophic microbial communities and symbioses. Aquat Microb Ecol 53: 99-118.
122. Kunkely H, Vogler A (1990) Photoluminescence of platinum complex [PtII(4, 7-diphenyl-1, 10-phenanthroline)(CN)2] in solution. J Am Chem Soc 112(14): 5625-5627.
123. Lai S-W, Hou Y-J, Che C-M, Pang H-L, Wong K-Y, Chang CK, Zhu N (2004) Electronic spectroscopy, photophysical properties, and emission quenching studies of an oxydatively robust perfuorinated platinum porphyrin. Inorg Chem 43: 3724-3732.
124. Lakowicz JR (2006) Principle of fluorescence spectroscopy. Springer, Baltimore.
125. Lakowicz JR, Berndt K (1991) Lifetime-selective fluorescence imaging using a RF phase sensitive camera. Rev Sci Instrum 62: 1727-1734.
126. Lamansky S, Djurovich P, Murphy D, Abdel-Razzaq F, Lee H-E, Adachi C, Burrows PE, Forrest SR, Thompson ME (2001) Highly phosphorescent bis-cyclometalated iridium complexes: synthesis, photophysical characterization, and use in organic light emitting diodes. J Am Chem Soc 123(18): 4304-4312.
127. Larkum A, Koch E, Kühl M (2003) Diffusive boundary layers and photosynthesis of teh epilithic algal community of coral reefs. Mar Biol 142: 1073-1082.
128. Larsen M, Borisov SM, Grundwald B, Klimant I, Glud RN (2011) A simle and inexpensive high resolution color ratiometric planar optode imaging approach: application to oxygen and pH sensing. Limnol Oceanogr Meth 9: 348-360.
129. Law G-L, Pal R, Palsson LO, Parker D, Wong K-L (2009) Responsive and reactive terbium complexes with an azaxanthone sensitiser and one naphthyl group: applications in ratiometric oxygen sensing in vitro and in regioselective cell killing. Chem Commun 47: 7321-7323.
130. Lebedev AY, Cheprakov AV, Sakadzic S, Boas DA, Wilson DF, Vinogradov SA (2009) Dendritic phosphorescent probes for oxygen imaging in biological systems. ACS Appl Mater Interfaces 1(6): 1292-1304.
131. Lecoq J, Parpaleix A, Roussakis E, Ducros M, Houssen YG, Vinogradov SA, Charpak S (2011) Simultaneous two-photon imaging of oxygen and blood flow in deep cerebral vessels. Nat Med 17(7): 893-898.
132. Lee S-K, Okura I (1997) Optical sensor for oxygen using a porphyrin-doped sol-gel glass. Analyst 122: 81-84.
133. Lee S-K, Okura I (1997) Porphyrin-doped sol-gel glass as a probe for oxygen sensing. Anal Chem Acta 342: 181-188.
134. Lee S-K, Okura I (1997) Photostable optical oxygen sening material: platinum tetrakis(pentafluorophenyl)porphyrin immobilized in polystyrene. Anal Comm 34: 185-188.
135. Lee Y-EK, Ulbrich EE, Kim G, Hah H, Strollo C, Fan W, Gurjar R, Koo S, Kopelman R (2010) Near infrared luminescent oxygen nanosensors with nanoparticle matrix tailored sensitivity. Anal Chem 82(20): 8446-8455.
136. Li X, Rosenzweig Z (1997) A fiber optic sensor for rapid analysis of bilirubin in serum. Anal Chim Acta 353: 263-273.
137. Li L, Walt DR (1995) Dual-analyte fiber-optic sensor for the simultaneous and continuous measurement of glucose and oxygen. Anal Chem 67(20): 3746-3752.
138. Li S, Zhao X (2011) Oxygen sensing nanofibers doped with red-emitting Eu(III) complex: synthesis, characterization, machanism, and sensing performance. Synth Met 161: 737-742.
139. Liebsch G, Klimant I, Frank B, Holst G, Wolfbeis OS (2000) Luminescence lifetime imaging of oxygen, pH, and carbon dioxide distribution using optical sensors. Appl Spectrosc 54(4): 548-559.
