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Volumn 5, Issue 2, 1999, Pages 466-473

Evidence of the reversible formation of cationic π-allylpalladium(II) complexes in the oxidative addition of allylic acetates to palladium(0) complexes

Author keywords

Allyl complexes; Cations; Mechanistic studies; Palladium; Reversible oxidative addition

Indexed keywords

ALLYL COMPOUND; CATION; FURAN DERIVATIVE; PALLADIUM COMPLEX; TETRAHYDROFURAN;

EID: 0032971683     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3765(19990201)5:2<466::AID-CHEM466>3.0.CO;2-E     Document Type: Article
Times cited : (81)

References (36)
  • 2
    • 0003417469 scopus 로고
    • (Eds: B. M. Trost, I. Pflemming, M. F. Semmelhack), Pergamon, Oxford
    • b) S. A. Godleski, in Comprehensive Organic Synthesis, Vol. 4 (Eds: B. M. Trost, I. Pflemming, M. F. Semmelhack), Pergamon, Oxford, 1991.
    • (1991) Comprehensive Organic Synthesis , vol.4
    • Godleski, S.A.1
  • 9
    • 0001490103 scopus 로고
    • a) To our knowledge only one π-allylpalladium complex resulting from an oxidative addition of an allylic acetate has been reported with acetate as the counter anion, see; T. Yamamoto, O. Saito, A. Yamamoto, J. Am. Chem. Soc. 1981, 103, 5600-5602;
    • (1981) J. Am. Chem. Soc. , vol.103 , pp. 5600-5602
    • Yamamoto, T.1    Saito, O.2    Yamamoto, A.3
  • 27
    • 85033968682 scopus 로고    scopus 로고
    • note
    • a) Two small signals were also present at δ= 18.42 and 18.48 due to decomposition of the cationic π-allylpalladium complex in the NMR tube;
  • 28
    • 85033963239 scopus 로고    scopus 로고
    • note
    • b) The spectrum was contaminated by some triphenylphosphine oxide at δ= 25.68.
  • 30
    • 85033949796 scopus 로고    scopus 로고
    • note
    • 2, respectively
  • 31
    • 85033970480 scopus 로고    scopus 로고
    • note
    • 0 values were determined based on different values of D measured in the range 380-440 nm and were found to be independent of the selected wavelengths in this range, yet the best precision was obtained at 405 mm.
  • 35
    • 85033957172 scopus 로고    scopus 로고
    • note
    • [8b]


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.