Cu II-catalyzed asymmetric hydrosilylation of diaryl- and aryl heteroaryl ketones: Application in the enantioselective synthesis of orphenadrine and neobenodine

Chemistry - A European Journal

Volumn 18, Issue 24, 2012, Pages 7486-7492

  Sui, Yao Zong ^a   Zhang, Xi Chang ^a,b   Wu, Jun Wen ^a   Li, Shijun ^a   Zhou, Ji Ning ^a   Li, Min ^a   Fang, Wenjun ^b   Chan, Albert S C ^c   Wu, Jing ^a  

^a HANGZHOU NORMAL UNIVERSITY   (China)

^b ZHEJIANG UNIVERSITY   (China)

^c HONG KONG BAPTIST UNIVERSITY   (Hong Kong)

Author keywords

alcohols; asymmetric catalysis; copper; enantioselectivity; hydrosilylation

Indexed keywords

AIR-STABLE; ASYMMETRIC CATALYSIS; ASYMMETRIC SYNTHESIS; BROAD SPECTRUM; CATALYST SYSTEM; CATALYTIC AMOUNTS; ENANTIOSELECTIVE REDUCTION; ENANTIOSELECTIVE SYNTHESIS; HIGH YIELD; IN-SITU; POLYMETHYLHYDROSILOXANES; TERT BUTANOL;

ALCOHOLS; CATALYSIS; COPPER; HYDROSILYLATION; KETONES; SODIUM;

ENANTIOSELECTIVITY;

4 METHYLDIPHENHYDRAMINE; ANTIHISTAMINIC AGENT; COPPER; DRUG DERIVATIVE; KETONE; LIGAND; ORPHENADRINE; TERT BUTYL ALCOHOL;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM; SYNTHESIS;

CATALYSIS; COPPER; HISTAMINE ANTAGONISTS; KETONES; LIGANDS; MOLECULAR STRUCTURE; ORPHENADRINE; STEREOISOMERISM; TERT-BUTYL ALCOHOL;

EID: 84861799695     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201200379     Document Type: Article

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