140. Liebsch G, Klimant I, Wolfbeis OS (1999) Luminescence lifetime temperature sensing based on sol-gels and poly(acrylonitrile)s dyed with ruthenium metal-ligand complexes. Adv Mater 11(15): 1296-1299.
141. Lin C-T, Böttcher M, Creutz C, Sutin N (1976) Mechanism of the quenching of the emission of substituted polypyridineruthenium(II) complexes by Iron(III), chromium(III) and europium(III) ions. J Am Chem Soc 98: 6536-6544.
142. Lippitsch ME, Pusterhofer J, Leiner MJP, Wolfbeis OS (1988) Fibre-optic oxygen sensor with the fluorescence decay time as the infomation carrier. Anal Chim Acta 205: 1-6.
143. Liu Y, Guo H, Zhao J (2011) Ratiometric luminescent molecular oxygen sensors based on uni-luminophores of C[caret]N Pt(II)(acac) complexes that show intense visible-light absorption and balanced fluorescence/phosphorescence dual emission. Chem Comm 47(41): 11471-11473.
144. Liu Y-M, Pereoro-Garcia R, Valencia-Gonzalez MJ, Diaz-Gracia ME, Sanz-Medel A (1994) Evaluation of some immobilized room-temperature phosphorescent metal chelates as sensing materials for oxygen. Anal Chem 66: 836-840.
145. Liu X, Sun W, Zou L, Xie Z, Li X, Lu C, Wang L, Cheng Y (2012) Neutral cuprous complexes as ratiometric oxygen gas sensors. Dalton Trans 41(4): 1312-1319.
146. Lo L-W, Koch CJ, Wilson DF (1996) Calibration of oxygen-dependent quenching of the phosphorescence of Pd-meso-tetra(4-carboxyphenyl)porphine: a phosphor with general application for measuring oxygen concentration in biological systems. Anal Biochem 236: 153-160.
147. MacCraith BD, Mc Donagh CM, O'Keffe G, Keyes ET, Vos JG, O'Kelly B, McGilp JF (1993) Fibre optic oxygen sensor based on fluorescence quenching of evanescent-wave excited ruthenium complexes in sol-gel derived porous coatings. Analyst 118: 385-388.
148. Mack J, Asano Y, Kobayashi N, Stillman MJ (2005) Application of MCD spectroscopy and TD-DFT to a highly non-planar porphyrinoid ring system. New insights on red-shifted porphyrinoid spectral bands. J Am Chem Soc 127(50): 17697-17711.
149. Mak CSK, Pentlehner D, Stich M, Wolfbeis OS, Chan WK, Yersin H (2009) Exceptional oxygen sensing capabilities and triplet state properties of Ir(ppy-NPh2)3. Chem Mater 21(11): 2173-2175.
150. Marazuela MD, Moreno-Bondi MC (1998) Determination of choline-containing phospholipids in serum with a fiber-optic biosensor. Anal Chim Acta 374(1): 19-29.
151. Mayr T, Borisov SM, Abel T, Enko BWK, Mistlberger G, Klimant I (2009) Light harvesting as a simple and versatile way to enhance brightness of luminescent sensors. Anal Chem 81: 6541-6545.
152. McDonagh C, Bowe P, Mongey KMBD (2002) Characterization of porosity and sensor response times of sol-gel-derived thin films for oxygen sensor application. J Non-Cryst Solids 306: 138-148.
153. McDonagh C, Burke CS, MacCraith BD (2008) Optical chemical sensors. Chem Rev 108(2): 400-422.
154. Mcevoy AK, McDonagh C, MacCraith BD (1997) Optimization of sol-gel-derived silica films for optical oxygen sensing. J Sol-Gel Sci Technol 8: 1121-1125.
155. McLaurin EJ, Greytak AB, Bawendi MG, Nocera DG (2009) Two-photon absorbing nanocrystal sensors for ratiometric detection of oxygen. J Am Chem Soc 131: 12994-13001.
