메뉴 건너뛰기




Volumn 127, Issue 39, 2005, Pages 13510-13511

Catalytic decarboxylative sp-sp3 coupling

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID DERIVATIVE; ACETYLIDE; ALLYL COMPOUND; CARBON DIOXIDE; CARBOXYLIC ACID DERIVATIVE; ORGANOMETALLIC COMPOUND; PALLADIUM; PROPIOLIC ACID DERIVATIVE; UNCLASSIFIED DRUG;

EID: 25844460569     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0542688     Document Type: Article
Times cited : (200)

References (29)
  • 2
    • 25844474824 scopus 로고
    • Early examples of decarboxylative coupling reactions: (a) Bjorkland, C.; Nilsson, M. Acta Chem. Scand. 1968, 22, 2585-2588.
    • (1968) Acta Chem. Scand. , vol.22 , pp. 2585-2588
    • Bjorkland, C.1    Nilsson, M.2
  • 22
    • 25844468457 scopus 로고    scopus 로고
    • note
    • We speculate that the slower reaction of the least sterically hindered substrate indicates that either phosphine dissociation or dissociative σ-allyl formation is rate-limiting for the mono- and unsubstituted substrates.
  • 26
    • 25844512255 scopus 로고    scopus 로고
    • note
    • trans-1s reacts exclusively by elimination, thus isomerization to cis-1s does not occur to any appreciable extent during the reaction.
  • 28
    • 33847086796 scopus 로고
    • Palladium-induced ionization of allylic acetates occurs mainly with inversion of stereochemistry. Trost, B. M.; Verhoeven, T. R. J. Am. Chem. Soc. 1980, 102, 4730-4743.
    • (1980) J. Am. Chem. Soc. , vol.102 , pp. 4730-4743
    • Trost, B.M.1    Verhoeven, T.R.2
  • 29
    • 25844514006 scopus 로고    scopus 로고
    • note
    • 2H to PhCCH in 10 min at room temperature.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.