Hydrogen-bond-driven electrophilic activation for selectivity control: Scope and limitations of fluorous alcohol-promoted selective formation of 1,2-disubstituted benzimidazoles and mechanistic insight for rationale of selectivity

Journal of Organic Chemistry

Volumn 77, Issue 22, 2012, Pages 10158-10167

  Chebolu, Rajesh ^a   Kommi, Damodara N ^a   Kumar, Dinesh ^a   Bollineni, Narendra ^a   Chakraborti, Asit K ^a  

^a NATIONAL INSTITUTE OF PHARMACEUTICAL EDUCATION AND RESEARCH NIPER   (India)

Author keywords

[No Author keywords available]

Indexed keywords

BENZIMIDAZOLES; CYCLOCONDENSATION; ELECTROPHILIC ACTIVATION; FLUOROUS; HYDROGEN BOND DONORS; O-PHENYLENEDIAMINE; SELECTIVE FORMATION; SELECTIVITY CONTROL; TRIFLUOROETHANOL;

ALDEHYDES; ETHANOL; HYDROGEN; MASS SPECTROMETRY; ORGANIC COMPOUNDS; ORGANIC SOLVENTS;

PROPANOL;

ALCOHOL; ALDEHYDE; BENZIMIDAZOLE DERIVATIVE; FLUORINE; HEXAFLUORO 2 PROPANOL; PHENYLENEDIAMINE; TRIFLUOROETHANOL;

ALDOL REACTION; ARTICLE; CHEMICAL ANALYSIS; ELECTROPHILICITY; HYDROGEN BOND; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY;

ALCOHOLS; ALDEHYDES; BENZIMIDAZOLES; CATALYSIS; HYDROCARBONS, FLUORINATED; HYDROGEN BONDING; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR STRUCTURE; SOLVENTS;

EID: 84869197385     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo301793z     Document Type: Article

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