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Volumn , Issue 8, 2007, Pages 810-812

Drastic effects of the second coordination sphere on neutral vs. anionic guest binding to a biomimetic Cu(II) center embedded in a calix[6]aza-cryptand

Author keywords

[No Author keywords available]

Indexed keywords

ANION; BIOMIMETIC MATERIAL; CALIXARENE; CALIX[6]AZA CRYPTAND; COORDINATION COMPOUND; HYDROXIDE; LIGAND; UNCLASSIFIED DRUG;

EID: 33847083890     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b613564a     Document Type: Article
Times cited : (42)

References (23)
  • 1
    • 33847061352 scopus 로고    scopus 로고
    • 2237-3042
    • Chem. Rev., 1996, 96, 2237-3042
    • (1996) Chem. Rev.
  • 7
    • 33847057018 scopus 로고    scopus 로고
    • 2 complex displays a non-distorted axial trigonal bipyramidal geometry. See:
    • 2O: 846 (220), EtOH: 855 (325), MeCN: 830 (470), DMF: 869 (295)
  • 21
    • 0000969116 scopus 로고    scopus 로고
    • a = 2 in water; see the supplementary information) Mononuclear Cu(ii)-hydroxo species are rare species that are difficult to stabilize as they classically dimerize to produce the more stable dinuclear species. With ligand calix[6]tris(imidazole), the Cu(ii) complexes undergo a drastic conformation change in the presence of hydroxides to yield di- and trinuclear species with hydroxide bridges out of the cavity. See:
    • L. M. Berreau S. Mahapatra J. A. Halfen V. G. Young, Jr. W. B. Tolman Inorg. Chem. 1996 35 6339
    • (1996) Inorg. Chem. , vol.35 , pp. 6339
    • Berreau, L.M.1    Mahapatra, S.2    Halfen, J.A.3    Young Jr., V.G.4    Tolman, W.B.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.