Catalysis through temporary intramolecularity: Mechanistic investigations on aldehyde-catalyzed cope-type hydroamination lead to the discovery of a more efficient tethering catalyst

Journal of the American Chemical Society

Volumn 134, Issue 40, 2012, Pages 16571-16577

  Guimond, Nicolas ^a   MacDonald, Melissa J ^a   Lemieux, Valérie ^a   Beauchemin, André M ^a  

^a UNIVERSITY OF OTTAWA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYLIC AMINES; CATALYTIC CYCLES; CATALYTIC SYSTEM; FIRST-ORDER; HIGH YIELD; HYDROAMINATION PRODUCTS; HYDROAMINATIONS; KINETIC ISOTOPE EFFECTS; PARAFORMALDEHYDES; RATE-LIMITING STEPS; REACTION CONDITIONS;

ACETAL RESINS; ALDEHYDES; CATALYSIS; CATALYSTS; ISOTOPES; OLEFINS; REACTION INTERMEDIATES; REACTION KINETICS;

ORGANIC COMPOUNDS;

ACETALDEHYDE; ALDEHYDE; ALKYLHYDROXYLAMINE; ALPHA BENZYLOXYACETALDEHYDE; AMINE; HYDROXYLAMINE; PARAFORMALDEHYDE; UNCLASSIFIED DRUG;

AMINATION; ARTICLE; CATALYSIS; CATALYST; CHEMICAL PARAMETERS; CHEMICAL REACTION; CHEMICAL STRUCTURE; ENANTIOSELECTIVITY; HYDROAMINATION; INTRAMOLECULARITY; MOLECULAR MECHANICS; MOLECULAR PROBE;

ALDEHYDES; ALLYL COMPOUNDS; AMINATION; AMINES; CATALYSIS; HYDROXYLAMINES;

EID: 84867366871     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja303320x     Document Type: Article

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