Enantioselective phenyl transfer to aldehydes using 1,1′-bi-2- naphthol-3,3′-dicarboxamide as chiral auxiliary

Tetrahedron Letters

Volumn 46, Issue 36, 2005, Pages 6083-6086

  Ito, Katsuji ^a   Tomita, Yuki ^a   Katsuki, Tsutomu ^b  

^a FUKUOKA UNIVERSITY OF EDUCATION   (Japan)

^b KYUSHU UNIVERSITY   (Japan)

Author keywords

1,1 Bi 2 naphthol; Aryl transfer reaction; Asymmetric catalysis; Zinc

Indexed keywords

ALDEHYDE; AMIDE; NAPHTHOL DERIVATIVE; PHENYL GROUP; ZINC DERIVATIVE;

ARTICLE; CHEMICAL REACTION; CHIRALITY; ELECTRON TRANSPORT; ENANTIOSELECTIVITY; NUCLEAR MAGNETIC RESONANCE; X RAY ANALYSIS;

EID: 23244434083     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2005.06.161     Document Type: Article

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27. 4, and concentrated. Silica gel chromatography of the residue (hexane-ethyl acetate = 19:1-9:1) gave the desired product (40.7 mg, 93%) as an oil. Enantiomeric excess of the product was determined to be 95% by HPLC using chiral stationary phase column (Refs. 6a and 8a).