Origin of asymmetric induction in bicyclic guanidine-catalyzed thio-Michael reaction: A bifunctional mode of Lewis acid-Brønsted acid activation

Journal of Organic Chemistry

Volumn 77, Issue 15, 2012, Pages 6553-6562

  Cho, Bokun ^a   Tan, Choon Hong ^a   Wong, Ming Wah ^a  

^a NATIONAL UNIVERSITY OF SINGAPORE   (Singapore)

Author keywords

[No Author keywords available]

Indexed keywords

ACID ACTIVATION; ASYMMETRIC INDUCTION; BIFUNCTIONAL; BOND-FORMING STEP; DFT STUDY; ENERGETIC SPAN MODELS; REACTION PATHWAYS; TURNOVER FREQUENCY;

ADDITION REACTIONS; CATALYSIS; CHEMICAL BONDS;

CHEMICAL ACTIVATION;

BRONSTED ACID; CARBON; GUANIDINE DERIVATIVE; LEWIS ACID; SULFUR;

ARTICLE; CATALYSIS; CHEMICAL BOND; MICHAEL ADDITION; STEREOCHEMISTRY;

ACIDS; BICYCLO COMPOUNDS; CATALYSIS; GUANIDINE; MOLECULAR STRUCTURE; QUANTUM THEORY; SULFHYDRYL COMPOUNDS;

EID: 84864590096     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo301158c     Document Type: Article

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