Palladium-Catalyzed Carbonylation of Chloroacetates to Afford Malonates: Controlling the Selectivity of the Product in a Buffer

ChemCatChem

Volumn 4, Issue 11, 2012, Pages 1776-1782

  Hu, Jianglin ^a   Zhang, Qi ^a   Guan, Zhenhong ^a   Gu, Yanlong ^a   Mo, Wanling ^a   Li, Tao ^a   Li, Guangxing ^a  

^a HUAZHONG UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

Author keywords

Buffer; Carbonylation; Homogeneous catalysis; Malonates; Palladium

Indexed keywords

ALKALINE BUFFER; BUFFER; BUFFER MEDIUM; CATALYTIC CYCLES; DIETHYL MALONATES; EFFICIENT PROCESS; ETHYL CHLOROACETATE; FOUR CYCLES; HOMOGENEOUS CATALYSIS; MALONATES; OXIDATIVE ADDITIONS; PALLADIUM-CATALYZED; PD BLACK; PD CATALYST; REDUCTIVE ELIMINATION;

CARBONYLATION; PALLADIUM; REACTION KINETICS; SODIUM;

CATALYSIS;

EID: 84868015971     PISSN: 18673880     EISSN: 18673899     Source Type: Journal    
DOI: 10.1002/cctc.201200245     Document Type: Article

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