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Volumn 14, Issue 10, 2012, Pages 2500-2503

Synthesis and studies of a water-soluble and air-stable Cu I/CuII open-shell funnel complex

Author keywords

[No Author keywords available]

Indexed keywords

CALIXARENE; COPPER; LIGAND; PYRIDINE DERIVATIVE; TRIS(2 PYRIDYLMETHYL)AMINE; TRIS(2-PYRIDYLMETHYL)AMINE; WATER;

EID: 84862087015     PISSN: 15237060     EISSN: 15237052     Source Type: Journal    
DOI: 10.1021/ol3007875     Document Type: Article
Times cited : (14)

References (39)
  • 2
    • 0000122198 scopus 로고    scopus 로고
    • Reviews on bioinorganic enzymology.
    • Reviews on bioinorganic enzymology: Chem. Rev. 1996, 96, 2237-3042.
    • (1996) Chem. Rev. , vol.96 , pp. 2237-3042
  • 4
    • 1542334767 scopus 로고    scopus 로고
    • Reviews on biomimetic inorganic chemistry.
    • Reviews on biomimetic inorganic chemistry: Chem. Rev. 2004, 104, 347-1200.
    • (2004) Chem. Rev. , vol.104 , pp. 347-1200
  • 36
    • 1642458294 scopus 로고    scopus 로고
    • For a simple TMPA ligand, three successive protonation constants have been reported with log K = 6.3, 4.5, and 2.7. See
    • For a simple TMPA ligand, three successive protonation constants have been reported with log K = 6.3, 4.5, and 2.7. See: Mareque-Rivas, J. C.; Prabaharan, R.; Torres Martin de Rosales, R. Chem Commun. 2004, 76-77
    • (2004) Chem Commun. , pp. 76-77
    • Mareque-Rivas, J.C.1    Prabaharan, R.2    Torres Martin De Rosales, R.3
  • 39
    • 0037087677 scopus 로고    scopus 로고
    • The first open-shell water stable Cu(I) complex was obtained with a tris(imidazole)-calix[6]arene ligand substituted by three sulfonato groups at the large rim. The ligand however did not allow the characterization of the Cu(II) complex in water, the solubility of which was poor due to charge-charge neutralization (between the three sulfonato substituents and the cupric center)
    • The first open-shell water stable Cu(I) complex was obtained with a tris(imidazole)-calix[6]arene ligand substituted by three sulfonato groups at the large rim. The ligand however did not allow the characterization of the Cu(II) complex in water, the solubility of which was poor due to charge-charge neutralization (between the three sulfonato substituents and the cupric center): Rondelez, Y.; Bertho, G.; Reinaud, O. Angew. Chem., Int. Ed. 2002, 41, 1044-1046
    • (2002) Angew. Chem., Int. Ed. , vol.41 , pp. 1044-1046
    • Rondelez, Y.1    Bertho, G.2    Reinaud, O.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.