156. McLean TM, Moody JL, Waterland MR, Telfer SG (2012) Luminescent rhenium(I)-dipyrrinato complexes. Inorg Chem 51: 446-455.
157. Medina-Castillo AL, Fernandez-Sanchez JF, Klein C, Nazeeruddin MK, Segura-Carretero A, Fernandez-Gutierrez A, Graetzel M, Spichiger-Keller UE (2007) Engineering of efficient phosphorescent iridium cationic complex for developing oxygen-sensitive polymeric and nanostructured films. Analyst 132(9): 929-936.
158. Meier RJ, Schreml S, Wang X-d, Landthaler M, Babilas P, Wolfbeis OS (2011) Simultaneous photographing of oxygen and pH in vivo using sensor films. Angew Chem Int Ed 50(no. 46): 10893-10896.
159. Meier B, Werner T, Klimant I, Wolfbeis OS (1995) Novel oxygen sensor material based on a ruthenium bipyridyl complex encapsulated in zeolite Y: dramatic differences in the efficiency of luminescence quenching by oxygen on going from surface-adsorbed to zeolite-encapsulated fluorophores. Sen Actuators B 29: 240-245.
160. Millikan GA (1942) The oximeter, an instrument for measuring continuously the oxygen saturation of arterial blood in man. Rev Sci Instr 13(10): 434-444.
161. Mills A (1999) Response characteristics of optical sensors for oxygen: a model based on a distribution in [small tau]oand kq. Analyst 124(9): 1309-1314.
162. Mills A, Lawrie K, Bardin J, Apedalie A, Skinner GA, O'Rouke C (2012) An O2 smart plastic film for packaging. Analyst 137: 106-112.
163. Mills A, Lepre A, Theobald BRC, Slade E, Murrer BA (1997) Use of luminescent gold compounds in the design of thin-film oxygen sensors. Anal Chem 69: 2842-2847.
164. Mills A, Thomas M (1997) Fluorescence-based thin plastic film ion-pair sensors for oxygen. Analyst 122: 63-68.
165. Mills A, Tommons C, Bailey RT, Crilly P, Tedford MC (2011) Thin-film oxygen sensors using a luminescent polynuclear gold(I) complex. Anal Chem Acta 702: 269-273.
166. Mingoarranz FJ, Moreno-Bondi MC, Garcia-Fresnadillo D, de Dios C, Orellana G (1995) Oxygen-sensitive layers for optical fibre devices. Mikrochim Acta 121: 107-118.
167. Mitsubayashi K, Kon T, Hashimoto Y (2003) Optical bio-sniffer for ethanol vapor using an oxygen-sensitive optical fiber. Biosens Bioelectron 19(3): 193-198.
168. Morin AM, Xu W, Demas JN, DeGraff BA (2000) Oxygen sensors based on quenching of tris-(4, 7-diphenyl-1. 10-phenanthroline)ruthenium(II) in fluorinated polymers. J Fluoresc 10: 7-12.
169. Nagl S, Baleizao C, Borisov SM, Schäferling M, Barberan MN, Wolfbeis OS (2007) Optical sensing and imaging of trace oxygen with record response. Angew Chem Int Ed 46: 2317-2319.
170. Napp J, Behnke T, Fischer L, Würth C, Wottawa M, Katschinski DM, Alves F, Resch-Genger U, Schäferling M (2011) Targeted luminescent near-infrared polymer-nanoprobes for in vivo imaging of tumor hypoxia. Anal Chem 83: 9039-9046.
171. Neugebauer U, Pellegrin Y, Devocelle M, Forster RJ, Signac W, Moran N, Keyes TE (2008) Ruthenium polypyridyl peptide conjugates: membrane permeable probes for cellular imaging. Chem Commun 42(42): 5307-5309.
172. Niedermair F, Borisov SM, Zenkl G, Hofmann OT, Weber H, Saf R, Klimant I (2010) Tunable phosphorescent NIR oxygen indicators based on mixed benzo- and naphthoporphyrin complexes. Inorg Chem 49(no. 20): 9333-9342.
