Theoretical mechanistic study of the TBD-catalyzed intramolecular aldol reaction of ketoaldehydes

Journal of Organic Chemistry

Volumn 75, Issue 14, 2010, Pages 4728-4736

  Hammar, Peter ^a   Ghobril, Cynthia ^b   Antheaume, Cyril ^b   Wagner, Alain ^b   Baati, Rachid ^b   Himo, Fahmi ^c  

^a ROYAL INSTITUTE OF TECHNOLOGY   (Sweden)

^b UNIVERSITÉ DE STRASBOURG   (France)

^c STOCKHOLM UNIVERSITY   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

ALDOL REACTIONS; BIFUNCTIONAL; C-C BOND FORMATION; DENSITY FUNCTIONAL THEORY CALCULATIONS; ENOLIZATION; INTRAMOLECULAR ALDOL REACTIONS; MECHANISTIC PATHWAYS; MECHANISTIC STUDIES; PRODUCT SELECTIVITIES;

CHEMICAL BONDS; CONDENSATION REACTIONS;

DENSITY FUNCTIONAL THEORY;

1,5,7 TRIAZABICYCLO[4.4.0]DEC 5 ENE; ALDEHYDE DERIVATIVE; BICYCLO COMPOUND; CARBON; GUANIDINE; HETEROCYCLIC COMPOUND; PROLINE; UNCLASSIFIED DRUG;

ALDOL REACTION; ARTICLE; CATALYST; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; CONTROLLED STUDY; DENSITY FUNCTIONAL THEORY; PROTON TRANSPORT; REACTION ANALYSIS; STEREOCHEMISTRY;

ALDEHYDES; AZABICYCLO COMPOUNDS; CATALYSIS; KETONES; MODELS, MOLECULAR; MODELS, THEORETICAL; PROLINE; STEREOISOMERISM;

EID: 77954554809     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo100488g     Document Type: Article

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