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note
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We speculate that the slower reaction of the least sterically hindered substrate indicates that either phosphine dissociation or dissociative σ-allyl formation is rate-limiting for the mono- and unsubstituted substrates.
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23
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26
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25844512255
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note
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trans-1s reacts exclusively by elimination, thus isomerization to cis-1s does not occur to any appreciable extent during the reaction.
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28
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33847086796
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Palladium-induced ionization of allylic acetates occurs mainly with inversion of stereochemistry. Trost, B. M.; Verhoeven, T. R. J. Am. Chem. Soc. 1980, 102, 4730-4743.
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29
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25844514006
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note
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2H to PhCCH in 10 min at room temperature.
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