173. Nock V, Blaikie RJ, David T (2008) Patterning, integration and characterization of polymer optical oxygen sensors for microfluidics devices. Lab Chip 8: 1300-1307.
174. O'Riordan TC, Zhdanov AV, Ponomarev GV, Papkovsky DB (2007) Analysis of intracellular oxygen and metabolic responses of mammalian cells by time-resolved fluorometry. Anal Chem 79(24): 9414-9419.
175. Okazaki T, Imasaka T, Ishibashi N (1988) Optical-fiber sensor based on the second-harmonic emission of a near-infrared semiconductor laser as light source. Anal Chim Acta 209: 327-331.
176. Opitz N, Graf H-J, Lübbers DW (1988) Oxygen sensor for the temperature range 300 to 500 K based on fluorescence quenching of indicator-treated silicone rubber membranes. Sens Actuators 13(2): 159-163.
177. Papkovsky DB (1995) New oxygen sensors and their application to biosensing. Sens Actuators B 29(1-3): 213-218.
178. Papkovsky DB, Olah J, Troyanovsky IV, Sadovsky NA, Rumyantseva VD, Mironov AF, Yaropolov AI, Savitsky AP (1992) Phosphorescent polymer films for optical oxygen sensors. Biosens Bioelectron 7(3): 199-206.
179. Papkovsky DB, Ponomarev GV, Trettnak W, O'Leary P (1995) Phosphorescent complexes of phorphyrin ketones: optical properties and application to oxygen sensing. Anal Chem 67: 4112-4117.
180. Park EJ, Reid KR, Tang W, Kennedy RT, Kopelman R (2005) Ratiometric fiber optic sensors for the detection of inter- and intra-cellular dissolved oxygen. J Mater Chem 15(27-28): 2913-2919.
181. Pasic A, Koehler H, Klimant I, Schaupp L (2007) Miniaturized fiber-optic hybrid sensor for continuous glucose monitoring in subcutaneous tissue. Sens Actuators B 122: 60-68.
182. Pasic A, Koehler H, Schaupp L, Pieber T, Klimant I (2006) Fiber-optic flow-through sensor for online monitoring of glucose. Anal Bioanal Chem 386(5): 1293-1302.
183. Peterson JI, Fitzgerald RV, Buckhold DK (1984) Fiber-optic probe for in vivo measurement of oxygen partial pressure. Anal Chem 56(1): 62-67.
184. Polerecky L, Lott C, Weber M (2008) In situ measurement of gross photosynthesis using a microsensor-based light-shade shift method. Limnol Oceanogr Meth 6: 373-383.
185. Pollack M, Pringsheim P, Terwoord D (1944) A method for determining small quantities of oxygen. J Chem Phys 12(7): 295-299.
186. Puklin E, Carlson B, Gouin S, Costin C, Green E, Ponomarev S, Tanji H, Gouterman M (2000) Ideality of pressure-sensitive paint. I. Platinum tetra(pentafluorophenyl)porphine in fluoroacrylic polymer. J Appl Polym Sci 77: 2795-2804.
187. Roberts L, Lines R, Reddy S, Hay J (2011) Investigation of polyviologens as oxygen indicators in food packaging. Sens Actuators B 152: 63-67.
188. Rogers JE, Nguyen KA, Hufnagle DC, McLean DG, Su W, Gossett KM, Burke AR, Vinogradov SA, Pachter R, Fleitz PA (2003) Observation and interpretation of annulated porphyrins: studies on the photophysical properties of meso-tetraphenylmetalloporphyrins. J Phys Chem A 107(51): 11331-11339.
189. Röösli S, Pretsch E, Morf WE, Tsuchida E, Nishide H (1997) Selective optical response to oxygen of membranes based on immobilized cobalt(II) porphyrins. Anal Chim Acta 338: 119-125.
190. Rosenow TC, Walzer K, Leo K (2008) Near-infrared organic light emitting diodes based on heavy metal phthalocyanines. J Appl Phys 103(no. 4): 043105.
191. Rozhkov VV, Khajehpour M, Vinogradov SA (2003) Luminescent Zn and Pd tetranaphthaloporphyrins. Inorg Chem 42(14): 4253-4255.
