The reaction mechanism of the enantioselective tsuji allylation: Inner-sphere and outer-sphere pathways, internal rearrangements, and asymmetric c-c bond formation

Journal of the American Chemical Society

Volumn 134, Issue 46, 2012, Pages 19050-19060

  Keith, John A ^a   Behenna, Douglas C ^b   Sherden, Nathaniel ^b   Mohr, Justin T ^b   Ma, Sandy ^b   Marinescu, Smaranda C ^b   Nielsen, Robert J ^a   Oxgaard, Jonas ^a   Stoltz, Brian M ^b   Goddard, William A ^a  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

^b California Institute of Technology   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYL FRAGMENTS; ALLYLATION REACTIONS; ASYMMETRIC C-C BOND FORMATION; COMPUTATIONAL SCHEMES; ENANTIOSELECTIVE; ENOLATES; INNERSPHERE MECHANISM; PD SPECIES; REACTION MECHANISM; REACTION PATHWAYS; REDUCTIVE ELIMINATION; TRANSITION STATE;

ALLYLATION; CHEMICAL BONDS; CHEMICAL COMPOUNDS; DENSITY FUNCTIONAL THEORY; NUCLEOPHILES; OLEFINS; PALLADIUM COMPOUNDS; QUANTUM THEORY; SPHERES;

ENANTIOSELECTIVITY;

ALKYLATION; ALLYLATION; ARTICLE; CHEMICAL BOND; CHEMICAL MODIFICATION; CONFORMATION; CRYSTAL STRUCTURE; ENANTIOSELECTIVITY; NUCLEOPHILICITY; THERMODYNAMICS;

CARBON; STEREOISOMERISM; THERMODYNAMICS;

EID: 84869426195     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja306860n     Document Type: Article

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