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Volumn , Issue , 2010, Pages 83-104

The Stability of Carbon-Centered Radicals

Author keywords

Carbon centered radical stability in organic synthesis, biological chemistry and polymer chemistry; IMOMO scheme application; RSE values in practical applications

Indexed keywords


EID: 84861494642     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9780470584118.ch5     Document Type: Chapter
Times cited : (41)

References (49)
  • 3
    • 85042547097 scopus 로고    scopus 로고
    • CRC Press, Standard bond dissociation energies (in kJ/mol) for the systems in Tables 5.1 and 5. 2 are listed as follows: CH3-H +439. 3 ±0. 4 kJ/mol; CH3CH2-H +420. 5±1. 3 kJ/mol; (CH3)2CH-H +410. 5±2. 9 kJ/mol; (CH3)3C-H +400. 4±2. 9 kJ/mol; CH2CHCH2-H +369±3 kJ/mol; C6H5CH2-H +375. 5±5 kJ/mol; CH2F-H +423. 8±4. 2 kJ/mol; CHF2-H +431. 8±4. 2 kJ/mol; CH3-CH3 +377. 4±0. 8 kJ/mol; CH3-CH2CH3 +370. 3±2. 1 kJ/mol; CH3CH2-CH2CH3 +363. 2±2. 5 kJ/mol; CH3-CH2F +388. 3±8. 4 kJ/ mol; CH3-CHF2 +405. 0±8. 4 kJ/mol; CH3-CF3 +429. 3±5. 0 kJ/mol
    • Luo, Y. -R, Comprehensive Handbook of Chemical Bond Energies, CRC Press, 2007; Standard bond dissociation energies (in kJ/mol) for the systems in Tables 5.1 and 5.2 are listed as follows: CH3-H +439.3 ±0.4 kJ/mol; CH3CH2-H +420.5±1.3 kJ/mol; (CH3)2CH-H +410.5±2.9 kJ/mol; (CH3)3C-H +400.4±2.9 kJ/mol; CH2CHCH2-H +369±3 kJ/mol; C6H5CH2-H +375.5±5 kJ/mol; CH2F-H +423.8±4.2 kJ/mol; CHF2-H +431.8±4.2 kJ/mol; CH3-CH3 +377.4±0.8 kJ/mol; CH3-CH2CH3 +370.3±2.1 kJ/mol; CH3CH2-CH2CH3 +363.2±2.5 kJ/mol; CH3-CH2F +388.3±8.4 kJ/ mol; CH3-CHF2 +405.0±8.4 kJ/mol; CH3-CF3 +429.3±5.0 kJ/mol.
    • (2007) Comprehensive Handbook of Chemical Bond Energies
    • Luo, Y.-R.1
  • 7
    • 84867907561 scopus 로고    scopus 로고
    • Standard bond dissociation energies (in kJ/mol) as obtained from 88th ed.; David, R. L. Ed.; CRC publishers, 2007, are as follows: CFH2-CFH2 +368.2±8.4 kJ/mol; H-CF3 +445.2±2.9 kJ/mol
    • Standard bond dissociation energies (in kJ/mol) as obtained from CRC Handbook of Chemistry and Physics, 88th ed.; David, R. L. Ed.; CRC publishers, 2007, are as follows: CFH2-CFH2 +368.2±8.4 kJ/mol; H-CF3 +445.2±2.9 kJ/mol.
    • CRC Handbook of Chemistry and Physics


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.