192. Rumsey WL, Vanderkooi JM, Wilson DF (1988) Imaging of phosphorescence: a novel method for measuring oxygen distribution in perfused tissue. Science 241(4873): 1649-1651.
193. Sacksteder L, Demas JN, DeGraff BA (1993) Design of oxygen sensors based on quenching of luminescent metal complexes: effect of ligand size on heterogeneity. Anal Chem 65(23): 3480-3483.
194. Sacksteder L, Lee M, Demas JN, DeGraff BA (1993) Long-lived, highly luminescent rhenium(I) complexes as molecular probes: intra- and intermolecular excited-state interactions. J Am Chem Soc 115(18): 8230-8238.
195. Sakadzic S, Roussakis E, Yaseen MA, Mandeville ET, Srinivasan VJ, Arai K, Ruvinskaya S, Devor A, Lo EH, Vinogradov SA, Boas DA (2010) Two-photon high-resolution measurement of partial pressure of oxygen in cerebral vasculature and tissue. Nat Meth 7(9): 755-759.
196. Schäferling M (2012) The art of fluorescence imaging with chemical sensors. Angew Chem Int Ed Engl 51(15): 3532-3554.
197. Schaffar BPH, Wolfbeif OS (1990) A fast responding fibre optic glucose biosensor based on an oxygen optrode. Biosens Bioelectron 5(2): 137-148.
198. Schmälzlin E, van Dongen JT, Klimant I, Marmodee B, Steup M, Fisahn J, Geigenberger P, Löhmannsröben H-G (2005) An optical multifrequency phase-modulation method using microbeads for measuring intracellular oxygen concentration in plants. Biophys J 89: 1339-1345.
199. Schneider K, Schütz V, John G, Heinzle E (2010) Optical device for parallel online measurement of dissolved oxygen and pH in shake flask cultures. Bioprocess Biosyst Eng 33(5): 541-547.
200. Schreml S, Meier RJ, Wolfbeis OS, Maisch T, Szeimies RM, Landthaler M, Regensburger J, Santarelli F, Klimant I, Babilas P (2011) 2D luminescence imaging of phystiological wound oxygenation. Exp Dermatol 20(7): 550-554.
201. Schrenkhammer P, Wolfbeis OS (2008) Fully reversible optical biosensors for uric acid using oxygen transduction. Biosens Bioelectron 24: 994-999.
202. Schröder CR, Polerecky L, Klimant I (2007) Time-resolved pH/pO2 mapping with luminescent hybrid sensors. Anal Chem 79(1): 60-70.
203. Severinghaus JW, Honda Y (1987) History of blood gas analysis. VII. Pulse oximetry. J Clin Monit 3: 135-138.
204. Shaw G (1967) Quenching by oxygen diffusion of phosphorescence emission of aromatic molecules in polymethyl methacrylate. Trans Faraday Soc 63: 2181-2189.
205. Smith CS, Branham CW, Marquardt BJ, Mann KR (2010) Oxygen gas sensing by luminescence quenching in crystals of Cu(xantphos)(phen) + complexes. J Am Chem Soc 132: 14079-14085.
206. Smith CS, Mann KR (2012) Exceptionally long-lived luminescence from [Cu(I)(isocyanide)2(phen)] + complexes in nanoporous crystals enables remarkable oxygen gas sensing. J Am Chem Soc 134(21): 8786-8789.
207. Sommer JR, Farley RT, Graham KR, Yang Y, Reynolds JR, Xue J, Schanze KS (2009) Efficient near-infrared polymer and organic light-emitting diodes based on electrophosphorescence from (tetraphenyltetranaphtho[2, 3]porphyrin)platinum(II). ACS Appl Mater Interfaces 1(2): 274-278.
208. Songzhu L, Xiangting D, Jinxian W, Guixia L, Wenshen Y, Roukun J (2010) Fabrication of Eu(III) complex doped nanofibrous membrane and their oxygen-sensitive properties. Spectrochim Acta A 77: 885-889.
