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a) To our knowledge only one π-allylpalladium complex resulting from an oxidative addition of an allylic acetate has been reported with acetate as the counter anion, see; T. Yamamoto, O. Saito, A. Yamamoto, J. Am. Chem. Soc. 1981, 103, 5600-5602;
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0000518909
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2 with bidentate or monodentate phosphine ligands in allylic substitutions see: a) J. C. Fiaud, A. Hibon de Gournay, M. Larchevêque, H. B. Kagan, J. Organomet. Chem. 1978, 154, 175-185;
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85033968682
-
-
note
-
a) Two small signals were also present at δ= 18.42 and 18.48 due to decomposition of the cationic π-allylpalladium complex in the NMR tube;
-
-
-
-
28
-
-
85033963239
-
-
note
-
b) The spectrum was contaminated by some triphenylphosphine oxide at δ= 25.68.
-
-
-
-
29
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33845555800
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B. Akermark, G. Akermark, L. S. Hegedus, K. Zetterberg, J. Am. Chem. Soc. 1981, 103, 3037-3040.
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30
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-
85033949796
-
-
note
-
2, respectively
-
-
-
-
31
-
-
85033970480
-
-
note
-
0 values were determined based on different values of D measured in the range 380-440 nm and were found to be independent of the selected wavelengths in this range, yet the best precision was obtained at 405 mm.
-
-
-
-
34
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0001124147
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T. Hayashi, A. Yamamoto, T. Hagihara, J. Org. Chem. 1986, 51, 723-727.
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35
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85033957172
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note
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[8b]
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36
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37049135258
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