Why triple bonds protect acenes from oxidation and decomposition

Journal of the American Chemical Society

Volumn 134, Issue 36, 2012, Pages 15071-15082

  Fudickar, Werner ^a   Linker, Torsten ^a  

^a UNIVERSITY OF POTSDAM   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYNYL GROUPS; BIMOLECULAR RATE CONSTANTS; COMPUTATIONAL STUDIES; CONCERTED MECHANISM; ENDOPEROXIDES; FRONTIER MOLECULAR ORBITALS; FUTURE DESIGNS; OXIDATION STABILITY; PENTACENES; PHOTOOXYGENATIONS; RADICAL STABILIZATION ENERGY; REACTION ENERGY; REGIOISOMERS; SINGLET OXYGEN; TRIPLE BONDS;

CHEMICAL BONDS; DENSITY FUNCTIONAL THEORY; FUNCTIONAL GROUPS; MOLECULAR ORBITALS; RATE CONSTANTS;

OXIDATION;

ALKYNYL GROUP; ANTHRACENE DERIVATIVE; CYCLOALKENE; ENDOPEROXIDE; FUNCTIONAL GROUP; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE; RADICAL; SINGLET OXYGEN;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION KINETICS; DECOMPOSITION; DENSITY FUNCTIONAL THEORY; ENERGY; ISOMER; MOLECULAR STABILITY; OXIDATION; PHOTOOXIDATION; REACTION ANALYSIS; SEMICONDUCTOR; STEREOCHEMISTRY;

ANTHRACENES; KINETICS; MOLECULAR STRUCTURE; NAPHTHACENES; OXIDATION-REDUCTION; QUANTUM THEORY; SINGLET OXYGEN; TEMPERATURE;

EID: 84866375897     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja306056x     Document Type: Article

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