209. Spellane PJ, Gouterman M, Kim AAS, Liu YC (1980) Porphyrins 40. Electronic spectra and four-orbital energies of free-base, zinc, copper, and palladium tertrakis(perfluorophenyl)porphyrins. Inorg Chem 19: 386-391.
210. Steiner MS, Duerkop A, Wolfbeis OS (2011) Optical methods for sensing glucose. Chem Soc Rev 40(9): 4805-4839.
211. Steunenberg P, Ruggi A, van den Berg NS, Buckle T, Kuil J, Fijs WB, Velders AH (2012) Phosphorescence imaging of living cells with amino acid-functionalized tris(2-phenylpyridine)iridium(III) complexes. Inorg Chem 51(no. 4): 2105-2114.
212. Stich MI, Borisov SM, Henne U, Schäferling M (2009) Read-out of multiple optical chemical sensors by means of digital color cameras. Sens Actuators B 139(1): 204-207.
213. Stubenrauch K, Sandholzer M, Niedermair F, Waich K, Mayr T, Klimant I, Trimmel G, Slugovc C (2008) Poly(norbornene)s as matrix materials for platinum tetrakis(pentafuorophenyl)porphyrin based optica oxygen sensors. Eur Polym J 44: 2558-2566.
214. Thévenot DR, Toth K, Durst RA, Wilson GS (2001) Electrochemical biosensors: recommended definitions and classification. Biosens Bioelectron 16: 121-131.
215. Thomas P, Halter M, Tona A, Raghavan SR, Plant AL, Forry S (2009) A noninvasive thin film sensor for monitoring oxygen tension during in vitro cell culture. Anal Chem 81(22): 9239-9246.
216. Tian Y, Shumway BR, Meldrum DR (2010) A New cross-linkable oxygen sensor covalently bonded into poly(2-hydroxyethyl methacrylate)-co-polyacrylamide thin film for dissolved oxygen sensing. Chem Mater 22(6): 2069-2078.
217. Trettnak W, Kolle C, Reininger F, Dolezal C, O'Leary P (1996) Miniaturized luminescence lifetime-based oxygen sensor instrumentation utilizing a phase modulation technique. Sens Actuators B 35-36: 506-512.
218. Trettnak W, Leiner MJP, Wolfbeis OS (1988) Optical sensors. Part 34. Fibre optic glucose biosensor with an oxygen optrode as the transducer. Analyst 113(10): 1519-1523.
219. Tusa JK, He H (2005) Critical care analyzer with fluorescent optical chemosensors for blood analytes. J Mater Chem 15(27-28): 2640-2647.
220. van Houten KA, Walters KA, Schanze KS, Pilato RS (2000) Study of the heterocyclic-substituted platinum-1, 2-enedithiolate 3ILCT excited states by transient absorption spectroscopy. J Fluoresc 10(1): 35-40.
221. Vasil'ev VV, Borisov SM (2002) Optical oxygen sensors based on phosphorescent water-soluble platinum metals porphyrins immobilized in perfluorinated ion-exchange membrane. Sensors Actuators B 82(no. 2-3): 272-276.
222. Vasil'ev VV, Borisov SM, Chubarova YO, Rumyantseva VD (2003) Dimerization, aggregation, and luminescent properties of palladium(II) and platinum(II) complexes with meso-tetrakis(4-carboxyphenyl)porphyrin. Russ J Inorg Chem 48(no. 3): 385-390.
223. Vogel A, Venugopalan V (2003) Mechanisms of pulsed laser ablation of biological tissues. Chem Rev 103(2): 577-644.
224. Voraberger HS, Kreimaier H, Biebernik K, Kern W (2001) Novel oxygen optrode withstanding autoclavation: technical solutions and performance. Sens Actuators B 74: 179-185.
225. Wang X, Chen H, Zhou T, Lin Z, Zeng J, Xie Z, Chen X, Wong K, Chen G, Wang X (2009) Optical colorimetric sensor strip for direct readout glucose measurement. Biosens Bioelectron 24(12): 3702-3705.
226. Wang Y, Li B, Zhang L, Zuo Q, Li P, Zhang J, Su Z (2011) High-performance oxygen sensors based on EuIII complex/polystyrene composite nanofibrous memabranes prepared by electrospinning. Chem Phys Chem 12: 349-355.
227. Wang Z, McWilliams AR, Evans CEB, Lu X, Chung S, Winnik MA, Manners I (2002) Covalent attachment of RuII phenanthroline complexes to polythionylphosphazenes: the development and evaluation of single-component polymeric oxygen sensors. Adv Funct Mater 12(6-7): 415-419.
228. Wang X, Meier RJ, Link M, Wolfbeis OS (2010) Photographing oxygen distribution. Angew Chem Int Edit 49(29): 4907-4909.
229. Wang XF, Uchida T, Coleman DM, Minami S (1991) A two dimensional fluorescence lifetime imaging system using a gated image intesifier. Appl Spectrosc 45: 360-366.
230. Wang X, Zhou T, Chen X, Wong K, Wang X (2008) An optical biosensor for the rapid determination of glucose in human serum. Sens Actuators B 129(2): 866-873.
231. Wenzhöfer F, Glud RN (2004) small-scale spatial and temporal variability in coastal benthic O2 dynamics: effects of fauna activity. Limnol Oceanogr 49(5): 1471-1481.
232. Werner T, Klimant I, Huber C, Krause C, Wolfbeis OS (1999) Fiber optic ion-microsensors based on luminescence lifetime. Mikrochim Acta 131(1): 25-28.
233. Wilhem S, Wolfbeis O (2011) Irreversible sensing of oxygen ingress. Biosens Actuators B 153: 199-204.
234. Wolfbeis OS (2006) Fiber-optic chemical sensors and biosensors. Anal Chem 78(12): 3859-3874.
235. Wolfbeis OS, Leiner PMJ, Posch HE (1986) A new sensing material for optical oxygen measurement, with the indicator embedded in an aqueous phase. Mikrochim Acta 90(5): 359-366.
236. Wolfbeis OS, Oehme I, Papkovskaya N, Klimant I (2000) Sol-gel based glucose biosensors employing optical oxygen transducers, and a method for compensating for variable oxygen background. Biosens Bioelectron 15: 69-76.
237. Wolfbeis OS, Posch HE, Kroneis HW (1985) Fiber optical fluorosensor for determination of halothane and/or oxygen. Anal Chem 57: 2556-2561.
238. Woods RJ, Scypinski S, Cline LJ (1984) Transient digitizer for the determination of microsecond luminescence lifetimes. Anal Chem 56(8): 1395-1400.
239. Wu XJ, Choi MMF (2003) Hydrogel network entrapping cholesterol oxidase and octadecylsilica for optical biosensing in hydrophobic organic or aqueous micelle solvents. Anal Chem 75: 4019-4027.
240. Wu XJ, Choi MMF (2004) An optical glucose biosensor based on entrapped-glucose oxidase in silicate xerogel hybridised with hydroxyethyl carboxymethyl cellulose. Anal Chim Acta 514(2): 219-226.
241. Wu XJ, Choi MMF (2004) Spongiform immobilization architecture of ionotropy polymer hydrogel coentrapping alcohol oxidase and horseradish peroxidase with octadecylsilica for optical biosensing alcohol in organic solvent. Anal Chem 76(15): 4279-4285.
242. Wu XJ, Choi MMF, Wu XM (2004) An organic-phase optical phenol biosensor coupling enzymatic oxidation with chemical reduction. Analyst 129(11): 1143-1149.
243. Wu X, Choi MMF, Xiao D (2000) A glucose biosensor with enzyme-entrapped sol-gel and an oxygen-sensitive optode membrane. Analyst 125(no. 1): 157-162.
244. Wu W, Wu W, Ji S, Guo H, Song P, Han K, Chi L, Shao J, Zhao J (2010) Tuning the emission properties of cyclometalated platinum(II) complexes by intramolecular electron-sink/arylethynylated ligands and its application for enhanced luminescent oxygen sensing. J Mater Chem 20(43): 9775-9786.
245. Xavier MP, Garcia-Fresnadillo D, Moreno-Bondi MC, Orellana G (1998) Oxygen sensing in nonaqueous media using porous glass with covalently bound luminescence Ru(II) complexes. Anal Chem 70: 5184-5189.
246. Xiang H, Zhou L, Feng Y, Cheng J, Wu D, Zhou X (2012) Tunable fluorescent/phosphorescent platinum(II) porphyrin-fluorene copolymers for ratiometric dual emissive oxygen sensing. Inorg Chem 51(9): 5208-5212.
247. Xiao D, Choi MMF (2002) Aspartame optical biosensor with bienzyme-immobilized eggshell membrane and oxygen-sensitive optode membrane. Anal Chem 74(4): 863-870.
248. Xie K, Zhang X-W, Huang L, Wang Y-T, Lei Y, Rong J, Qian C-W, Xie Q-L, Wang Y-F, Hong A, Xiong S (2011) On-line monitoring of oxygen in TubeSpin, a novel, small-scale disposable bioreactor. Cytotechnology 63(4): 345-350.
249. Xu H, Aylott JW, Kopelman R, Miller TJ, Philbert MA (2001) A real-time ratiometric method for the determination of molecular oxygen inside living cells using sol-gel-based spherical optical nanosensors with applications to Rat C6 glioma. Anal Chem 73(17): 4124-4133.
250. Xu W, Kneas KA, Demas JN, DeGraff BA (1996) Oxygen sensors based on luminescence quenching of metal complexes: osmium complexes suitable for laser diode excitation. Anal Chem 68(15): 2605-2609.
251. Xu W, McDonough RC, Langsdorf B, Demas JN, DeGraff BA (1994) Oxygen sensor based on luminescence quenching: Interactions of metal complexes with the polymer supports. Anal Chem 66: 4133-4141.
252. Xu W, Schmidt R, Whaley M, Demas JN, DeGraff BA, Karikari EK, Farmer BL (1995) Oxygen sensors based on luminescence quenching: interations of pyrene with the polumer supports. Anal Chem 67: 3172-3180.
253. Yingkui L (2011) High performance oxygen sensing nanofibrous membranes of Eu(III) complex/polystyrene prepared by electrospinning. Spectrochim Acta A 79: 356-360.
254. Yoshihara T, Yamaguchi Y, Hosaka M, Takeuchi T, Tobita S (2012) Ratiometric molecular sensor for monitoring oxygen levels in living cells. Angew Chem Int Ed 51: 4148-4151.
255. Zanzotto A, Szita N, Boccazzi P, Lessard P, Sinskey AJ, Jensen KF (2004) Membrane-aerated microbioreactor for high-throughput bioprocessing. Biotechnol Bioeng 87(2): 243-254.
256. Zhang G, Chen J, Payne SJ, Kooi SE, Demas JN, Fraser CL (2007) Multi-emissive difluoroboron dibenzoylmethane polylactide exhibiting intense fluorescence and oxygen-sensitive room-temperature phosphorescence. J Am Chem Soc 129: 8942-8943.
257. Zhang S, Hosaka M, Yoshihara T, Negishi K, Iida Y, Tobita S, Takeuchi T (2010) Phosphorescent light-emitting iridium complexes serve as a hypoxia-sensing probe for tumor imaging in living animals. Cancer Res 70(11): 4490-4498.
258. Zhang G, Palmer GM, Dewhirst MW, Fraser CL (2009) A dual-emissive-materials design concept enables tumour hypoxia imaging. Nat Mater 8: 747-751.
259. Zhujun Z, Seitz WR (1986) Optical sensor for oxygen based on immobilized hemoglobin. Anal Chem 58(1): 220-222.
260. Zuo Q, Li B, Zhang L, Wang Y, Liu Y, Zhang J, Chen Y, Guo L (2010) Synthesis, photophysical and oxygen-sensing properties of a novel Eu3+ complex incorporated in mesoporous MCM-41. J Solid State Chem 183: 1715-1720.